期刊
POLYMERS
卷 8, 期 5, 页码 -出版社
MDPI
DOI: 10.3390/polym8050171
关键词
MOFs; anion exchange; polyoxometalates
资金
- Spanish MINECO [CTQ2014-59209-P, MAT2014-56143-R]
- Spanish MINECO (Excellence Unit Maria de Maeztu) [MDM-2015-0538]
- Generalitat Valenciana (Prometeo)
- Generalitat Valenciana (ISIC-Nano)
- VLC/Campus Program
- Blaise Pascal International Chair
The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exchange process of a Gd based MOF, involving molecular species like polyoxometalates (POMs), and [AuCl4](-). This post-synthetic modification has been characterized by IR, EDAX, and single crystal diffraction, which have provided unequivocal evidence of the location of the anion molecules in the framework.
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