Reversible Small-Molecule Interactions with Coordinatively Unsaturated Metal Centers Held in Metallathiaborane Clusters

Postsynthetic modifications of [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] with Lewis bases: cluster modular tuning

(2016) Susana Luaces et al.   DALTON TRANSACTIONS

Preface for Small Molecule Activation: From Biological Principles to Energy Applications. Part 3: Small Molecules Related to (Artificial) Photosynthesis

(2016) Marcetta Y. Darensbourg et al.   INORGANIC CHEMISTRY

Exploiting Metal–Ligand Bifunctional Reactions in the Design of Iron Asymmetric Hydrogenation Catalysts

(2015) Robert H. Morris   ACCOUNTS OF CHEMICAL RESEARCH

Non-innocent ligands

(2015) Louise A. Berben et al.   CHEMICAL COMMUNICATIONS

Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η2-C2H4)(PPh3)RhSB8H7(PPh3)]

(2015) Susana Luaces et al.   DALTON TRANSACTIONS

[1,1-(η2-dppe)-3-(NC5H5)-closo-1,2-RhSB9H8]: conformational lability and reactivity with H2 upon protonation

(2015) Ana C. Mateo et al.   DALTON TRANSACTIONS

Preface for Small-Molecule Activation: From Biological Principles to Energy Applications. Part 2: Small Molecules Related to the Global Nitrogen Cycle

(2015) Nicolai Lehnert et al.   INORGANIC CHEMISTRY

Forums on Small-Molecule Activation: from Biological Principles to Energy Applications

(2015) Franc Meyer et al.   INORGANIC CHEMISTRY

Metal-mediated transformations of small molecules

(2014) Louise A. Berben et al.   CHEMICAL COMMUNICATIONS

Metal–ligand bifunctional reactivity and catalysis of protic N-heterocyclic carbene and pyrazole complexes featuring β-NH units

(2014) Shigeki Kuwata et al.   CHEMICAL COMMUNICATIONS

Substitutional Lability of Diphosphine Ligands in Tetrahedral Iron(II) Chloro Complexes

(2014) Robert Langer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

NH3-Promoted Ligand Lability in Eleven-Vertex Rhodathiaboranes

(2014) Beatriz Calvo et al.   INORGANIC CHEMISTRY

3-Pyridylacetonitrile-ligated 11-vertex rhodathiaboranes: synthesis, characterization, and X-ray crystal structure

(2014) B. Calvo et al.   JOURNAL OF COORDINATION CHEMISTRY

Do agostic interactions play a role in the stabilization of the nido structure of [(PPh3)2RhSB9H10]?

(2014) Jonathan Bould et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Hydridorhodathiaboranes: Synthesis, Characterization, and Reactivity

(2014) Álvaro Álvarez et al.   ORGANOMETALLICS

Heterolytic H2 activation on a carbene-ligated rhodathiaborane promoted by isonido-nido cage opening

(2013) Beatriz Calvo et al.   CHEMICAL COMMUNICATIONS

Proton-Assisted Hydrogen Activation on Polyhedral Cations

(2013) Beatriz Calvo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unusual cationic rhodathiaboranes: synthesis and characterization of [8,8,8-(H)(PR3)2-9-(Py)-nido-8,7-RhSB9H10]+and [1,3-μ-(H)-1,1-(PR3)2-3-(Py)-isonido-1,2-RhSB9H8]+

(2013) Beatriz Calvo et al.   DALTON TRANSACTIONS

Synthesis and characterization of mixed-ligand ferracarboranes. Direct metalation of the nido-carborane [nido-7,8-C2B9H12]− mono-anion with 14-e [Ph2P(CH2)nPPh2]FeCl2 (n = 2, 3)

(2013) Anton P. Tyurin et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Facile two-electron reduction of a closo-rhodathiadecaborane

(2012) Susana Luaces et al.   DALTON TRANSACTIONS

Reactions of 11-Vertex Rhodathiaboranes with HCl: Synthesis and Reactivity of New Cl-Ligated Clusters

(2012) Beatriz Calvo et al.   INORGANIC CHEMISTRY

Modification of [8,8,8-(H)(PPh3)2-9-(Py)-nido-8,7-RhSB9H9], Py = NC5H5, with Monodentate Phosphines: Reactivity and Mechanistic Insights

(2012) Beatriz Calvo et al.   ORGANOMETALLICS

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chemistry of 11-vertex rhodathiaboranes: reactions with monodentate phosphines

(2011) Beatriz Calvo et al.   DALTON TRANSACTIONS

Cleavage of unreactive bonds with pincer metal complexes

(2011) Martin Albrecht et al.   DALTON TRANSACTIONS

The synthesis, molecular and electronic structure of cyanovinylidene complexes

(2011) Ella M. Long et al.   INORGANICA CHIMICA ACTA

Brønsted Acid/Base Driven Chemistry with Rhodathiaboranes: A Labile {SB9H9}–Thiadecaborane Fragment System

(2011) Beatriz Calvo et al.   ORGANOMETALLICS

New Iridathiaboranes with ReversibleIsonido↔NidoCluster Flexibility

(2010) Jonathan Bould et al.   INORGANIC CHEMISTRY

Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis

(2009) Jarl Ivar van der Vlugt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkyne-Promoted H2Loss in a Metallaborane:Nido-to-ClosoCluster Transformation and sp CH Bond Oxidative Addition

(2009) Álvaro Álvarez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cooperating Ligands in Catalysis

(2008) Hansjörg Grützmacher   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Borane reaction chemistry. Alkyne insertion reactions into boron-containing clusters. Products from the thermolysis of [6,9-(2-HCC–C5H4N)2-arachno-B10H12]

(2008) Jonathan Bould et al.   DALTON TRANSACTIONS

Reversible Ethylene Dihydrogen Mediated 11-Vertexnido→closo→nidoConversion in a Metallathiaborane Cluster

(2008) Álvaro Álvarez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkene Hydrogenation on an 11-Vertex Rhodathiaborane with Full Cluster Participation

(2008) Álvaro Álvarez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY