Article
Chemistry, Multidisciplinary
Tianyi Guo, Anastasiia Svanidze, Xiaoyu Zheng, Peter Palffy-Muhoray
Summary: Photomechanical materials, such as liquid crystalline azo-acrylate networks, show different photoresponse regimes depending on the intensity of illumination. The characteristic intensity of the material determines the boundaries between these regimes.
APPLIED SCIENCES-BASEL
(2022)
Article
Chemistry, Multidisciplinary
Jinyu Sheng, Wojciech Danowski, Stefano Crespi, Ainoa Guinart, Xiaobing Chen, Cosima Stahler, Ben L. L. Feringa
Summary: Overcrowded alkene based molecular motors and switches, due to their intrinsic chirality near the core CC bond, are highly suitable for constructing light-switchable dynamic systems. However, the lack of design principles and challenging synthesis hinders their full exploitation. Therefore, systematic investigations of key parameters are crucial for further development. This study provides an alternative synthetic route, elucidates the influence of substituents on the photochemistry, and establishes a structure-property relationship for tailored design of photochromes.
Article
Materials Science, Multidisciplinary
Jisoo Jeon, Jun-Chan Choi, Hyeok Lee, Woongbi Cho, Kwangseok Lee, Jae Gwang Kim, Jae-Won Lee, Kyung-Il Joo, Maenghyo Cho, Hak-Rin Kim, Jeong Jae Wie
Summary: This study reports the continuous photomechanical jumping of polymer monoliths with on-demand height and angle programmability, utilizing self-assembled azobenzene-functionalized liquid crystalline polymers for jumping action, achieving a maximum jumping height of 15.5 body lengths.
Article
Crystallography
Adam J. Berges, Wangxiang Li, Wenwen Xu, Fei Tong, Rabih O. Al-Kaysi, Ryan C. Hayward, Christopher J. Bardeen
Summary: This paper investigates the growth of 9-methylanthracene nanowires in anodic aluminum oxide templates and explores the potential of utilizing crystal expansion for generating motion. The study reveals that incomplete filling, crystal orientation, and debris on the template surface may hinder the observation of vertical actuation.
Article
Chemistry, Multidisciplinary
Willibald J. Stockerl, Ruth M. Gschwind
Summary: This article describes the observation and assignment of high energetic (Z)-configured intermediates in imidazolidinone iminium ions through in situ photoisomerization. Stabilization conditions for (E,Z) and (Z,Z) isomers were also determined.
CHEMICAL COMMUNICATIONS
(2023)
Article
Biochemistry & Molecular Biology
Marco Marazzi, Cristina Garcia-Iriepa, Carlos Benitez-Martin, Francisco Najera, Antonio Monari, Diego Sampedro
Summary: Studying photoswitches activated by two-photon absorption (TPA) reveals that protonated Schiff-bases (retinal)-like photoswitches outperform other families, with theoretical predictions suggesting potential applications in optogenetics.
Article
Chemistry, Multidisciplinary
Zouheir Sekkat
Summary: Photoactive polymers play a crucial role in various areas of photonics, including data storage, holography, nonlinear optics, and photomechanics. Photomechanics, in particular, is an important application where these materials convert light energy into mechanical motion. This paper presents a novel model that predicts the generation of mechanical pressure through photo-induced changes in the volume and length of anisometric isomers, and provides simple analytical expressions to describe the dynamics of volume and strain changes when photomechanic samples are irradiated with polarized light.
APPLIED SCIENCES-BASEL
(2023)
Article
Chemistry, Multidisciplinary
Pankaj Bharmoria, Shima Ghasemi, Fredrik Edhborg, Raul Losantos, Zhihang Wang, Anders Martensson, Masa-aki Morikawa, Nobuo Kimizuka, Umit Isci, Fabienne Dumoulin, Bo Albinsson, Kasper Moth-Poulsen
Summary: We report the first example of direct far-red triplet sensitized molecular photoswitching in a condensed phase, demonstrating new biosustainable fabrication designs to address key challenges in solid-state photoswitching.
Article
Chemistry, Multidisciplinary
Pierre Hansjacob, Frederic R. Leroux, Morgan Donnard
Summary: The research reports a fully selective Zn-catalyzed hydrocyanation of ynamides, allowing the synthesis of various trisubstituted E-alpha-enamidonitriles. The catalyst-free photoisomerization results in the energetically comparable Z-stereoisomer. Furthermore, the synthetic potential of these newly synthesized alpha-enamidonitriles is evaluated through the synthesis of original heterocycles.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Inorganic & Nuclear
Yun-Rui Chen, Meng-Ze Jia, Jia-Qi Pan, Bin Tan, Jie Zhang
Summary: In this study, photoinduced bending behavior triggered by [2 + 2] cycloaddition of a photoactive complex was successfully achieved, accompanied by photochromic and fluorescence changes. The introduction of flexible methylene groups and cation-pi interactions provided convenience for long-distance observation of photomechanical motion.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Physical
Nadja K. Singer, Katharina Schloegl, J. Patrick Zobel, Marko D. Mihovilovic, Leticia Gonzalez
Summary: Understanding the thermal isomerization mechanism of azobenzene derivatives is crucial for designing photoswitches with adjustable half-lives. Through quantum chemical calculations, nonadiabatic transition state theory, and photosensitized experiments, we unravel the thermal Z/E isomerization of a heteroaromatic azoswitch, phenylazo-1,3,5-trimethylpyrazole, and predict two pathways at room temperature, involving different reaction mechanisms and spin-orbit couplings.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Chemistry, Physical
Eleanor K. Ashworth, Neville J. A. Coughlan, W. Scott Hopkins, Evan J. Bieske, James N. Bull
Summary: This study investigates the wavelength-dependent bifurcation phenomenon in deprotonated 4-hydroxybenzal acetone (pCK(-)) using photoisomerization and photodissociation action spectroscopies. The results reveal that autodetachment occurs across the entire 370-480 nm band, while E -> Z photoisomerization only occurs in the blue portion of the band (370-430 nm). Furthermore, the rate of E -> Z photoisomerization is affected by the different functional groups and the barrier height in the gas phase compared to solution.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Chemistry, Physical
Eleanor K. Ashworth, Neville J. A. Coughlan, W. Scott Hopkins, Evan J. Bieske, James N. Bull
Summary: This article investigates the photophysical behavior of molecules based on the deprotonated p-hydroxycinnamate moiety, revealing a wavelength-dependent bifurcation between photoisomerization and electron autodetachment. Potential energy surface calculations indicate the presence of a barrier between the Franck-Condon region and the isomerizing conical intersection.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Review
Chemistry, Applied
Javier Corpas, Pablo Mauleon, Ramon Gomez Arrayas, Juan C. Carretero
Summary: The stereoselective photoisomerization of olefins via Energy Transfer (EnT) sensitization has significant potential in designing catalytic stereodivergent methodologies. EnT catalysis has emerged as a powerful tool for olefin geometry control, with high functional group tolerance and multicatalytic compatibility.
ADVANCED SYNTHESIS & CATALYSIS
(2022)
Article
Chemistry, Multidisciplinary
Thomas J. Gately, Watit Sontising, Connor J. Easley, Imadul Islam, Rabih O. Al-Kaysi, Gregory J. O. Beran, Christopher J. Bardeen
Summary: 9-Anthracene carboxylic acid derivatives form a family of thermally reversible photomechanical molecular crystals, with steric interactions playing a dominant role in photodimer formation and an energetic threshold of 80-90 kJ per mole for the dimerization reaction. Fluorinated 9ACs exhibit absent intermolecular bonding, explaining observed trends in dissociation kinetics and mechanical reset times. Photodimer dissociation kinetics depend on the initial photodimer amount, leading to a complex relationship between halogen atom substitution and dissociation rates.
Article
Chemistry, Multidisciplinary
Fei Tong, Wangxiang Li, Zhiwei Li, Imadul Islam, Rabih O. Al-Kaysi, Christopher J. Bardeen
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Article
Chemistry, Multidisciplinary
Fei Tong, Daichi Kitagawa, Ibraheem Bushnak, Rabih O. Al-Kaysi, Christopher J. Bardeen
Summary: This study demonstrates that (Z)-DVAM molecular crystalline microwires can exhibit continuous oscillatory motion when exposed to a combination of ultraviolet and visible light, mimicking the behavior of biological flagella. This is the first example of molecular crystals showing complex oscillatory behavior under continuous irradiation, with rotational frequency depending on light intensity and polarization.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Crystallography
Adam J. Berges, Wangxiang Li, Wenwen Xu, Fei Tong, Rabih O. Al-Kaysi, Ryan C. Hayward, Christopher J. Bardeen
Summary: This paper investigates the growth of 9-methylanthracene nanowires in anodic aluminum oxide templates and explores the potential of utilizing crystal expansion for generating motion. The study reveals that incomplete filling, crystal orientation, and debris on the template surface may hinder the observation of vertical actuation.
Article
Chemistry, Multidisciplinary
Thomas J. Gately, Cameron Cook, Raghad Almuzarie, Imadul Islam, Zachary Gardner, Robbie J. Iuliucci, Rabih O. Al-Kaysi, Gregory J. O. Beran, Christopher J. Bardeen
Summary: This paper explores the effects of fluorine substitution on the molecular properties, crystal packing, and solid-state photochemical reactivity of Cinnamalmalononitrile (CM) derivatives. The addition of fluorines shifts the molecular energy gap and enables polymorphism, altering the polymorph landscape and energetics. Experimental and computational results illustrate how even minor modifications to the molecular structure can significantly impact crystal structures and photomechanical behavior.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Chemistry, Multidisciplinary
Cameron J. Cook, Wangxiang Li, Brandon F. Lui, Thomas J. Gately, Rabih O. Al-Kaysi, Leonard J. Mueller, Christopher J. Bardeen, Gregory J. O. Beran
Summary: This study presents a new computational framework for predicting photomechanical transformations in solid-state crystals and establishes a photomechanical engine cycle that quantifies the mechanical performance resulting from the transformation. The approach relies on crystal structure prediction, solid-state topochemical principles, and high-quality electronic structure methods. The study validates the framework on two well-studied systems and predicts the experimentally-unknown solid-state transformation of another system. The results highlight the importance of crystal packing in determining molecular crystal engine performance and demonstrate the potential of photomechanical crystal engines.
Editorial Material
Crystallography
Fei Tong, Rabih O. O. Al-Kaysi, Daichi Kitagawa
Article
Crystallography
Yuhao Li, Peiyao Wang, Zhongzhao Duan, Tianle Zhang, Fei Tong
Summary: In this study, fluorescent hollow organic molecular cocrystals were prepared using a surfactant-mediated co-precipitation method. The size and morphology of the cocrystals could be easily controlled by adjusting the surfactant type, concentration, incubation time, and temperature. The cocrystals exhibited high crystallinity and contained two symmetric empty cavities when a specific surfactant was used. Additionally, the cocrystals emitted bright red luminescence with a strong charge-transfer property.
Review
Chemistry, Multidisciplinary
Wegood M. Awad, Daniel W. Davies, Daichi Kitagawa, Jad Mahmoud Halabi, Marieh B. Al-Handawi, Ibrahim Tahir, Fei Tong, Gonzalo Campillo-Alvarado, Alexander G. Shtukenberg, Tamador Alkhidir, Yuki Hagiwara, Mubarak Almehairbi, Linfeng Lan, Shodai Hasebe, Durga Prasad Karothu, Sharmarke Mohamed, Hideko Koshima, Seiya Kobatake, Ying Diao, Rajadurai Chandrasekar, Hongyu Zhang, Changquan Calvin Sun, Christopher Bardeen, Rabih O. Al-Kaysi, Bart Kahr, Pance Naumov
Summary: Molecular crystals have diverse physical properties and can be studied by responding to electric, magnetic, and light fields. The mechanical properties of molecular crystals enhance our understanding of weakly bound molecules under internal and external forces. The importance of mechanical properties to practical applications and the need for improvement in measurement techniques and conceptual tools are emphasized.
CHEMICAL SOCIETY REVIEWS
(2023)
Article
Chemistry, Physical
Arshad Khan, Ibraheem Bushnak, Zhouyu Jiang, Rabia Usman, Prafulla B. Choudhari, Chao Feng, Rabih O. Al-Kaysi, Faiz-Ur Rahman
Summary: In recent years, the collaboration of macrocyclic chemistry and co-crystal engineering has rapidly advanced for the creation of functional solid-state materials. In this study, a novel jellyfish-like co-crystal structure was constructed by precise engineering of supramolecular interactions, guiding future endeavors in the design of supramolecular interactions and development of promising novel functional materials.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Multidisciplinary
Thomas J. Gately, Watit Sontising, Connor J. Easley, Imadul Islam, Rabih O. Al-Kaysi, Gregory J. O. Beran, Christopher J. Bardeen
Summary: 9-Anthracene carboxylic acid derivatives form a family of thermally reversible photomechanical molecular crystals, with steric interactions playing a dominant role in photodimer formation and an energetic threshold of 80-90 kJ per mole for the dimerization reaction. Fluorinated 9ACs exhibit absent intermolecular bonding, explaining observed trends in dissociation kinetics and mechanical reset times. Photodimer dissociation kinetics depend on the initial photodimer amount, leading to a complex relationship between halogen atom substitution and dissociation rates.
Article
Chemistry, Multidisciplinary
Kevin R. Chalek, Xinning Dong, Fei Tong, Ryan A. Kudla, Lingyan Zhu, Adam D. Gill, Wenwen Xu, Chen Yang, Joshua D. Hartman, Alvicler Magalhaes, Rabih O. Al-Kaysi, Ryan C. Hayward, Richard J. Hooley, Gregory J. O. Beran, Christopher J. Bardeen, Leonard J. Mueller
Summary: The study demonstrates how a novel combination of techniques including ensemble oriented-crystal solid-state NMR, X-ray diffraction, and first principles computational modeling can establish the atomic-resolution mechanism for the photomechanical response of crystals composed of photoreactive molecules. The model constructed based on these techniques accurately predicts the elongation of the crystal nanorods. Understanding how molecular-level photochemistry generates mechanical displacements allows for the tuning of the expansion of the nanorods by controlling the initial orientation of the unit cell, offering new insights into the relationship between atomic-level structural rearrangement and mechanical response in nanostructured samples.
Article
Materials Science, Multidisciplinary
Mengjiao Dong, Liyun Liao, Chensheng Li, Yingxiao Mu, Yanping Huo, Zhong-Min Su, Fushun Liang
Summary: This study investigates the influence of the polarity of polymer matrices on persistent room-temperature phosphorescence (pRTP). It is discovered that intense phosphorescence emission can be achieved in highly polar matrices such as polyacrylic acid (PAA). The dipole-dipole interaction between the polar fluorophore and polar matrix is proposed to stabilize the excited state and facilitate the generation of efficient room-temperature phosphorescence emissions.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Han-Jiang Yang, Weijia Xiang, Xiangzhou Zhang, Jin-Yun Wang, Liang-Jin Xu, Zhong-Ning Chen
Summary: This article reports a 2D copper(I)-based cluster material for X-ray imaging, which exhibits ultra-high spatial resolution, high photoluminescence efficiency, and low detection limit. The material shows excellent linear response to X-ray dose rates and light output, and has the best spatial resolution among reported lead-free metal halide hybrids.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Review
Materials Science, Multidisciplinary
Taek Joon Kim, Sang-hun Lee, Dayeong Kwon, Jinsoo Joo
Summary: Donor-acceptor heterostructures using organic-inorganic halide perovskites, two-dimensional transition metal dichalcogenides, pi-conjugated organic small/macro molecules, and quantum dots are promising platforms for exciton-based photonics and optoelectronics. Hetero-interlayer excitons and hetero-intermolecular excitons formed through optical and/or electrical charge transfer in various heterostructures are important quasi-particles for light emission, detection, and harvesting systems.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Liemao Cao, Xiaohui Deng, Zhen-kun Tang, Rui Tan, Yee Sin Ang
Summary: We investigate the interface properties between WSi2N4 and Mo2B, O-modified Mo2B, and OH-modified Mo2B nanosheets. We find that WSi2N4 and Mo2B form n-type Schottky contacts, while functionalizing Mo2B with O and OH leads to the formation of both n-type and p-type ohmic contacts with WSi2N4. Additionally, we demonstrate the emergence of quasi-ohmic contact with ultralow lateral Schottky barrier and zero vertical interfacial tunneling barriers in Mo2B(OH)2-contacted WSi2N4.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Ga Eun Kim, Hae-Jin Kim, Heesuk Jung, Minwoo Park
Summary: This study presents a solution to the commercialization challenges of flexible LEDs based on MAPbBr(3) by incorporating polyurethane and an In-Ga-Zn-Sn liquid alloy. The designed devices showed high flexibility, efficiency, and durability, with improved electron injection and reduced defects, making them promising for next-generation displays.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Tao Shen, Zeng Wu, Zhen Jiang, Dongsheng Yan, Yan Zhao, Yang Wang, Yunqi Liu
Summary: Sidechain engineering is an important molecular design strategy for tuning the solid-state packing and structural ordering of conjugated polymers. The effects of sidechain direction on the optoelectronic properties of polymers and device performance were systematically investigated in this study. The results demonstrate that tuning the sidechain substitution direction can effectively improve the molecular structure and light absorption properties of polymers, providing new insights for the rational design of functional polymers.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Lotte Clinckemalie, Bapi Pradhan, Roel Vanden Brande, Heng Zhang, Jonathan Vandenwijngaerden, Rafikul Ali Saha, Giacomo Romolini, Li Sun, Dirk Vandenbroucke, Mischa Bonn, Hai I. Wang, Elke Debroye
Summary: In this study, a facile strategy using a non-conductive polymer was proposed to fabricate stable, pinhole-free thick films. The effect of introducing a second phase into CsPbBr3 perovskite crystals on their photophysical properties and charge transport was investigated. The dual phase devices exhibited improved stability and more effective operation at higher voltages in X-ray detection.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Jingye Zou, Shenglan Hao, Pascale Gemeiner, Nicolas Guiblin, Omar Ibder, Brahim Dkhil, Charles Paillard
Summary: When rare-earth ions are embedded in a ferroelectric material, their photoluminescence can serve as an all-optical probe for temperature, electric field, and mechanical stimulus. However, the impact of ferroelectric phase transitions on photoluminescence is not well understood. In this study, we demonstrate changes in the photoluminescence of green emission bands during critical ferroelectric transitions in an Er-doped BaTiO3 material. We also find that the intensity ratio and wavelength position difference of sub-peaks provide information on the phase transitions.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Jiangchao Han, Daming Zhou, Wei Yang, Chen Lv, Xinhe Wang, Guodong Wei, Weisheng Zhao, Xiaoyang Lin, Shengbo Sang
Summary: Rare type-II spin-gapless semiconductors (SGSs) have attracted increasing attention due to their unique spin properties. In this study, the interface contacts and spin transport properties of different devices composed of VSi2P4 ferromagnetic layers were investigated. The results show that VSi2P4 is a promising material for designing vertical van der Waals heterostructures with a giant tunnel magnetoresistance (TMR) in spintronic applications.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Tianqi Zhao, Renagul Abdurahman, Qianting Yang, Ruxiangul Aiwaili, Xue-Bo Yin
Summary: In this study, we designed and prepared Cr and Ba-doped gamma-Ga2O3 nanoparticles to achieve near-infrared emission and enhance the emission intensity. The emission mechanism was proposed based on the trap depth, band gap, and energy levels of Cr ions. The ratiometric temperature sensing and encryption information transfer demonstrated the potential applications of this technology.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Shuvankar Gupta, Jyotirmoy Sau, Manoranjan Kumar, Chandan Mazumdar
Summary: In this study, a new spin-gapless semiconductor material CoFeMnSn is reported, and its stable structure and spin-polarized band structure are determined through experimental realization and theoretical calculations. The compound exhibits a high ferromagnetic transition temperature, making it excellent for room temperature applications. The nearly temperature-independent resistivity, conductivity, and carrier concentration of the compound, adherence to the Slater-Pauling rule, and the high intrinsic anomalous Hall conductivity achieved through hole doping further confirm its spin-gapless semiconductor nature. Additionally, the compound's SGS and topological properties make it suitable for spintronics and magneto-electronics devices.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Ikumi Aratani, Yoji Horii, Yoshinori Kotani, Hitoshi Osawa, Hajime Tanida, Toshiaki Ina, Takeshi Watanabe, Yohko F. Yano, Akane Mizoguchi, Daisuke Takajo, Takashi Kajiwara
Summary: In this study, two-dimensional arrays of single-molecule magnets (SMMs) based on metal-organic frameworks (MOFs) were systematically modified through Langmuir-Blodgett methods and chemical modifications. The introduction of bulky alkoxide groups induced structural changes and perpendicular magnetic anisotropy. This research provides a promising strategy for the construction of high-density magnetic memory devices using molecular spintronics.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Zonghao Lei, Houhe Dong, Lijie Sun, Bing Teng, Yanfei Zou, Degao Zhong
Summary: Researchers have successfully developed four different up-conversion phosphors based on the Eulytite-type host Ba3Yb(PO4)(3). The optical temperature sensing properties of these phosphors were thoroughly investigated, and it was found that Ba3Yb(PO4)(3):Tm/Er/Ho showed potential for optical temperature measurement applications.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
C. Roncero-Barrero, M. A. Carvajal, J. Ribas-Arino, I. de P. R. Moreira, M. Deumal
Summary: This study computationally investigates the conductivity of four isostructural compounds with different Se contents, and reveals the parameters that define their conductivity in stable organic radical materials. The results provide insights into the influence of Se content on the conductivity and highlight the importance of considering multiple parameters in understanding the trends in conductivity.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Remi Arras, Kedar Sharma, Lionel Calmels
Summary: In this study, we investigated the interplay between structural defects in NiFe2O4, showing that the complex formed by a Ni-Oh/Fe-Td-cation swap and a neutral oxygen vacancy is more stable than these two isolated defects, and significantly reduces the width of the minority-spin band gap.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)