期刊
RSC ADVANCES
卷 6, 期 47, 页码 40799-40805出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra04885d
关键词
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资金
- Strategic Priority Research Program of the Chinese Project Academy of Science [XDA09010201]
- National Natural Science Foundation of China [51371186]
- Zhejiang Province Key Science and Technology Innovation Team [2013TD16]
- Ningbo 3315 International Team of Advanced Energy Storage Materials
A composite with ultrafine SiOx (x = 1.57, around 2 nm) nanoparticles confined in a carbon framework is synthesized by a simple thermopolymerization process and subsequent heat treatment. In the composite, the carbon framework can provide a consecutive network to improve the electrical conductivity of the composite and cushion the volume expansion to prevent the active material peeling from the current collector. The ultrafine SiOx nanoparticles can alleviate mechanical strain and shorten the diffusion/transport distance of lithium ions and electrons. In consequence, the as-synthesized composite delivers a high reversible capacity of 540 mA h g(-1) at a current density of 500 mA g(-1) after 200 cycles. The composite delivers good electrochemical performance, making it a promising candidate for the next-generation high-energy LIBs.
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