期刊
ORGANIC CHEMISTRY FRONTIERS
卷 3, 期 4, 页码 434-438出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qo00426h
关键词
-
资金
- National Basic Research Program of China [2015CB856600]
- National Natural Science Foundation of China [21422209, 21272255, 21432011, 21421091]
- CAS/SAFEA International Partnership Program for Creative Research Teams
A cobalt complex of iminopyridine-oxazoline catalyzes sequential hydroboration of alkyl and aryl alkynes with pinacolborane to form 1,1-diboronate esters. The reactions proceed under mild conditions with high yields, high regioselectivity, and wide functional group tolerance. The synthetic utility of 1,1-di(boronates) is demonstrated by chemoselective monoarylation and stepwise diarylation through palladium-catalyzed Suzuki-Miyaura coupling reactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据