Reduction of persistent photoconductivity in a few-layer MoS2 field-effect transistor by graphene oxide functionalization

We functionalized two-dimensional few-layer MoS2 based FET with graphene oxide (GO) in order to improve its persistent photoconductivity and photoresponse time. Both pristine and GO functionalized devices show n-type semiconductor behavior with high on/off ratio exceeding similar to 10(5). The photoresponse of the GO-MoS2 hybrid device shows almost complete recovery from persistent photoconductivity and a substantial decrease in response time from similar to 15 s in the pristine MoS2 device to similar to 1 s in the GO-MoS2 device. The reasons behind this improvement have been explored and discussed on the basis of electrostatic and photo interaction between GO and MoS2. As GO is a strong candidate for various sensing applications, therefore this intelligent hybrid system, where GO interacts electrostatically with the underlying MoS2 channel, has tremendous potential to add more functionalities to a pristine MoS2 device for realizing various smart nanoscale FET-based biochemical and gas sensors for myriad applications.