Article
Energy & Fuels
Alexandra Saitova, Sergey Strokin, Jorge Ancheyta
Summary: The study compared the pyrolysis and oxidation processes of asphaltenes extracted from Yarega heavy crude oil and its residues in both nitrogen and air atmosphere. Different stages of pyrolysis and oxidation were identified, with varying characteristics observed for the different samples. Kinetic parameters were estimated and the findings can potentially contribute to the development of asphaltene processing methods in petroleum refineries.
Article
Energy & Fuels
Dicho Stratiev, Ivelina Shishkova, Ilian Kolev, Dobromir Yordanov, Vesislava Toteva
Summary: Sixteen petroleum crudes and an imported atmospheric residue from various countries were processed in the LUKOIL Neftohim Burgas (LNB) refinery to evaluate their impact on the ebullated bed vacuum residue H-Oil hydrocracking (EBVRHC) performance. The study found that resins had the highest conversion, saturates had the lowest, and different petroleum crudes showed distinct propensity for asphaltenes to participate in radical recombination reactions.
INTERNATIONAL JOURNAL OF OIL GAS AND COAL TECHNOLOGY
(2021)
Review
Engineering, Chemical
Ana M. Sousa, Henrique A. Matos, Maria J. Pereira
Summary: The study reviewed the main principles affecting emulsions, the influence of water fraction on flow patterns, the equations for estimating physical properties, and the methods for identifying or characterizing emulsions.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Chemistry, Physical
Alexey V. Vakhin, Mohammed A. Khelkhal, Irek I. Mukhamatdinov, Rezeda E. Mukhamatdinova, Arash Tajik, Olga Slavkina, Sergey Y. Malaniy, Marat R. Gafurov, Aydar R. Nasybullin, Oleg G. Morozov
Summary: This study investigates the effect of electromagnetic heating on heavy oil upgrading. The use of nanosized magnetite enhances microwave radiation application and catalyzes the breaking of carbon-heteroatom bonds. The transformation of asphaltenes involves the formation of light aromatic compounds.
Article
Thermodynamics
Umesh B. Deshannavar, Ramasamy Marappagounder
Summary: Threshold crude oil fouling models use activation energy to predict initial fouling rates, but this approach has limitations; A modified threshold fouling model that does not rely on activation energy has been proposed and validated in this study.
HEAT TRANSFER ENGINEERING
(2021)
Article
Energy & Fuels
Caiua Araujo Alves, Jose Francisco Romero Yanes, Filipe Xavier Feitosa, Hosiberto Batista de Sant'Ana
Summary: This study compares the effects of asphaltene stability from two different crude oil samples on water-model oil interfacial tension and emulsion stability. The size of molecules in the feedstock has a predominant effect on reducing interfacial tension, while larger molecules are responsible for emulsion stability.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2022)
Article
Thermodynamics
Jin Huo, Shuai Zhao, Jingjun Pan, Wanfen Pu, Mikhail A. Varfolomeev, Dmitrii A. Emelianov
Summary: This study investigated the low-temperature oxidation (LTO) characteristics of crude oils and their SARA components under isothermal conditions. It was found that mass loss in the LTO region was mainly caused by hydrocarbon evaporation, and the interactions between SARA components influenced the formation of products during LTO reactions.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2022)
Article
Environmental Sciences
Blake E. Hunnie, Lars Schreiber, Charles W. Greer, Gary A. Stern
Summary: The Baffin Island Oil Spill (BIOS) Project was conducted in the early 1980s to study the fate of crude oil in the Arctic. In 2019, the study sites were revisited and oiled sediment samples were collected. Analysis showed the presence of petroleum hydrocarbons in various concentrations, with extensive weathering processes observed in certain hydrocarbon groups since the previous study in 2001.
MARINE POLLUTION BULLETIN
(2023)
Article
Biotechnology & Applied Microbiology
Abdul Salam Abdul Raheem, Dorra Hentati, Dawoud Bahzad, Raeid M. M. Abed, Wael Ismail
Summary: We enriched bacterial consortia from oilfield samples and found that they have potential for bio-catalytic upgrading of heavy crude oil. Treatment with one bacterial consortium resulted in an increase in saturates fraction, a decrease in aromatics fraction, a reduction in asphaltene content, and an increase in resins. The biotreated oil also showed better recovery of fractions compared to the non-treated oil. The bacterial consortia composition varied with the source and changed over time, with certain bacteria identified as key players in the bioupgrading process.
INTERNATIONAL BIODETERIORATION & BIODEGRADATION
(2022)
Article
Chemistry, Physical
E. A. Alshaafi, A. Prakash, S. M. Mercer
Summary: The potential of ultrasonic techniques in characterizing water-in-oil emulsions was investigated for industrial applications by studying stability and droplet size distribution in different mineral and crude oil samples. The technique was successfully applied to characterize emulsions with varying asphaltene content in crude oils, demonstrating its applicability in determining acceptable levels to avoid formation of stable emulsions. Attenuation measurements provided a clearer illustration of water separation process in various emulsions compared to volume measurements, with observed attenuation effects linked to emulsion system rheology.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Chemistry, Physical
Brayan F. Garcia, Soheil Saraji
Summary: This study examines interfacial rheology and polar component dynamics in crude oil and brine systems with different salinities. It reveals that diffusion/adsorption processes are the dominant relaxation mechanisms and transient interfacial rheology plays a crucial role in defining final apparent interfacial properties.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Energy & Fuels
Ekaterina E. Barskaya, Ekaterina S. Okhotnikova, Yulia M. Ganeeva, Tatiana N. Yusupova
Summary: In this article, two crude oils with the same composition of resins, asphaltene, and solid paraffin were studied to show their different rheological behavior at low shear rates. The chemical composition of high molecular weight components in crude oil, such as asphaltene and solid paraffin, was analyzed using EPR, IR spectroscopy, and chromatography. The results indicate that the difference in rheological behavior is attributed to the content of saturated and aromatic hydrocarbons in the crude oils.
PETROLEUM SCIENCE AND TECHNOLOGY
(2022)
Review
Energy & Fuels
Chengdong Yuan, Wan-fen Pu, Mohamed Amine Ifticene, Shuai Zhao, Mikhail A. Varfolomeev
Summary: Air injection as a thermal method for heavy oil recovery has a long history but has not been widely applied due to technical complexity. However, with the increasing demand for the development of hard-to-recover resources, air injection technique has gained more attention and significant advancements have been made in theory and technology. This review discusses recent progress in the reaction mechanism of crude oil oxidation and catalytic methods for intensifying crude oil combustion, as well as addressing the challenges and potential solutions for the air injection process. Neglected aspects of the air injection process are also highlighted, along with promising perspectives for future research.
Article
Energy & Fuels
Aaron Macias, Esau A. Hernandez, Vicente Samano, Jorge Ancheyta
Summary: The regular solution model with HBT molar volume correlation is used to predict asphaltene precipitation in crude oils and blends. The presence of other compounds greatly affects asphaltene precipitation under the same temperature and pressure conditions. The proposed model accurately predicts asphaltene precipitation using average properties and assumptions.
PETROLEUM SCIENCE AND TECHNOLOGY
(2023)
Article
Energy & Fuels
Oscar E. Medina, Jaime Gallego, Santiago Cespedes, Nashaat N. Nassar, Tatiana Montoya, Farid B. Cortes, Camilo A. Franco
Summary: This work investigates the thermo-oxidative behavior of saturates, aromatics, and resins at different pressures. The study found that as pressure increases, the influence of aromatics on oxidation reactions at high temperatures becomes greater. Aromatics and resins exhibited four stages in the oxidation process at high pressures, while saturates only had two stages. The amount of coke generated followed the order of saturates < aromatics < resins. The kinetic analysis results supported the experimental findings.
Article
Chemistry, Physical
Bo Bao, Seyed Hadi Zandavi, Huawei Li, Junjie Zhong, Arnav Jatukaran, Farshid Mostowfi, David Sinton
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2017)
Article
Engineering, Electrical & Electronic
Parvaneh Saffari, Ali Basaligheh, Vincent J. Sieben, Kambiz Moez
IEEE TRANSACTIONS ON CIRCUITS AND SYSTEMS I-REGULAR PAPERS
(2018)
Article
Chemistry, Physical
Junjie Zhong, Jason Riordon, Seyed Hadi Zandavi, Yi Xu, Aaron H. Persad, Farshid Mostowfi, David Sinton
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2018)
Article
Biochemical Research Methods
Junjie Zhong, Soheil Talebi, Yi Xu, Yuanjie Pang, Farshid Mostowfi, David Sinton
Article
Chemistry, Multidisciplinary
Junjie Zhong, Yinuo Zhao, Chang Lu, Yi Xu, Zhehui Jin, Farshid Mostowfi, David Sinton
Article
Chemistry, Analytical
Sean C. Morgan, Andre D. Hendricks, Mae L. Seto, Vincent J. Sieben
Article
Energy & Fuels
Raha Khosravi, Cesar Rodriguez, Farshid Mostowfi, Vincent Sieben
Article
Energy & Fuels
Shahnawaz Molla, Farshid Mostowfi
Summary: The newly developed microfluidic device accurately measures the dew point pressure of retrograde gas condensates, with small sample volume and fast speed, making it suitable for characterizing gas condensate reservoirs at multiple temperatures.
Article
Chemistry, Analytical
Joshua J. Creelman, Edward A. Luy, Gabryelle C. H. Beland, Colin Sonnichsen, Vincent J. Sieben
Summary: The novel microfluidic optical cell enables simultaneous measurement of light absorbance and fluorescence on microlitre volumes of fluid, with excellent performance evaluated using a stable fluorescent dye. Linear relationships were found for absorbance and fluorescence over a wide concentration range, and the approach is applicable to numerous colorimetric- or fluorescence-based assays.
Article
Chemistry, Analytical
Benjamin J. Murphy, Edward A. Luy, Katerina L. Panzica, Gregory Johnson, Vincent J. Sieben
Summary: A novel method of conserving heat energy in microfluidic systems has been proposed, which reduces heat transfer by surrounding the heated optical cell with air pockets. The insulated design significantly reduces power consumption and performs well in nitrate concentration measurements.
Article
Chemistry, Physical
Farshid Mostowfi, Plamen Tchoukov, Nikolay Panchev, Tadeusz Dabros, Jan Czarnecki
Summary: Electrohydrodynamic instabilities in thin water-in-oil emulsion films were induced by an external DC electric field, with the dominant wavelengths measured for different strengths of electric fields aligning reasonably well with theoretical predictions based on a linear stability model. This model considered the experimentally measured repulsive disjoining pressure and calculated Maxwell stress, providing insights into the rupture mechanism of emulsion films under the influence of an electric field.
COLLOIDS AND INTERFACES
(2021)
Article
Biochemical Research Methods
Arnav Jatukaran, Junjie Zhong, Ali Abedini, Atena Sherbatian, Yinuo Zhao, Zhehui Jin, Farshid Mostowfi, David Sinton
Article
Nanoscience & Nanotechnology
Arnav Jatukaran, Junjie Zhong, Aaron H. Persad, Yi Xu, Farshid Mostowfi, David Sinton
ACS APPLIED NANO MATERIALS
(2018)
Article
Chemistry, Multidisciplinary
Junjie Zhong, Ali Abedini, Lining Xu, Yi Xu, Zhenbang Qi, Farshid Mostowfi, David Sinton