期刊
JOURNAL OF RENEWABLE MATERIALS
卷 4, 期 1, 页码 18-23出版社
SCRIVENER PUBLISHING LLC
DOI: 10.7569/JRM.2015.634131
关键词
Choline chloride; free-radical polymerization-crosslinking; hydrogels; phase segregation; renewable monomers
New methods of preparation of crosslinked polymers from itaconic acid as a renewable monomer have been explored. Synthesis of hydrogels and xerogels from the acid in deep eutectic solvents (DESs) are described and some basic properties of the materials are reported. Most importantly, a surfactant-free method of creation of macroporous poly(itaconic-co-bisacrylamide) by phase separation polymerization in binary mixture of the DES and poly(ethylene glycol) is demonstrated.
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