期刊
RSC ADVANCES
卷 6, 期 93, 页码 90069-90075出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra18733a
关键词
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资金
- National High Technology Research and Development Program of China [2009AA03Z319]
- Fundamental Research Funds for the Central Universities of China [DUT12LK04]
Air-cathodes with properties of efficiency, durability and low cost are essential for high performance metal-air batteries and fuel cells for practical applications. In this study, non-precious metal ORR electrocatalysts derived by the encapsulation of Co nanoparticles in N-doped graphene nanoshells were synthesized by a typical one-step pyrolysis process. Compared with commercial Pt/C catalysts, the prepared Co-30@N-G hybrid electrocatalyst showed a high ORR activity at the same level in an alkaline medium. Subsequently, the Co-30@N-G hybrid electrocatalyst has been used as a cathode of Zn-air batteries, which displays equivalent performance to the systems derived using a commercial Pt/C catalyst. The Co-30@N-G derived mechanical rechargeable Zn-air battery showed a persistent flat discharge curve with minimum voltage loss at a high discharge rate of 40 mA cm(-2). The robustness of the Co-30@N-G ORR catalyst can allow the batteries to work constantly by periodically replacing the Zn anode and electrolyte, presenting an efficient and economical cathode for Zn-air flow batteries or Zn-air fuel cells.
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