Utilization of Non-Innocent Redox Ligands in [FeFe] Hydrogenase Modeling for Hydrogen Production

Synthetic Advances Inspired by the Bioactive Dinitrosyl Iron Unit

(2015) Randara Pulukkody et al.   ACCOUNTS OF CHEMICAL RESEARCH

Redox Communication within Multinuclear Iron-Sulfur Complexes Related to Electronic Interplay in the Active Site of [FeFe]Hydrogenase

(2015) Kai-Ti Chu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselectivity in Ligand Substitution Reactions on Diiron Complexes Governed by Nucleophilic and Electrophilic Ligand Properties

(2015) Ryan D. Bethel et al.   INORGANIC CHEMISTRY

Synthesis and photo-catalytic H 2 evolution of three novel biomimetic photocatalysts based on [FeFe]-Hases model compound

(2015) Hui-Qin Zheng et al.   JOURNAL OF POWER SOURCES

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Investigations on the Role of Proton-Coupled Electron Transfer in Hydrogen Activation by [FeFe]-Hydrogenase

(2014) David W. Mulder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Production Catalyzed by Bidirectional, Biomimetic Models of the [FeFe]-Hydrogenase Active Site

(2014) James C. Lansing et al.   ORGANOMETALLICS

1,1′-bis(diphenylphosphino)ferrocene as an intramolecular or intermolecular bridging ligand related to the phenyl-functionalized diiron propanedithiolate complex: synthesis and catalysis of the reduction of protons

(2014) Chang-Gong Li et al.   TRANSITION METAL CHEMISTRY

Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

(2013) Shishir Ghosh et al.   CHEMICAL COMMUNICATIONS

Synthesis and characterization of [FeFe]-hydrogenase mimics appended with a 2-phenylazopyridine ligand

(2013) Raphael A. Seidel et al.   Journal of Sulfur Chemistry

Redox Chemistry of Noninnocent Quinones Annulated to 2Fe2S Cores

(2013) Gabriel B. Hall et al.   ORGANOMETALLICS

Identification and Characterization of the “Super-Reduced” State of the H-Cluster in [FeFe] Hydrogenase: A New Building Block for the Catalytic Cycle?

(2012) Agnieszka Adamska et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biomimetic model for [FeFe]-hydrogenase: asymmetrically disubstituted diiron complex with a redox-active 2,2′-bipyridyl ligand

(2012) Souvik Roy et al.   DALTON TRANSACTIONS

1,2-Ene dithiolate bridged diiron carbonyl-phosphine and -phosphite complexes in relevance to the active site of [FeFe]-hydrogenases: Synthesis, characterization and electrocatalysis

(2012) Gummadi Durgaprasad et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Structural and Spectroscopic Features of Mixed Valent FeIIFeI Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase

(2012) Chung-Hung Hsieh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evolution in the understanding of [Fe]-hydrogenase

(2011) Michael J. Corr et al.   CHEMICAL SOCIETY REVIEWS

Photoinitiated multistep charge separation in ferrocene–zinc porphyrin–diiron hydrogenase model complex triads

(2011) Premaladha Poddutoori et al.   Energy & Environmental Science

Synthesis, structural characterization and electrochemical studies of [Fe2(μ-L)(CO)6] and [Fe2(μ-L)(CO)5(PPh3)] (L = pyrazine-2,3-dithiolate, quinoxaline-2,3-dithiolate and pyrido[2,3-b]pyrazine-2,3-dithiolate): Towards modeling the active site of [FeFe]–Hydrogenase

(2011) Gummadi Durgaprasad et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Mechanistic and Physiological Implications of the Interplay among Iron–Sulfur Clusters in [FeFe]-Hydrogenases. A QM/MM Perspective

(2011) Claudio Greco et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

(2011) James M. Camara et al.   Nature Chemistry

Non-innocent ligands in bioinorganic chemistry—An overview

(2010) Wolfgang Kaim et al.   COORDINATION CHEMISTRY REVIEWS

Ultrafast Photodriven Intramolecular Electron Transfer from a Zinc Porphyrin to a Readily Reduced Diiron Hydrogenase Model Complex

(2010) Amanda P. S. Samuel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Diiron Hydrogenase Mimics Bearing Hydroquinone and Related Ligands. Electrochemical and Computational Studies of the Mechanism of Hydrogen Production and the Role of O−H···S Hydrogen Bonding†

(2010) Jinzhu Chen et al.   ORGANOMETALLICS

Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases†

(2009) Cédric Tard et al.   CHEMICAL REVIEWS

Mechanistic Insight into Formation of Oxo-Iron(IV) Porphyrin π-Cation Radicals from Enzyme Mimics of Cytochrome P450 in Organic Solvents

(2009) Natalya Hessenauer-Ilicheva et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diiron Proton Reduction Catalysts Possessing Electron-Rich and Electron-Poor Naphthalene-1,8-dithiolate Ligands

(2009) Robert J. Wright et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electronic and geometric effects of phosphatriazaadamantane ligands on the catalytic activity of an [FeFe] hydrogenase inspired complex

(2009) Aaron K. Vannucci et al.   DALTON TRANSACTIONS

The crystal structure of C176A mutated [Fe]-hydrogenase suggests an acyl-iron ligation in the active site iron complex

(2009) Takeshi Hiromoto et al.   FEBS LETTERS

Modeling [FeFe] hydrogenase: Synthesis and protonation of a diiron dithiolate complex containing a phosphine-N-heterocyclic-carbene ligand

(2009) Didier Morvan et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Isolation and first EPR characterization of the [FeFe]-hydrogenases from green algae

(2008) Christina Kamp et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Small molecule mimics of hydrogenases: hydrides and redox

(2008) Frédéric Gloaguen et al.   CHEMICAL SOCIETY REVIEWS

The effect of bridgehead steric bulk on the ground state and intramolecular exchange processes of (μ-SCH2CR2CH2S)[Fe(CO)3][Fe(CO)2L] complexes

(2008) Michael L. Singleton et al.   COMPTES RENDUS CHIMIE

Series of Mixed Valent Fe(II)Fe(I) Complexes That Model the HoxState of [FeFe]Hydrogenase: Redox Properties, Density-Functional Theory Investigation, and Reactivities with Extrinsic CO

(2008) Christine M. Thomas et al.   INORGANIC CHEMISTRY

New Nitrosyl Derivatives of Diiron Dithiolates Related to the Active Site of the [FeFe]-Hydrogenases

(2008) Matthew T. Olsen et al.   INORGANIC CHEMISTRY

Terminal Hydride in [FeFe]-Hydrogenase Model Has Lower Potential for H2Production Than the Isomeric Bridging Hydride

(2008) Bryan E. Barton et al.   INORGANIC CHEMISTRY

Photoelectron spectroscopy of dithiolatodiironhexacarbonyl models for the active site of [Fe–Fe] hydrogenases: Insight into the reorganization energy of the “rotated” structure in the enzyme

(2008) Benjamin J. Petro et al.   JOURNAL OF MOLECULAR STRUCTURE

Nitrosyl Derivatives of Diiron(I) Dithiolates Mimic the Structure and Lewis Acidity of the [FeFe]-Hydrogenase Active Site

(2008) Matthew T. Olsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aza- and Oxadithiolates Are Probable Proton Relays in Functional Models for the [FeFe]-Hydrogenases

(2008) Bryan E. Barton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY