4.6 Article

Effect of SDS/THF on thermodynamic and kinetic properties of formation of hydrate from a mixture of gases (CH4+C2H6+C3H8) for storing gas as hydrate

期刊

JOURNAL OF ENERGY CHEMISTRY
卷 25, 期 3, 页码 409-417

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jechem.2016.01.018

关键词

Phase equilibrium; Induction time; Formation rate; Storage capacity

资金

  1. University Grants Commission, New Delhi, India

向作者/读者索取更多资源

In this work, the effect of sodium dodecyl sulfate (SDS) and combined effect of sodium dodecyl sulfate (SDS) and tetrahydrofuran (THF) on thermodynamic and kinetic properties of CH4+C2H6+C3H8 hydrate formation have been studied. Four different concentrations of sodium dodecyl sulfate (100 ppm, 500 ppm, 1000 ppm and 1500 ppm) have been used to see its effect on phase equilibrium condition and formation kinetics. Though sodium dodecyl sulfate (SDS) does not vary the pressure-temperature condition of hydrate formation, it has a prominent favorable effect on induction time, gas consumption, storage capacity and formation rate. The addition of 3% (mol) tetrahydrofuran (THF) to water+SDS system results in large shifts in phase equilibrium boundary to lower pressure and higher temperature. It has been noticed that the addition of tetrahydrofuran further enhances the formation rate. So the mixture of sodium dodecyl sulfate (SDS) and tetrahydrofuran (THF) can be effectively used as promoter for storing natural gas as hydrate. (C) 2016 Science Press and Dalian Institute of Chemical Physics. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Physical

Mathematical regression models for rheological behavior of interaction between polymer-surfactant binary mixtures and electrolytes

Tandrima Banerjee, Abhijit Samanta, Ajay Mandal

Summary: The rheological behaviors of polymer-surfactant binary mixtures, specifically partially hydrolyzed polyacrylamide (PHPAM) polymer and sodium dodecyl sulfate (SDS) surfactant solutions, were investigated in this study. The addition of salt and alkali was found to have significant effects on the viscosity of these solutions. The findings provide important insights into the understanding of the rheological behaviors of polymer-surfactant mixtures.

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY (2022)

Article Chemistry, Physical

Synthesis and characterization of surface-active ionic liquids for their potential application in enhanced oil recovery

Prathibha Pillai, Ajay Mandal

Summary: The research investigates the potential application of surface active ionic liquids in enhanced oil recovery, showing their good surface activity and high efficiency on the interface under reservoir conditions. Through laboratory assessment, the synthesized SAILs have shown promise for use in EOR.

JOURNAL OF MOLECULAR LIQUIDS (2022)

Article Energy & Fuels

Analytical model of incremental oil recovery as a function of WAG ratio and tapered WAG ratio benefits over uniform WAG ratio for heterogeneous reservoir

Mohammad Yunus Khan, Ajay Mandal

Summary: The water-alternating-gas (WAG) operating scheme and reservoir permeability heterogeneity are crucial parameters affecting the WAG displacement process. The analytical model developed in this study considers WAG ratio, viscous gravity ratio, and mobility ratio for stratified heterogeneous reservoirs. The study shows that decreasing WAG ratio accelerates incremental oil recovery, especially at high viscous gravity conditions.

JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING (2022)

Article Energy & Fuels

Optimized deep learning model assisted pressure transient analysis for automatic reservoir characterization

Rakesh Kumar Pandey, Anil Kumar Dahiya, Ankesh Kumar Pandey, Ajay Mandal

Summary: An optimized deep learning model has been proposed for automatic interpretation of pressure drawdown tests, achieving high accuracy in predicting parameters from pressure data with minimized manual intervention.

PETROLEUM SCIENCE AND TECHNOLOGY (2022)

Review Energy & Fuels

Carbon dioxide thickening: A review of technological aspects, advances and challenges for oilfield application

Nilanjan Pal, Xuan Zhang, Muhammad Ali, Ajay Mandal, Hussein Hoteit

Summary: This article reviews the technical advances, challenges, and applicability of CO2 thickeners, particularly for hydrocarbon recovery. Different types of thickeners, including binary co-polymers and small molecule compounds, have been investigated and show promise for CO2 thickening.
Review Energy & Fuels

Mini-review on Recent Advances in the Application of Surface-Active Ionic Liquids: Petroleum Industry Perspective

Prathibha Pillai, Moumita Maiti, Ajay Mandal

Summary: Ionic liquids are a promising new material for various industrial applications due to their unique structures and properties. This paper reviews the previous research on the application of ionic liquids in the petroleum industry and related processes, including enhanced oil recovery, drilling fluids, gas hydrate, CO2 capture, and flow assurance. The in-depth discussion aims to aid professionals and researchers in understanding the current situation and planning for the future.

ENERGY & FUELS (2022)

Article Energy & Fuels

Inhibition Effect of Synthesized Ionic Liquids on Hydrate Formation: A Kinetic and Thermodynamic Study

Moumita Maiti, Prathibha Pillai, Aniruddha Sharma, Ajoy Kumar Bhaumik, Ajay Mandal

Summary: In this study, the effect of two ionic liquids on the formation and dissociation of hydrates was investigated. The results showed that these ionic liquids were effective in inhibiting hydrate formation both thermodynamically and kinetically. The induction time and formation rate of hydrates were significantly increased in the presence of these ionic liquids compared to pure water. Additionally, the performance of the ionic liquids in hydrate inhibition increased with increasing alkyl chain length.

ENERGY & FUELS (2022)

Article Chemistry, Physical

Synergistic effect of low saline ion tuned Sea Water with ionic liquids for enhanced oil recovery from carbonate reservoirs

Rohit Kumar Saw, Prathibha Pillai, Ajay Mandal

Summary: In recent decades, low salinity water flooding (LSWF) has gained attention for its effectiveness in oil recovery. However, there is a lack of studies in the literature on the potential of using Ionic Liquids (ILs) as candidates for chemical enhanced oil recovery (CEOR) combined with LSWF. This study evaluates the synergistic effect of ILs with varying chain lengths with low saline ion tuned seawater (ITSW) for enhanced oil recovery from carbonate reservoirs. The analysis shows that ILs demonstrate a better synergistic effect with ITSW, reducing interfacial tension, altering rock wettability, and exhibiting less adsorption density at the reservoir temperature. ILs with the longest chain length ([C12mim] [BF4]) show superior properties and significantly increase oil recovery in low saline ITSW.

JOURNAL OF MOLECULAR LIQUIDS (2022)

Article Chemistry, Physical

A mechanistic study of low salinity water-based nanoparticle-polymer complex fluid for improved oil recovery in sandstone reservoirs

Rohit Kumar Saw, Anshuman Singh, Neetish Kumar Maurya, Ajay Mandal

Summary: Low salinity water flooding is cost-effective and environmentally friendly, and the addition of nanoparticles and polymers can significantly increase oil recovery. The viscosity of complex chemical slugs can be increased by adding nanoparticles to polymer solutions. Low salinity water requires a lower concentration of polymer to reach the target viscosity compared to high saline formation water. The addition of nanoparticles reduces interfacial tension and contact angle, leading to higher oil recovery in low salinity water. Injection of low salinity water-based complex fluid results in incremental recovery of OOIP compared to low salinity water and conventional formation water flooding.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2023)

Article Chemistry, Multidisciplinary

Experimental Investigation of the Synergistic Effect of Two Nonionic Surfactants on Interfacial Properties and Their Application in Enhanced Oil Recovery

Rohit Kumar Saw, Deep Sinojiya, Prathibha Pillai, Shubham Prakash, Ajay Mandal

Summary: This study aims to investigate the synergistic effects of two nonionic surfactants (Tergitol 15-S-12 and PEG 600) on surface properties, including surface tension, interfacial tension (IFT), and wettability alteration, in chemically enhanced oil recovery (EOR). The optimum composition of the surfactant mixture, determined through surface tension measurement, showed a minimum surface tension value of 30.3 mN/m at a concentration of 225 ppm of Tergitol 15-S-12 and 1 wt % of PEG 600. The surfactant mixture exhibited an ultra-low IFT of 0.672 mN/m at optimum salinity. The wettability alteration study revealed a shift in rock wettability from oil-wet to water-wet region through contact angle observations and X-ray diffraction analysis.

ACS OMEGA (2023)

Article Energy & Fuels

Experimental investigation on fluid/fluid and rock/fluid interactions in enhanced oil recovery by low salinity water flooding for carbonate reservoirs

Rohit Kumar Saw, Ajay Mandal

Summary: The low salinity water flooding (LSWF) technique is cost-effective and environmentally friendly, but its mechanisms are not yet clear. Recovery in LSWF depends on fluid/fluid and rock/fluid interactions. This study investigated both interactions and found different optimal conditions for improved oil recovery. Rock/fluid interaction showed an incremental recovery of 14%, while fluid/fluid interaction showed an incremental recovery of 7% over simple seawater injection. Results highlight the importance of considering both interactions and wettability alteration in LSWF design.
Article Chemistry, Physical

Experimental studies on effectiveness of graphene oxide nanosheets dispersion in water/aqueous PHPA for enhanced oil recovery

Dinesh Joshi, Neetish Kumar Maurya, Ajay Mandal

Summary: The application of graphene oxide nanosheets (GONs) in enhanced oil recovery has been shown to have unique characteristics, including reduction of interfacial tension and alteration of wetting properties. Experimental results demonstrate that GONs can alter the wettability of rock surfaces, leading to increased oil recovery.

JOURNAL OF MOLECULAR LIQUIDS (2023)

Article Energy & Fuels

Experimental and kinetic modelling studies on the gas hydrate inhibition effect of PVP K-90 in drilling fluids

Moumita Maiti, Ajoy Kumar Bhaumik, Ajay Mandal

Summary: Hydrate inhibitors are crucial for preventing hydrate growth and ensuring smooth drilling operations. Water-soluble polymers, such as polyvinyl pyrrolidone (PVP K-90), have been found effective in reducing hydrate formation rates. This study investigates the influence of PVP K-90 concentration on hydrate inhibition in predesigned drilling fluids containing methane, ethane, and propane.

GAS SCIENCE AND ENGINEERING (2023)

Article Chemistry, Physical

Enhanced oil recovery using a novel non-ionic surfactant synthesized from olive oil: Performance and synergistic effects

Rohit Kumar Saw, Pranali M. Rane, Dinesh Joshi, Shubham Prakash, Lavisha Jangid, Ajay Mandal

Summary: In recent years, there has been increasing interest in the application of natural surfactants in enhanced oil recovery (EOR) due to environmental concerns. This study introduces a novel non-ionic surfactant synthesized from olive oil and evaluates its properties. The synthesized surfactant showed effective emulsification, wettability modification, and efficient oil displacement. Additionally, the surfactant had a low critical micelle concentration, indicating its ability to reduce interfacial tension.

JOURNAL OF MOLECULAR LIQUIDS (2023)

Article Energy & Fuels

Inhibition Effect of Synthesized Ionic Liquids on Hydrate Formation: A Kinetic and Thermodynamic Study

Moumita Maiti, Prathibha Pillai, Aniruddha Sharma, Ajoy Kumar Bhaumik, Ajay Mandal

Summary: This study investigates the effect of two ionic liquids on the formation and dissociation of gas hydrates and finds that they are effective inhibitors. The inhibition performance of the ionic liquids increases with increasing alkyl chain length.

ENERGY & FUELS (2022)

Article Chemistry, Applied

In-situ coating and surface partial protonation co-promoting performance of single-crystal nickel-rich cathode in all-solid-state batteries

Maoyi Yi, Jie Li, Mengran Wang, Xinming Fan, Bo Hong, Zhian Zhang, Aonan Wang, Yanqing Lai

Summary: In this study, polyacrylic acid (PAA) was used as a binder for the cathode in all-solid-state batteries. Through H+/Li+ exchange reaction, a uniform PAA-Li coating layer was formed on the cathode surface, improving the stability of the cathodic interface and the crystal structure. The SC-NCM83-PAA cathode exhibited superior cycling performance compared to traditional PVDF binder.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Arbitrary skin metallization by pencil-writing inspired solid-ink rubbing for advanced energy storage and harvesting

Yonghan Zhou, Zhongfeng Ji, Wenrui Cai, Xuewei He, Ruiying Bao, Xuewei Fu, Wei Yang, Yu Wang

Summary: By learning from the pencil-writing process, a solid-ink rubbing technology (SIR-tech) has been invented to develop durable metallic coatings on diverse substrates. The composite metallic skin by SIR-tech outperforms pure liquid-metal coating and shows great potential for various applications.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Coupling Sb2WO6 microflowers and conductive polypyrrole for efficient potassium storage by enhanced conductivity and K plus diffusivity

Ruiqi Tian, Hehe Zhang, Zeyu Yuan, Yuehua Man, Jianlu Sun, Jianchun Bao, Ming-Sheng Wang, Xiaosi Zhou

Summary: In this study, polypyrrole-encapsulated Sb2WO6 microflowers were synthesized and demonstrated to exhibit excellent potassium storage properties and cycling stability. The improved performance of Sb2WO6@PPy was attributed to the unique microflower structure, enhanced electronic conductivity, and protective PPy coating.

JOURNAL OF ENERGY CHEMISTRY (2024)

Review Chemistry, Applied

Physics-based battery SOC estimation methods: Recent advances and future perspectives

Longxing Wu, Zhiqiang Lyu, Zebo Huang, Chao Zhang, Changyin Wei

Summary: This paper presents a comprehensive survey on physics-based state of charge (SOC) algorithms applied in advanced battery management system (BMS). It discusses the research progresses of physical SOC estimation methods for lithium-ion batteries and presents future perspectives for this field.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

d-d Orbital coupling induced by crystal-phase engineering assists acetonitrile electroreduction to ethylamine

Honggang Huang, Yao Chen, Hui Fu, Cun Chen, Hanjun Li, Zhe Zhang, Feili Lai, Shuxing Bai, Nan Zhang, Tianxi Liu

Summary: The d-d orbital coupling induced by crystal-phase engineering effectively adjusts the electronic structure of electrocatalysts, improving their activity and stability, which is significant for electrocatalyst research.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

In-doping collaboratively controlling back interface and bulk defects to achieve efficient flexible CZTSSe solar cells

Quanzhen Sun, Yifan Li, Caixia Zhang, Shunli Du, Weihao Xie, Jionghua Wu, Qiao Zheng, Hui Deng, Shuying Cheng

Summary: In this study, indium (In) ions were introduced into flexible Cu2ZnSn(S,Se)(4) (CZTSSe) solar cells to modify the back interface and passivate deep level defects in CZTSSe bulk. The results showed that In doping effectively inhibited the formation of secondary phase and V-Sn defects, decreased the barrier height at the back interface, passivated deep level defects in CZTSSe bulk, increased carrier concentration, and significantly reduced the V-OC deficit. Eventually, a flexible CZTSSe solar cell with a power conversion efficiency of 10.01% was achieved. This synergistic strategy of interface modification and bulk defects passivation through In incorporation provides a new approach for fabricating efficient flexible kesterite-based solar cells.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Toward a comprehensive hypothesis of oxygen-evolution reaction in the presence of iron and gold

Negah Hashemi, Jafar Hussain Shah, Cejun Hu, Subhajit Nandy, Pavlo Aleshkevych, Sumbal Farid, Keun Hwa Chae, Wei Xie, Taifeng Liu, Junhu Wang, Mohammad Mahdi Najafpour

Summary: This study investigates the effects of Fe on the oxygen-evolution reaction (OER) in the presence of Au. The study identifies two distinct areas of OER associated with Fe and Au sites at different overpotentials. Various factors were varied to observe the behaviors of FeOxHy/Au during OER. The study reveals strong electronic interaction between Fe and Au, and proposes a lattice OER mechanism based on FeOxHy.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Exploring the impact of Nafion modifier on electrocatalytic CO2 reduction over Cu catalyst

Yingshi Su, Yonghui Cheng, Zhen Li, Yanjia Cui, Caili Yang, Ziyi Zhong, Yibing Song, Gongwei Wang, Lin Zhuang

Summary: This study systematically investigates the key roles of Nafion on Cu nanoparticles electrocatalyst for CO2RR. The Nafion modifier suppresses the hydrogen evolution reaction, increases CO2 concentration and mass transfer process, and activates CO2 molecule to enhance C2 product generation. As a result, the selectivity of the hydrogen evolution reaction is reduced and the efficiency of C2 products is significantly improved.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Electronic structure and spin state regulation of vanadium nitride via a sulfur doping strategy toward flexible zinc-air batteries

Daijie Deng, Honghui Zhang, Jianchun Wu, Xing Tang, Min Ling, Sihua Dong, Li Xu, Henan Li, Huaming Li

Summary: By doping sulfur into vanadium nitride, the S-VN/Co/NS-MC catalyst exhibits enhanced oxygen reduction reaction activity and catalytic performance. When applied in liquid and flexible ZABs, it shows higher power density, specific capacity, and cycling stability.

JOURNAL OF ENERGY CHEMISTRY (2024)

Review Chemistry, Applied

Self-assembly of perovskite nanocrystals: From driving forces to applications

Yi Li, Fei Zhang

Summary: Self-assembly of metal halide perovskite nanocrystals holds significant application value in the fields of display, detector, and solar cell due to their unique collective properties. This review covers the driving forces, commonly used methods, and different self-assembly structures of perovskite nanocrystals. Additionally, it summarizes the collective optoelectronic properties and application areas of perovskite superlattice structures, and presents an outlook on potential issues and future challenges in the development of perovskite nanocrystals.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Ag-integrated mixed metallic Co-Fe-Ni-Mn hydroxide composite as advanced electrode for high-performance hybrid supercapacitors

Anki Reddy Mule, Bhimanaboina Ramulu, Shaik Junied Arbaz, Anand Kurakula, Jae Su Yu

Summary: Direct growth of redox-active noble metals and rational design of multifunctional electrochemical active materials play crucial roles in developing novel electrode materials for energy storage devices. In this regard, silver (Ag) has attracted great attention in the design of efficient electrodes. The construction of multifaceted heterostructure cobalt-iron hydroxide (CFOH) nanowires (NWs)@nickel cobalt manganese hydroxides and/or hydrate (NCMOH) nanosheets (NSs) on the Ag-deposited nickel foam and carbon cloth (i.e., Ag/ NF and Ag/CC) substrates is reported. The as-fabricated Ag@CFOH@NCMOH/NF electrode delivered superior areal capacity value of 2081.9 μA h cm-2 at 5 mA cm-2. Moreover, as-assembled hybrid cell based on NF (HC/NF) device exhibited remarkable areal capacity value of 1.82 mA h cm-2 at 5 mA cm-2 with excellent rate capability of 74.77% even at 70 mA cm-2. Furthermore, HC/NF device achieved maximum energy and power densities of 1.39 mW h cm-2 and 42.35 mW cm-2, respectively. To verify practical applicability, both devices were also tested to serve as a self-charging station for various portable electronic devices.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Insights into ionic association boosting water oxidation activity and dynamic stability

Zanling Huang, Shuqi Zhu, Yuan Duan, Chaoran Pi, Xuming Zhang, Abebe Reda Woldu, Jing-Xin Jian, Paul K. Chu, Qing-Xiao Tong, Liangsheng Hu, Xiangdong Yao

Summary: In this study, it was found that Ni sites act as a host to attract Fe(III) to form Fe(Ni)(III) binary centers, which promote the oxygen evolution reaction (OER) activity and stability by cyclical formation of intermediates. Additionally, other ions can also catalyze the OER process on different electrodes.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Reversible Mn2+/Mn4+double-electron redox in P3-type layer-structured sodium-ion cathode

Jie Zeng, Jian Bao, Ya Zhang, Xun-Lu Li, Cui Ma, Rui-Jie Luo, Chong-Yu Du, Xuan Xu, Zhe Mei, Zhe Qian, Yong-Ning Zhou

Summary: The balance between cationic redox and oxygen redox is crucial for achieving high energy density and cycle stability in sodium batteries. This study demonstrates the reversible Mn2+/Mn4+ redox in a P3-Na0.65Li0.2Co0.05Mn0.75O2 cathode material through Co substitution, effectively suppressing the contribution of oxygen redox and improving structure stability.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

The initial stages of Li2O2 formation during oxygen reduction reaction in Li-O2 batteries: The significance of Li2O2 in charge-transfer reactions within devices

Daniela M. Josepetti, Bianca P. Sousa, Simone A. J. Rodrigues, Renato G. Freitas, Gustavo Doubek

Summary: Lithium-oxygen batteries have high energy density potential but face challenges in achieving high cyclability. This study used operando Raman experiments and electrochemical impedance spectroscopy to evaluate the initial discharge processes in porous carbon electrodes. The results indicate that the reaction occurs at the Li2O2 surface and the growth of Li2O2 forms a more compact and homogeneous structure.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Porous metal oxides in the role of electrochemical CO2 reduction reaction

Ziqi Zhang, Jinyun Xu, Yu Zhang, Liping Zhao, Ming Li, Guoqiang Zhong, Di Zhao, Minjing Li, Xudong Hu, Wenju Zhu, Chunming Zheng, Xiaohong Sun

Summary: This paper explores the challenge of increasing global CO2 emissions and highlights the role of porous metal oxide materials in electrocatalytic reduction of CO2 (CO2RR). Porous metal oxides offer high surface area and tunability for optimizing CO2RR reaction mechanisms.

JOURNAL OF ENERGY CHEMISTRY (2024)