期刊
ORGANIC CHEMISTRY FRONTIERS
卷 3, 期 8, 页码 949-952出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qo00194g
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资金
- Heinrich-Boll-Stiftung e.V.
Aromatic and heteroaromatic diazonium salts were smoothly converted into the corresponding pentafluoroethyl thioethers by reaction with Me4NSC2F5 in the presence of catalytic amounts of elemental copper. This Sandmeyer-type reaction proceeds at room temperature under mild conditions and is applicable to a wide range of functionalised molecules. It enables the late-stage introduction of pentafluoroethylthio groups, a promising but largely unexplored substituent, into bioactive molecules.
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