Article
Engineering, Chemical
Zheng Wang, Junyong Zhu, Shuainan Xu, Yatao Zhang, Bart Van der Bruggen
Summary: A stable composite membrane was developed by utilizing Cu-TCPP nanosheets to stabilize GO membranes, resulting in significantly improved water permeance and remarkable solute retention.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Nanoscience & Nanotechnology
Keizo Nakagawa, Misato Kunimatsu, Kengo Yasui, Tomohisa Yoshioka, Takuji Shintani, Tomoki Yasui, Eiji Kamio, Wei-Song Hung, Kueir-Rarn Lee, Shik Chi Edman Tsang, Hideto Matsuyama
Summary: Two-dimensional nanomaterials, specifically the GO/NbN membrane with a dense heterolayer interface, show superior separation performance in nanofiltration due to the locally tuned interfacial layer design. Molecular dynamics simulations indicate a stable interlayer spacing and strong interaction between nanosheet surfaces, contributing to the higher rejection rate. The layered GO/NbN membrane has a fundamentally different structure from previously reported laminar membranes.
ACS APPLIED NANO MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Marliyana Aizudin, Nur Hashimah Alias, Yun Xin Angel Ng, Muhammad Haikal Mahmod Fadzuli, Seng Chuan Ang, Yi Xun Ng, Rafeeque Poolamuri Pottammel, Fu Yang, Edison Huixiang Ang
Summary: This mini-review summarizes the recent progress in the synthesis of graphene-based nanomaterials (GBnMs) and their applications in water treatment technologies, specifically nanofiltration (NF) and solar desalination (SD). The challenges and future directions of this promising nanomaterial are also discussed.
Article
Engineering, Chemical
Zhiming Zhang, Hong Wu, Li Cao, Meidi Wang, Hongjian Wang, Fusheng Pan, Zhongyi Jiang
Summary: Graphene oxide (GO) lamellar membranes suffer from low flux and poor stability for practical applications due to tortuous transport pathways and weak interlamellar interactions. In this study, porous vermiculite (PVMT) nanosheets were incorporated into the GO-based membranes to establish fast and robust water-selective pathways. PVMT nanosheets provided in-plane pores, reducing the tortuosity and mass transport distance. The hydrophilicity and interlayer distance were enhanced by PVMT nanosheets, contributing to water-selective transport. The resulting membranes exhibited excellent dehydration performance with increased permeation flux and separation factor compared to pristine GO/PTFE membranes, while maintaining stability for 192 h operation. This study may inspire further research in constructing mass-transfer pathways within lamellar membranes.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Chemistry, Physical
Mattia Musto, Pietro Parisse, Maria Pachetti, Christian Memo, Giuseppe Di Mauro, Belen Ballesteros, Neus Lozano, Kostas Kostarelos, Loredana Casalis, Laura Ballerini
Summary: Microvesicles generated by astrocytes play a crucial role in intercellular communication, modulating neuronal functions. By utilizing nanotechnology and unconventional tools, deeper understanding of these glial signals can be achieved.
Article
Engineering, Environmental
Vahid Vatanpour, Basak Keskin, Seyed Ali Naziri Mehrabani, Hamid Karimi, Negar Arabi, Amir Hossein Behroozi, Ali Shokrollahi-far, Bahar Yavuzturk Gul, Ismail Koyuncu
Summary: This research introduces a feasible procedure for improving membrane separation performance by blending a nanocomposite material into the polyethersulfone membrane. The addition of 1% FBN-GO-Ag nanocomposite led to significant improvements in membrane properties, such as increased permeability, antifouling and antibacterial properties, separation ability, and mechanical strength.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
N. A. Chumakova, Vorobiev A. Kh, D. A. Astvatsaturov, T. S. Yankova, A. T. Rebrikova, M. Matveev
Summary: The orientational alignment of graphene oxide membranes was quantitatively determined using the spin probe technique. The values of the orientational order parameters up to the 6th rank were obtained. It was found that nitroxide probes and Cu(ii) complexes effectively reflected the alignment of the membranes. Moreover, the orientation alignment of the membranes prepared by vacuum filtration and drying the graphite oxide suspension were significantly different, with the latter showing poor alignment.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Engineering, Chemical
Zan Chen, Peng Zhang, Hong Wu, Sihan Sun, Xinda You, Biao Yuan, Jie Hou, Cuijia Duan, Zhongyi Jiang
Summary: In this study, graphene oxide nanosheets were modified with amino acids to enhance CO2 separation performance in mixed matrix membranes. The interaction mechanism between gas molecules and amino acids was further elucidated through density functional theory calculations. The amino acid-modified graphene oxide nanosheets showed promising potential to explore CO2 transfer mechanism and fabricate high separation performance membranes.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Electrical & Electronic
Subramanian Ravichandran, K. Pushpanathan, Suresh Sagadevan, A. R. Marlinda, Faruq Mohammad, Hamad A. Al-Lohedan, Mohd Rafie Johan
Summary: This study reported the influence of graphene concentration on the vibrational properties of PVA-graphene composites formed at room temperature. Physicochemical characterization and analysis were carried out using various techniques, revealing that the increased concentration of graphene caused changes in the PVA polymer structure and associated deviations in various parameters.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Engineering, Environmental
Yisa Zhou, Ya Zhang, Jian Xue, Rui Wang, Zongjie Yin, Li Ding, Haihui Wang
Summary: In this study, a continuous g-C3N4-GO membrane with excellent H2 permeation performance and good stability was successfully prepared by utilizing graphene oxide nanosheets to cover and repair defects in two-dimensional graphitic carbon nitride (g-C3N4) nanosheets.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Polymer Science
Chien-Hong Lin, Ming-Yen Chien, Yi-Cih Chuang, Chao-Chi Lai, Yi-Ming Sun, Ting-Yu Liu
Summary: The addition of graphene oxide nanosheets significantly improves the mechanical properties of the PSF membrane, enhances the coulombic efficiency of the VRFB, and demonstrates long-term chemical stability.
Article
Chemistry, Multidisciplinary
Poonsawat Paechotrattanakul, Kulpavee Jitapunkul, Pawin Iamprasertkun, Pannaree Srinoi, Weekit Sirisaksoontorn, Wisit Hirunpinyopas
Summary: Graphene oxide (GO) membranes with stacked nanosheets have poor ion rejection, but ultralow oxygen-containing graphene membranes exhibit ultrahigh stability and efficient ion and molecular sieving due to size exclusion and electrostatic repulsion. Machine learning is also used to optimize membrane performance for water purification.
Article
Chemistry, Multidisciplinary
T. T. Zuo, K. Liu, X. Q. Wei, S. Hu, Q. T. Che
Summary: Polymerized ionic liquid (PIL) and graphene oxide (GO) nanosheets were deposited on the surface of Kevlar aramid nanofibers (KANFs) substrates to construct anion exchange membranes (AEMs). The multilayered microstructure improved the mechanical properties and dimension stability of the AEMs. The interconnected hydroxide ion conduction channels were formed by the imidazolium cations in PIL and the polar oxygen functional groups in GO nanosheets.
MATERIALS TODAY CHEMISTRY
(2023)
Article
Environmental Sciences
Ahmed Elreedy, Sherif Ismail, Manal Ali, Shou-Qing Ni, Manabu Fujii, Mohamed Elsamadony
Summary: This study investigated the potential of nanomaterials, specifically graphene nanosheets and gamma-Fe2O3 nanoparticles, in enhancing anaerobic ammonium oxidation (anammox) process. Results showed that graphene nanosheets improved nitrogen removal rate and enzyme activity, while gamma-Fe2O3 nanoparticles increased nitrogen removal rate but had no effect on enzyme activity. The use of nanomaterials also influenced the composition of extracellular polymeric substances (EPS) and microbial enrichment in the anammox process.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2021)
Article
Chemistry, Physical
Aaron Morelos-Gomez, Souya Terashima, Ayaka Yamanaka, Rodolfo Cruz-Silva, Josue Ortiz-Medina, Roque Sanchez-Salas, Juan L. Fajardo-Diaz, Emilio Munoz-Sandoval, Florentino Lopez-Urias, Kenji Takeuchi, Syogo Tejima, Mauricio Terrones, Morinobu Endo
Summary: This study demonstrates that graphene oxide membranes have higher lactose permeation flux and water flux recovery compared to commercial nanofiltration and ultrafiltration membranes, showing better filtration performance and anti-fouling ability.
Article
Multidisciplinary Sciences
Yunfei Gao, Yao Yang, Roberto Schimmenti, Ellen Murray, Hanqing Peng, Yingming Wang, Chuangxin Ge, Wenyong Jiang, Gongwei Wang, Francis J. DiSalvo, David A. Muller, Manos Mavrikakis, Li Xiao, Hector D. Abruna, Lin Zhuang
Summary: This study presents the design of a Ni@CNx electrocatalyst with a carbon shell for enhanced HOR kinetics in alkaline membrane fuel cells. The Ni@CNx anode, when paired with a Co-Mn spinel cathode, achieved a record peak power density of over 200 mW/cm(2). The strategy described in this study marks a milestone in the development of low-cost hydrogen fuel cells and other energy technologies.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2022)
Article
Physics, Applied
Qianbiao Liu, Lijun Zhu, Xiyue S. Zhang, David A. Muller, Daniel C. Ralph
Summary: This study reports a distinct and giant bulk damping-like spin-orbit torque in strong-perpendicular magnetic anisotropy (PMA) ferrimagnetic Fe100-xTbx single layers. The giant bulk torque can switch thick Fe100-xTbx layers with very strong PMA and high coercivity at low current densities.
APPLIED PHYSICS REVIEWS
(2022)
Article
Physics, Applied
Patrick Vogt, Felix V. E. Hensling, Kathy Azizie, Jonathan P. McCandless, Jisung Park, Kursti DeLello, David A. Muller, Huili G. Xing, Debdeep Jena, Darrell G. Schlom
Summary: This study observes a catalytic mechanism during the growth of III-O and IV-O materials by suboxide molecular-beam epitaxy (S-MBE) and proposes a model to describe this growth process. By supplying molecular catalysts, the growth rates of the materials can be increased, resulting in higher crystalline quality.
PHYSICAL REVIEW APPLIED
(2022)
Article
Physics, Applied
Kayla X. Nguyen, Xiyue S. Zhang, Emrah Turgut, Michael C. Cao, Jack Glaser, Zhen Chen, Matthew J. Stolt, Celesta S. Chang, Yu-Tsun Shao, Song Jin, Gregory D. Fuchs, David A. Muller
Summary: The study explores the observation of magnetic phenomena at grain boundaries and interfaces in polycrystalline materials using four-dimensional Lorentz scanning transmission electron microscopy. By addressing the challenge of disentangling magnetic and grain contrast, the research discusses the important parameter for imaging magnetic materials with polycrystalline grains.
PHYSICAL REVIEW APPLIED
(2022)
Article
Chemistry, Multidisciplinary
Vishakha Gupta, Rakshit Jain, Yafei Ren, Xiyue S. Zhang, Husain F. Alnaser, Amit Vashist, Vikram V. Deshpande, David A. Muller, Di Xiao, Taylor D. Sparks, Daniel C. Ralph
Summary: The advantages of mechanically stacked samples of van der Waals materials for controlling the surface state of a three-dimensional topological insulator are demonstrated. The interaction between the topological surface state and an adjacent magnet layer can be controlled, resulting in an observed anomalous Hall effect.
Article
Nanoscience & Nanotechnology
Zhen Chen, Emrah Turgut, Yi Jiang, Kayla X. Nguyen, Matthew J. Stolt, Song Jin, Daniel C. Ralph, Gregory D. Fuchs, David A. Muller
Summary: This study demonstrates a new Lorentz electron ptychography method for high-resolution and high-sensitivity magnetic field imaging. Using the FeGe model, it was found that the method can accurately measure the magnetic field of skyrmions and resolve the internal structures of nanoscale spin textures.
NATURE NANOTECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Celesta S. Chang, Jiaxin Sun, Seunghyun Khim, Andrew P. Mackenzie, Darrell G. Schlom, David A. Muller
Summary: By studying single crystals and epitaxial thin films, we have found that ribbonlike defects are dominant in single-crystal PdCoO2, while different types of defects arising from substrate termination disrupt the lateral connectivity of the conducting planes in thin films. To enhance the quality of PdCoO2 films, selecting a proper substrate, improving surface quality, and reducing the step density are key factors.
PHYSICAL REVIEW MATERIALS
(2022)
Article
Materials Science, Coatings & Films
Tobias Schwaigert, Salva Salmani-Rezaie, Matthew R. Barone, Hanjong Paik, Ethan Ray, Michael D. Williams, David A. Muller, Darrell G. Schlom, Kaveh Ahadi
Summary: Strain-engineering is used to tune the instabilities of incipient ferroelectrics. High-quality KTaO3 thin films are grown by molecular-beam epitaxy. Excess potassium and a combination of ozone and oxygen are supplied with the TaO2 (or tantalum) molecular beams to grow the films with atomically abrupt interfaces. Atomic force microscopy reveals atomic steps at the film surface. Reciprocal space mapping demonstrates coherent strain to the substrates when the films are thin enough.
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A
(2023)
Review
Physics, Multidisciplinary
Javier Junquera, Yousra Nahas, Sergei Prokhorenko, Laurent Bellaiche, Jorge iniguez, Darrell G. Schlom, Long-Qing Chen, Sayeef Salahuddin, David A. Muller, Lane W. Martin, R. Ramesh
Summary: The past decade has witnessed significant progress in understanding emergent topological polar textures in oxide nanostructures, including vortices, skyrmions, merons, hopfions, dipolar waves, and labyrinthine domains. The discovery of low-dimensional ferroelectric oxide nanostructures has altered the perceived energy cost associated with the formation of these structures, allowing for manipulation of order parameters. This review provides a historical context, scientific description, and discussion of the potential applications and future challenges in this field.
REVIEWS OF MODERN PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Yao Yang, Yu-Tsun Shao, Jianbo Jin, Julian Feijoo, Inwhan Roh, Sheena Louisia, Sunmoon Yu, Maria V. Fonseca Guzman, Chubai Chen, David A. Muller, Hector D. Abruna, Peidong Yang
Summary: The design and synthesis of nanocatalysts with well-defined sizes, compositions, and structures have greatly enhanced our ability to control catalyst activity and selectivity for energy-related electrochemical reactions. By using operando electrochemical liquid-cell scanning transmission electron microscopy (EC-STEM), the dynamic evolution of Cu nanocatalysts during CO2 electroreduction was observed, providing valuable insights into their active states. With further technical advancements, operando EC-STEM is expected to become a powerful electroanalytical method for studying nanoscale electrocatalysts at solid/liquid interfaces.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Multidisciplinary Sciences
Ethan G. Arnault, Athby H. Al-Tawhid, Salva Salmani-Rezaie, David A. Muller, Divine P. Kumah, Mohammad S. Bahramy, Gleb Finkelstein, Kaveh Ahadi
Summary: A two-dimensional, anisotropic superconductivity was found at the KTaO3(111) interfaces, which violates the Pauli limit and is robust against in-plane magnetic field. The study shows that the Cooper pairs are more resilient when the bias is along [112] and the magnetic field is along [110]. The anisotropic nature of superconductivity is discussed in the context of electronic structure, orbital character, and spin texture at the KTaO3(111) interfaces.
Article
Materials Science, Multidisciplinary
Megan E. Holtz, Elliot Padgett, Aaron C. Johnston-Peck, Igor Levin, David A. Muller, Andrew A. Herzing
Summary: Measuring local polar ordering is crucial for understanding ferroelectricity in thin films. The cepstral approach allows us to determine the local polar displacements that drive ferroelectricity from nanobeam electron diffraction patterns. Experimental results demonstrate that this technique achieves a precision of 1.1 pm in mapping polar displacements with nanometer resolution.
MICROSCOPY AND MICROANALYSIS
(2023)
Article
Nanoscience & Nanotechnology
Zeming Sun, Darrah K. Dare, Zhaslan Baraissov, David A. Muller, Michael O. Thompson, Matthias U. Liepe
Summary: It has been believed that intermetallic Nb3Sn alloys form through Sn diffusion into Nb. However, our findings of significant oxygen content in Nb3Sn led us to investigate alternative formation mechanisms. Through experiments with different oxide interfaces, we have demonstrated a thermodynamic route that challenges the conventional Sn diffusion mechanism and highlights the involvement of a SnOx intermediate phase. This new mechanism provides principles for growth optimization and synthesis of high-quality Nb3Sn superconductors.
Article
Nanoscience & Nanotechnology
L. van Deurzen, J. Singhal, J. Encomendero, N. Pieczulewski, C. S. Chang, Y. Cho, D. A. Muller, H. G. Xing, D. Jena, O. Brandt, J. Laehnemann
Summary: Using low-temperature cathodoluminescence spectroscopy, the properties of N- and Al- polar AlN layers grown on bulk AlN{0001} by molecular beam epitaxy are studied. Both polarities of layers exhibit a suppression of deep-level luminescence compared to the bulk AlN substrate, a total absence of the prevalent donor with an exciton binding energy of 28 meV, and a much increased intensity of the emission from free excitons. The dominant donor in these layers has an associated exciton binding energy of 13 meV. Additionally, the observation of excited exciton states up to the exciton continuum allows for the direct extraction of the Γ(5) free exciton binding energy of 57 meV.
Article
Chemistry, Physical
Ming Zhou, Dasol Yoon, Yao Yang, Lihua Zhang, Can Li, Hongsen Wang, Anju Sharma, Shaojie Jiang, David A. A. Muller, Heictor D. Abruna, Jiye Fang
Summary: We developed a simple method to synthesize uniform-sized (9 nm) CoMn2O4 spinel nano-octahedra with {101} facets. Compared to their spherical counterparts and previously reported spinel electrocatalysts, these nano-octahedra exhibited enhanced electrocatalytic activity for the oxygen reduction reaction (ORR) in alkaline media. They achieved a high mass activity (MA) of 60.0 A/g at 0.85 V, surpassing their spherical counterparts (38.6 A/g). The CoMn2O4 nano-octahedra also showed favorable stability, maintaining an MA of 47.2 A/g after 10,000 durability cycles. This study highlights the promising approach of synthesizing advanced spinel nanooxides with controlled crystal facets for nonprecious metal ORR electrocatalysts, emphasizing the significance of catalyst shape control.
ACS ENERGY LETTERS
(2023)