Article
Engineering, Electrical & Electronic
Aparna Ukarande, Maruti V. Salve, Shweta Chaure, O. I. Olusola, T. M. W. J. Bandara, M. Furlani, B. -e. Mellander, M. A. K. L. Dissanayake, I. Albinsson, Nandu B. Chaure
Summary: In this study, CdTe thin films were successfully grown using a wet-chemical electrochemical technique in an aqueous bath. The effect of bath temperature on the properties of the sample and the optoelectronic performance of the solar cell devices was investigated. The annealed sample exhibited a polycrystalline cubic crystal structure of CdTe with the desired grain size and stoichiometry. The solar cell device showed a relatively high fill factor and efficiency.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Chemistry, Physical
Mamoona Riffat, Hassan Ali, H. A. Qayyum, M. Bilal, Tanvir Hussain
Summary: Solar-driven hydrogen production using a photocatalyst is the most effective method, and hydrogen is the most suitable renewable energy source. The efficiency of hydrogen production is low, but it can be enhanced by using a suitable photocatalyst. This study deposited ZnO thin films on CdTe thin films to form ZnO/CdTe heterostructure thin films as photoelectrodes for water splitting. The results showed that ZnO/CdTe heterostructure thin films have better photocurrent response and charge transfer compared to pure ZnO and CdTe thin films.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Multidisciplinary
Tomota Nagaura, Hoang-Phuong Phan, Victor Malgras, Tuan-Anh Pham, Hyunsoo Lim, Aditya Ashok, Jeonghun Kim, Jungmok You, Nam-Trung Nguyen, Jongbeom Na, Yusuke Yamauchi
Summary: This study presents a new synthesis route for mesoporous semiconductors through soft-template-assisted electrochemical deposition. The resulting films exhibit homogeneous distribution of mesopores and high sensitivity in photodetection, demonstrating the versatility and potential for applications in nanostructured semiconductors.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Materials Science, Multidisciplinary
A. U. Yimamu, M. A. Afrassa, B. F. Dejene, O. K. Echendu, J. J. Terblans, H. C. Swart, S. J. Motloung
Summary: Cadmium Telluride (CdTe) thin films were synthesized using a less commonly used salt, cadmium acetate, as a cadmium precursor. The film's structure, optical properties, conductivity, surface morphology, elemental composition, and surface roughness were investigated using XRD, UV-VIS, PEC, SEM, EDS, and SPM. The results showed that the film prepared at a deposition voltage of 1250 mV had better potential application.
MATERIALS TODAY COMMUNICATIONS
(2023)
Article
Physics, Applied
J. J. Andrews, M. Beaudoin, S. K. O'Leary, P. Koirala, B. Ramanujam, X. Tan, M. A. Razooqi Alaani, P. Pradhan, N. J. Podraza, R. W. Collins
Summary: This study critically examines the effects of cadmium chloride treatment and bromine/methanol wet etching on the structural and optical properties of polycrystalline CdTe thin-films. Experimental results were used to determine the spectral dependence of the optical absorption coefficient and to analyze the impact on the grazing incidence x-ray diffraction pattern. The study also extended to analyzing the external quantum efficiency of CdTe-based solar cells treated with cadmium chloride, providing insights into carrier trapping and recombination processes in different types of CdTe absorbers.
JOURNAL OF APPLIED PHYSICS
(2021)
Article
Materials Science, Multidisciplinary
A. U. Yimamu, M. A. Afrassa, B. F. Dejene, O. K. Echendu, K. G. Tshabalala, J. J. Terblans, H. C. Swart, S. J. Motloung
Summary: Cadmium telluride (CdTe) thin films were electrodeposited from an aqueous acidic solution, using cadmium acetate dihydrate and tellurium dioxide as precursors. The deposition time was varied to investigate the properties of the CdTe films. XRD analysis revealed polycrystalline cubic zinc blend, orthorhombic, and hexagonal structures in the films, with the dominant cubic phase. UV-vis spectrophotometry showed that the band gap of the as-deposited films ranged from 1.41 to 1.45 eV, but decreased to 1.39-1.42 eV after heat treatment. PEC measurements confirmed n-type conductivity in both forms. SEM analysis showed changes in surface morphology with deposition time, and an increase in grain size after heat treatment. EDS analysis indicated variations in the composition of the films with deposition time, with a decrease in tellurium and an increase in cadmium after annealing. SPM measurements revealed that the average surface roughness varied with deposition time, with the highest value observed for the 120 min deposition. The prepared CdTe films show potential as absorber layers in thin film solar cells.
MATERIALS RESEARCH EXPRESS
(2023)
Article
Materials Science, Multidisciplinary
Ali Ciris
Summary: This study investigated the impact of locational CdCl2 treatment on the MgZnO/CdS stacks. The application of CdCl2 to either the inter-face or the top-surface improved the grain structure of the stacks, while CdCl2 applied to both surfaces led to a porous structure. CdS and MgZnO absorption edges were observed in all stacks, along with emission bands relating to defect transitions in the MgZnO and CdS layers. The refractive index values decreased with CdCl2 treatment. The results suggest that local CdCl2 treatment has a clear effect on the structural and optical properties of MgZnO/CdS stacks.
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2023)
Article
Materials Science, Multidisciplinary
A. A. Faremi, P. A. Olubambi, S. S. Oluyamo
Summary: In this study, copper selenide films were synthesized potentiostatically at varied voltage on conductive FTO substrate, and their suitability as a window layer material in solar cells fabrication was investigated. The material properties were studied using XRD, SEM, EDX, XRF, and UV techniques.
Article
Energy & Fuels
Saima G. Sayyed, Habib M. Pathan, Arif Shaikh, Shoyebmohamad F. Shaikh, Abdullah M. Al-Enizi
Summary: The study presents a simple, effective, and inexpensive approach to deposit thin film of manganese oxide on a flexible stainless steel substrate for supercapacitor application. The impact of heat treatment and different electrolytes on the electrochemical performance of the electrode is investigated. The material demonstrates a large pseudo-capacitance and stability in 1M Na2SO4 electrolyte, making it a promising candidate for supercapacitor electrodes.
JOURNAL OF ENERGY STORAGE
(2021)
Review
Chemistry, Multidisciplinary
Shreyash Hadke, Menglin Huang, Chao Chen, Ying Fan Tay, Shiyou Chen, Jiang Tang, Lydia Wong
Summary: Chalcogenide semiconductors have excellent optoelectronic properties for use in solar cells, with a focus on emerging binary, ternary, and quaternary chalcogenides. The review analyzes their performance metrics, electronic band structure, and point defect characteristics, while also discussing potential pathways for practical applications in solar energy harvesting.
Article
Engineering, Electrical & Electronic
Moustafa Ahmed, Ahmed Bakry, Essam R. Shaaban, Hamed Dalir
Summary: ITO was prepared by solid-phase reaction of gradient In2O3 and SnO2 powders to fabricate films with different thicknesses. The structural, electrical, and optical parameters were studied, showing that film thickness affects the electrical properties and optical energy gap.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Nanoscience & Nanotechnology
Netrapal Singh, Hafsa Siddiqui, Manoj Goswami, Satendra Kumar, Mohammad Ashiq, Natarajan Sathish, Mysore Sridhar Santosh, Surender Kumar
Summary: Nanoscale-thick silver thin films (Ag-NTF) are fabricated on indium tin oxide-coated glasses through an electrochemical 3D printing process. The Ag-NTF electrode exhibits uniform and nanometer-thick film structure, with a mean crystallite size of 17 nm. The electrode shows excellent electrochemical activity, with a sensitivity of 25 +/- 1 mu A mM-1 cm-2 and a lower detection limit of 1.0 mu M for hydrogen peroxide sensing. The electrode also demonstrated good selectivity towards H2O2 and applicability in real-life samples.
ACS APPLIED NANO MATERIALS
(2023)
Article
Engineering, Electrical & Electronic
Antonio Arce-Plaza, F. J. Sanchez-Rodriguez, Maykel Courel, Rene Perez-Cuapio, J. A. Alvarado, J. Roque, M. Ortega-Lopez
Summary: A novel process for CdTe synthesis and deposition in solar cells technology was introduced, resulting in enhanced performance and reduced production costs. The photovoltaic devices manufactured using this process showed improved properties, as demonstrated by various characterization techniques and J-V analysis.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2021)
Article
Physics, Condensed Matter
T. K. W. Mohapi, A. U. Yimamu, K. G. Tshabalala, S. J. Motloung
Summary: In this study, electrodeposition was used to fabricate CdS and CdZrS thin films on fluorine-doped tin oxide substrates. The results showed that both films had a cubic crystal structure, and surface analysis confirmed the coverage of the substrate by the films. The shape and grain size of the films varied with the deposition voltage.
PHYSICA B-CONDENSED MATTER
(2023)
Article
Engineering, Electrical & Electronic
Deepak Suthar, Himanshu, S. L. Patel, S. Chander, M. D. Kannan, M. S. Dhaka
Summary: The research investigates the use of ZnTe layer to reduce losses in CdTe solar cells and optimizes the physical properties of ZnTe films to enhance device performance.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Chemistry, Physical
O. K. Echendu, S. Z. Werta, F. B. Dejene, V. Craciun
JOURNAL OF ALLOYS AND COMPOUNDS
(2018)
Article
Engineering, Electrical & Electronic
O. K. Echendu, S. Z. Werta, F. B. Dejene
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2019)
Article
Chemistry, Physical
O. K. Echendu, S. Z. Werta, F. B. Dejene, K. O. Egbo
JOURNAL OF ALLOYS AND COMPOUNDS
(2019)
Article
Engineering, Electrical & Electronic
O. K. Echendu, S. Z. Werta, F. B. Dejene, A. A. Ojo, I. M. Dharmadasa
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2019)
Article
Engineering, Electrical & Electronic
S. Z. Werta, O. K. Echendu, F. B. Dejene
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2019)
Review
Engineering, Electrical & Electronic
I. M. Dharmadasa, A. E. Alam, A. A. Ojo, O. K. Echendu
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2019)
Article
Materials Science, Multidisciplinary
S. Z. Werta, O. K. Echendu, K. O. Egbo, F. B. Dejene
Article
Physics, Condensed Matter
S. Z. Werta, O. K. Echendu, F. B. Dejene
PHYSICA B-CONDENSED MATTER
(2020)
Correction
Physics, Multidisciplinary
C. P. Onyenegecha, C. A. Onate, O. K. Echendu, A. A. Ibe, H. Hassanabadi
EUROPEAN PHYSICAL JOURNAL PLUS
(2020)
Article
Multidisciplinary Sciences
C. P. Onyenegecha, I. J. Njoku, A. I. Opara, O. K. Echendu, E. N. Omoko, F. C. Eze, C. J. Okereke, E. Onyeocha, F. U. Nwaneho
Summary: In this study, solutions of the modified Mobius square plus Eckart potential for the Schrodinger equation are obtained using the formula method. Numerical results and thermodynamic properties are presented, including the partition function Z, vibrational free energy F, vibrational internal energy U, vibrational entropy S, and vibrational specific heat C. Special cases of this potential are also discussed. The results are consistent with previous studies in the literature.
Article
Metallurgy & Metallurgical Engineering
Placid Nwaokafor, Kelechukwu B. Okeoma, Obi K. Echendu, Anthony C. Ohajianya, Kingsley O. Egbo
Summary: The study showed that internal strain values are correlated with the ductility and hardness of the material, with higher internal strain values corresponding to higher ductility values and lower hardness values.
METALLOGRAPHY MICROSTRUCTURE AND ANALYSIS
(2021)
Article
Materials Science, Multidisciplinary
A. U. Yimamu, M. A. Afrassa, B. F. Dejene, O. K. Echendu, K. G. Tshabalala, J. J. Terblans, H. C. Swart, S. J. Motloung
Summary: Cadmium telluride (CdTe) thin films were electrodeposited from an aqueous acidic solution, using cadmium acetate dihydrate and tellurium dioxide as precursors. The deposition time was varied to investigate the properties of the CdTe films. XRD analysis revealed polycrystalline cubic zinc blend, orthorhombic, and hexagonal structures in the films, with the dominant cubic phase. UV-vis spectrophotometry showed that the band gap of the as-deposited films ranged from 1.41 to 1.45 eV, but decreased to 1.39-1.42 eV after heat treatment. PEC measurements confirmed n-type conductivity in both forms. SEM analysis showed changes in surface morphology with deposition time, and an increase in grain size after heat treatment. EDS analysis indicated variations in the composition of the films with deposition time, with a decrease in tellurium and an increase in cadmium after annealing. SPM measurements revealed that the average surface roughness varied with deposition time, with the highest value observed for the 120 min deposition. The prepared CdTe films show potential as absorber layers in thin film solar cells.
MATERIALS RESEARCH EXPRESS
(2023)
Article
Materials Science, Multidisciplinary
A. U. Yimamu, M. A. Afrassa, B. F. Dejene, O. K. Echendu, J. J. Terblans, H. C. Swart, S. J. Motloung
Summary: Cadmium Telluride (CdTe) thin films were synthesized using a less commonly used salt, cadmium acetate, as a cadmium precursor. The film's structure, optical properties, conductivity, surface morphology, elemental composition, and surface roughness were investigated using XRD, UV-VIS, PEC, SEM, EDS, and SPM. The results showed that the film prepared at a deposition voltage of 1250 mV had better potential application.
MATERIALS TODAY COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
S. Z. Werta, O. K. Echendu, F. B. Dejene
ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY
(2019)
Article
Materials Science, Multidisciplinary
O. K. Echendu, B. F. Dejene, F. G. Hone
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
(2018)