期刊
ACS PHOTONICS
卷 3, 期 9, 页码 1589-1595出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsphotonics.6b00062
关键词
DNA origami; plasmonic heterodimers; hybridization; self-assembly
类别
资金
- ERC Starting Grant Passmembrane [261101]
- Janggen-Pohn-Stiftung and the Schweizerischer Nationalfonds (SNF)
- EPSRC [EP/G060649/1, EP/L027151/1, EP/K028510/1]
- ERC LINASS [320503]
- EPSRC [EP/L027151/1, EP/G060649/1, EP/K028510/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K028510/1, EP/G060649/1, EP/L027151/1] Funding Source: researchfish
We fabricate heterocomponent dimers built from a single 40 nm gold and a single 40 nm silver nanoparticle separated by sub-5 nm gaps. Successful assembly mediated by a specialized DNA origami platform is verified by scanning electron microscopy and energy-dispersive X-ray characterization. Dark-field optical scattering on individual dimers is consistent with computational simulations. Direct plasmonic coupling between each nanoparticle is observed in both experiment and theory only for these small gap sizes, as it requires the silver dipolar mode energy to drop below the energy of the gold interband transitions. A new interparticle-spacing-dependent coupling model for heterodimers is thus required. Such Janus-like nanoparticle constructs available from DNA-mediated assembly provide an effective tool for controlling symmetry breaking in collective plasmon modes.
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