期刊
ADVANCED ELECTRONIC MATERIALS
卷 2, 期 5, 页码 -出版社
WILEY
DOI: 10.1002/aelm.201600040
关键词
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资金
- National Science Foundation (NSF) through the University of Minnesota MRSEC [DMR-1420013]
- National Natural Science Foundation of China [51336009, 51206167]
- National Science Foundation [1511195, CNS-0821794]
- C-SPIN, one of six centers of STARnet, a Semiconductor Research Corporation program - MARCO
- DARPA
- NSF through the NNIN program
- NSF through the UMN MRSEC program
- University of Colorado Boulder
- University of Colorado Denver
- National Center for Atmospheric Research
- [NSF: DMR-1334867]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1334428] Funding Source: National Science Foundation
- Directorate For Engineering
- Div Of Electrical, Commun & Cyber Sys [1351002] Funding Source: National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1334867] Funding Source: National Science Foundation
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [1512776] Funding Source: National Science Foundation
Black phosphorus (BP) has emerged as a direct bandgap semiconducting material with great application potentials in electronics, photonics, and energy conversion. Experimental characterization of the anisotropic thermal properties of BP at the micrometer scale is extremely challenging. This study reports measurement results of the anisotropic thermal conductivity of BP along three primary crystalline orientations, using a novel time-resolved magneto-optical Kerr effect. The thermal conductivity along the zigzag crystalline direction is 84-101 W m(-1) K-1, nearly three times as large as that along the armchair direction (26-36 W m(-1) K-1). The through-plane thermal conductivity of BP ranges from 4.3 to 5.5 W m(-1) K-1. This study performs first-principles calculation to predict the phonon transport in BP along both in-plane through-plane directions, and identifies that the strong anisotropy of thermal transport in BP can be attributed to the structural-asymmetry-induced group velocity variations along different crystalline orientations, and the relaxation time variation induced by the direction of the applied temperature gradient. This work successfully unveils the fundamental mechanisms of anisotropic thermal transport along the three crystalline directions in BP, as demonstrated by the excellent agreement between the first-principles-based theoretical predictions and experimental characterizations on the anisotropic thermal conductivities of BP.
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