4.5 Article

Au-NP-Decorated Crystalline FeOCl Nanosheet: Facile Synthesis by Laser Ablation in Liquid and its Exclusive Gas Sensing Response to HCl at Room Temperature

期刊

ADVANCED MATERIALS INTERFACES
卷 3, 期 9, 页码 -

出版社

WILEY-BLACKWELL
DOI: 10.1002/admi.201500801

关键词

-

资金

  1. National Basic Research Program of China (973 Program) [2011CB302103]
  2. Natural Science Foundation of China [11374303, 51531006, 11404337]

向作者/读者索取更多资源

Here an alternative preparation route, pulsed laser ablation in liquid (LAL) of FeCl3 solution, is reported to facilely synthesize crystalline iron oxychloride (FeOCl) nanosheets at ambient conditions. Well-dispersed spherical gold (Au) nanoparticles (NPs) are simultaneously decorated on surface of the FeOCl nanosheets, which possess (010) preferred orientations with micro-sized dimensions in planar and tens of nanometers in thickness. The crystalline size and composition of the Au/FeOCl can be effectively modulated by simply changing FeCl3 concentrations. Technical observations illustrate that the nanocomposites possess good thermal stability and surface of which adsorbs abundant H2O molecularly and oxygen species chemically. The FeOCl nanosheets are formed through chemical side hydrolysis reaction in the localized liquid region with gradient temperature, which is derived from thermal transfer of LAL-induced plasma plume. The Au/FeOCl nanocomposites, as chemiresistors, show exceptionally high sensing response and perfect selectivity to HCl gas at room temperature. The excellent sensing behavior is ascribed to the Au-NP-enhanced surface chemisorption of oxygen species and selective adsorption of HCl for FeOCl nanosheets. The synthesized Au/FeOCl nanocomposites provide a new candidate for exclusive HCl detection. And the proposed LAL-assisted fabrication routes might open new perspectives for formation of other metal oxychloride compounds.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.5
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Multidisciplinary

Interface and M3+/M2+ Valence Dual-Engineering on Nickel Cobalt Sulfoselenide/Black Phosphorus Heterostructure for Efficient Water Splitting Electrocatalysis

Tingting Liang, Syama Lenus, Yaoda Liu, Ya Chen, Thangavel Sakthivel, Fuyi Chen, Fei Ma, Zhengfei Dai

Summary: This paper presents a study on the fabrication of a nickel cobalt sulfoselenide/black phosphorus heterostructure for efficient water electrolysis. The heterostructure demonstrates highly active and durable performance through interface and valence dual-engineering. It achieves low overpotentials and high stability in alkaline media, showing promise for future sustainable hydrogen energy deployment.

ENERGY & ENVIRONMENTAL MATERIALS (2023)

Article Physics, Multidisciplinary

The self-assembly behavior of polymer/nanorods hybrid system under oscillation field

Kang-Ying Wang, Cai-Yuan Ma, Hui-Min Yu, Hai-Tao Zhang, Jian-Yong Cen, Ying-Ying Wang, Jun-Xing Pan, Jin-Jun Zhang

Summary: The self-assembly behavior of diblock copolymer/homopolymer/nanorods hybrid system under oscillation field is studied. The effects of the amplitude and frequency of the oscillation field on the formation and evolution of the mixture morphology are investigated. It is found that the oscillation field has an important role in the formation and transformation of the ordered structure. The addition of polymers has a combing effect and the arrangement of nanorods changes with the amplitude and frequency of the oscillation field.

ACTA PHYSICA SINICA (2023)

Review Chemistry, Multidisciplinary

Gel Electrolytes for Electrochemical Actuators and Sensors Applications

Zhenzhen Deng, Yaoda Liu, Zhengfei Dai

Summary: In this review, the authors provide an overview of the classification of gel electrolytes according to the type of medium and summarize the research progress in using gel electrolytes to fabricate electrochemical actuators. They also discuss the current advancements in using gel electrolytes in different types of electrochemical sensors. Finally, they explore the future challenges and development prospects of electrochemical actuators and sensors based on gel electrolytes. The application potential of gel electrolytes warrants further attention and will have a significant impact on human life and development.

CHEMISTRY-AN ASIAN JOURNAL (2023)

Article Biochemistry & Molecular Biology

Two-Dimensional Iron Phosphorus Trisulfide as a High-Capacity Cathode for Lithium Primary Battery

Syama Lenus, Pallavi Thakur, Sai Smruti Samantaray, Tharangattu N. Narayanan, Zhengfei Dai

Summary: Metal phosphorus trichalcogenide (MPX3) materials have attracted attention as potential host electrodes in lithium batteries due to their environment-friendliness and advantageous X-P synergic effects. Two-dimensional iron thio-phosphate (FePS3) nanoflakes were synthesized using a salt-template synthesis method, and their electrochemical application in a high-capacity lithium primary battery (LPB) demonstrated a high specific capacity, energy density, and power density. The observed discharge mechanism of the FePS3-based primary cell and the findings from post-mortem analyses provide mechanistic insight into its high capacity.

MOLECULES (2023)

Article Chemistry, Physical

Enhancing the d/p-Band Center Proximity with Amorphous-Crystalline Interface Coupling for Boosted pH-Robust Water Electrolysis

Yaoda Liu, Thangavel Sakthivel, Feng Hu, Yahui Tian, Dongshuang Wu, Edison Huixiang Ang, Hang Liu, Shengwu Guo, Shengjie Peng, Zhengfei Dai

Summary: Researchers have developed a non-precious pH-robust electrocatalyst for efficient and stable water electrolysis. This catalyst exhibits excellent catalytic activity for hydrogen and oxygen evolution reactions in alkaline electrolytes, achieving ultralow overpotentials and high OER current density.

ADVANCED ENERGY MATERIALS (2023)

Article Chemistry, Multidisciplinary

Bimetal-Incorporated Black Phosphorene with Surface Electron Deficiency for Efficient Anti-Reconstruction Water Electrolysis

Wenfang Zhai, Ya Chen, Yaoda Liu, Thangavel Sakthivel, Yuanyuan Ma, Shengwu Guo, Yongquan Qu, Zhengfei Dai

Summary: In this article, a series of affordable bimetal-incorporated black phosphorene (BP) catalysts were constructed by an in situ electro-exfoliation/insertion method for anti-SRC water electrolysis. The optimized bimetal-BP structures displayed excellent and stable catalytic performances in hydrogen evolution (HER) and oxygen evolution (OER) reactions. The anti-SRC behaviors were elucidated by in situ Raman studies during HER/OER, suggesting a balanced electron transfer pathway on Ni sites.

ADVANCED FUNCTIONAL MATERIALS (2023)

Correction Behavioral Sciences

Inhibition of Piezo1/Ca(2+)/calpain signaling in the rat basal forebrain reverses sleep deprivation-induced fear memory impairments (vol 417, 113594, 2022)

Tao Ma, Ying-Ying Wang, Yan Lu, Long Feng, Yi-Tian Yang, Guan-Hua Li, Chi Li, Yang Chu, Wei Wang, Hao Zhang

BEHAVIOURAL BRAIN RESEARCH (2023)

Article Chemistry, Physical

Lithium-ion insertion properties of one-dimensional layered rhenium phosphide

Penglun Zheng, Xiaoli Sun, Yaoda Liu, Zhifa Li, Quanyi Liu, Yun Zheng, Zhengfei Dai

Summary: In this work, the metal phosphide Re6P13 was synthesized and used as an anode material for lithium-ion batteries (LIBs) for the first time. The Re6P13 @C composite electrode showed excellent electrical conductivity, high specific capacity (1265 mAh/g at 0.1 A g-1), good cycling life (775 mAh/g at 1 A g-1 after 100 cycles), and rate performance (558 mAh/g at 20 A g-1), making it a promising anode material for LIBs.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Medicine, General & Internal

Efficacy of the enhanced recovery after surgery protocol in operating room nursing of patients following single-port video-assisted thoracoscopic lung cancer surgery: A retrospective study

Lijun Wei, Yingying Wang

Summary: This study assessed the efficacy of the enhanced recovery after surgery (ERAS) protocol in operating room nursing care for patients who underwent single-port video-assisted thoracoscopic lung cancer surgery. The study compared the outcomes of patients who received nursing care under the ERAS protocol and those who had routine nursing care. The results showed that the ERAS protocol significantly improved postoperative recovery, reduced complications, and improved psychological well-being in patients undergoing single-port video-assisted thoracoscopic lung cancer surgery.

MEDICINE (2023)

Article Chemistry, Multidisciplinary

Enlarging the Ni-O Bond Polarizability in a Phosphorene-Hosted Metal-Organic Framework for Boosted Water Oxidation Electrocatalysis

Wenfang Zhai, Ya Chen, Yaoda Liu, Thangavel Sakthivel, Yuanyuan Ma, Yuanbin Qin, Yongquan Qu, Zhengfei Dai

Summary: A Ni metal-organic framework/black phosphorene heterostructure is used to optimize the performance of oxygen evolution reaction (OER). The p-type black phosphorene host increases the Ni-O bond polarizability of NiMOF, allowing for enhanced LOM pathway and OER performance. Experimental and computational results demonstrate the activated LOM pathway with a more balanced step barrier in the NiMOF/BP OER catalyst.

ACS NANO (2023)

Article Chemistry, Physical

Surpassing Pt hydrogen production from {200} facet-riched polyhedral Rh2P nanoparticles by one-step synthesis

Hongqiang Xin, Lan Sun, Yiwei Zhao, Zhengfei Dai, Qiaomei Luo, Shengwu Guo, Danyang Li, Ya Chen, Naoki Ogiwara, Hiroshi Kitagawa, Bo Huang, Fei Ma

Summary: Polyhedral-morphology controlled rhodium phosphide (Rh2P) nano-particles with dominant {200} facets exhibit high catalytic activity in water electrolysis, even superior to Pt/C catalyst. The exposure of {200} facets is advantageous for the catalytic performance of Rh2P NPs.

APPLIED CATALYSIS B-ENVIRONMENTAL (2023)

Review Chemistry, Multidisciplinary

Recent Advancements of Graphene-Based Materials for Zinc-Based Batteries: Beyond Lithium-Ion Batteries

Marliyana Aizudin, Wangqin Fu, Rafeeque Poolamuri Pottammel, Zhengfei Dai, Huanwen Wang, Xianhong Rui, Jixin Zhu, Cheng Chao Li, Xing-Long Wu, Edison Huixiang Ang

Summary: Graphene-based materials (GBMs) have unique properties that make them a promising choice for rechargeable battery electrodes. The development of lithium-ion batteries (LIBs) has been limited by lithium resources, high costs, and safety concerns, leading to the exploration of zinc-based alternatives. This review highlights recent advancements in GBMs and their composites for potential applications in various rechargeable batteries.
Review Nanoscience & Nanotechnology

Review of Mott-Schottky-Based Nanoscale Catalysts for Electrochemical Water Splitting

Moorthy Krishnamachari, Syama Lenus, K. Pradeeswari, R. Arun Pandian, Mohanraj Kumar, Jih-Hsing Chang, Senthil Pandian Muthu, Ramasamy Perumalsamy, Zhengfei Dai, Paranthaman Vijayakumar

Summary: Fundamental structural modification techniques of nanomaterials can be used to control the electronic structure of active sites and improve electrocatalytic activities. Appropriate surface reconstruction is necessary to overcome large electrochemical overpotential. Understanding fundamental structural modification mechanisms, such as the Janus structure, spillover effect, d-band center shift theory, and interfacial coupling, is essential. The Mott-Schottky (M-S) effect is a fundamental interface and valence engineering strategy that has gained interest recently due to its ability to enable mass transport, regulate the density of states, enable rapid electron transfer via band bending, and create a synergistic effect at the metal-semiconductor interface.

ACS APPLIED NANO MATERIALS (2023)

Review Chemistry, Multidisciplinary

Shining light on layered metal phosphosulphide catalysts for efficient water electrolysis: preparation, promotion strategies, and perspectives

Sijia Zhao, Ya Chen, Yaoda Liu, Jun Cheng, Zhengfei Dai

Summary: Electrocatalytic water splitting is important for producing clean hydrogen energy to mitigate the energy crisis and reduce pollution. Layered metal phosphosulphides (MPS3) have attracted significant interest in the catalytic community, but their low intrinsic activity hinders their application as efficient electrocatalysts for water splitting. Strategies such as exfoliation, doping, and heterojunction construction have been proposed to enhance the performance of MPS3-based electrocatalysts. This review provides guidance for the design and development of advanced electrocatalysts for hydrogen production.

GREEN CHEMISTRY (2023)

Article Chemistry, Multidisciplinary

Macroporous SnO2/MoS2 inverse opal hierarchitecture for highly efficient trace NO2 gas sensing

Hang Liu, Ying Zhao, Yaoda Liu, Tingting Liang, Yahui Tian, Thangavel Sakthivel, Shengjie Peng, Soo Young Kim, Zhengfei Dai

Summary: A macroporous SnO2/MoS2 inverse opal hierarchitecture has been developed for the efficient detection of NO2 gas, showing enhanced response, fast kinetics, and high selectivity at low temperatures.

CHEMICAL COMMUNICATIONS (2023)

暂无数据