4.8 Article

Rice-straw-derived hybrid TiO2-SiO2 structures with enhanced photocatalytic properties for removal of hazardous dye in aqueous solutions

期刊

NANO ENERGY
卷 20, 期 -, 页码 76-83

出版社

ELSEVIER
DOI: 10.1016/j.nanoen.2015.07.032

关键词

TiO2-SiO2 structure; Rice straw; Photocatalytic reaction; Methylene blue; Biotemplate

资金

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [NRF-2013R1A6A3A03021144]

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Rice straw, an agricultural bioresource, is utilized as a biotemplate in order to synthesize a hybrid TiO2-SiO2 structure, and the resulting products were used for removing hazardous methylene blue dye from aqueous solutions. Samples of the as-prepared hybrid TiO2-SiO2 structure are characterized by thermal gravity analysis, field emission scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen gas adsorption/desorption measurement, and UV/vis spectroscopy. The results obtained show that the hybrid TiO2-SiO2 structure possesses both anatase and rutile phases, along with amorphous SiO2. Its specific surface area is determined to be 141.1 m(2)/g, and its pore size to be 3.77 nm. Light harvesting within the visible-light range is found to be enhanced by the use of this hybrid TiO2-SiO2 structure. Moreover, the photocatalytic activity and stability are also improved, as demonstrated by the degradation of methylene blue dye under UV irradiation. (C) 2015 Elsevier Ltd. All rights reserved.

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