期刊
MATERIALS & DESIGN
卷 89, 期 -, 页码 1086-1094出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.matdes.2015.10.069
关键词
Hydrogen storage; Nanoporous materials; Hydrogen storage systems; Adsorption
资金
- UK Engineering and Physical Science Research Council (EPSRC) [EP/L018365/1, EP/K021109/1, EP/J016454/1]
- EPSRC Centre for Doctoral Training Centre in Sustainable Chemical Technologies at the University of Bath [EP/G03768X/1]
- Airbus Group Innovation, Munich, Germany
- University of Bath
- European Regional Development Fund (ERDF) INTERREG IV programme for Materials for Energy Efficiency in Transport (MEET)
- EPSRC [EP/J016454/1, EP/K021109/1, EP/L018365/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/L018365/1, EP/K021109/1, EP/J016454/1] Funding Source: researchfish
Current state-of-the-art methods consist of containing high-pressure compressed hydrogen in composite cylinders, with solid-state hydrogen storage materials an alternative that could improve on storage performance by enhancing volumetric densities. A new strategy that uses cryogenic temperatures to load hydrogen (cryocharging) is proposed and analysed in this work, comparing densities and final storage pressures for empty cylinders and containers with the high-surface area materials MIL-101 (Cr) and AX-21. Results show cryocharging as a viable option, as it can substantially lower the charging (at 77 K) and final pressures (at 298 K) for the majority of the cases considered. Kinetics are an equally important requirement for hydrogen storage systems, so the effective diffusivities at these conditions for both materials were calculated, and showed values comparable to the ones estimated in metal-organic frameworks and zeolites from quasielastic neutron scattering and molecular simulations. High-surface area materials tailored for hydrogen storage are a promising route for storage in mobile applications and results show that cryocharging is a promising strategy for hydrogen storage systems, since it increases volumetric densities and avoids energy penalties of operating at high pressures and/or low temperatures. (C) 2015 Elsevier Ltd. All rights reserved.
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