4.8 Article

Ultrahigh efficient water oxidation under visible light: Using Fe dopants to integrate nanostructure and cocatalyst in LaTiO2N system

期刊

NANO ENERGY
卷 19, 期 -, 页码 437-445

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2015.10.017

关键词

Water oxidation; LaTiO2N; Nanostructure; Cocatalyst; Dopant

资金

  1. National Natural Science Foundation of China [51572239, 51372224]
  2. Program for Innovative Research Team in University of Ministry of Education of China [IRT13037]
  3. National Science and Technology Support Program [2012BAC08B08]

向作者/读者索取更多资源

Solar light driven water oxidation is the key raction for artificial photocatalysis. The light driven water oxidation on LaTiO2N nanostructures do not exhibit high efficiency. In this work, we design a new strategy that using the Fe dopants, which could create empty mid -gap states, to tune the energy band matching between the cocatalysts and LaTiO2N nanostructures. This strategy significantly increase the photo-generated carriers' separation and it makes the CoO/Fe doped LaTiO2N nanostructures show 55% quantum efficiency for O-2 generation under visible light irradiation. (C) 2015 Elsevier Ltd. All rights reserved.

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