4.6 Article

Spontaneous growth of silver nanotrees dominated with (111) crystalline faces on monolithic activated carbon

期刊

RSC ADVANCES
卷 6, 期 104, 页码 102528-102533

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra19399d

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  1. National Natural Science Foundation of China [21601059, 21473067]
  2. Science and Technology Department of Jiangsu Province [BY2014085]
  3. Education Department of Jiangsu Provincial [14 KJB430006]
  4. State Oceanic Administration [201305007]
  5. Environmental Protection Department of Jiangsu Province [2012010]

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An environmentally friendly wet chemistry approach is used to synthesize silver nanotrees with a single step. The silver nanotrees with single crystalline (111) faces were synthesized without any external reducing or stabilizing agents in water media, involving a galvanic-cell mechanism between the silver nanostructure and biomass-derived monolithic activated carbon (MAC). By varying the concentration of [Ag(NH3)(2)]NO3, silver nanoflowers, nanowires and nanorods can also be selectively obtained. The silver morphology can also be tuned by some anions such as PO43-, Cl- and OH- in MAC, which afford a more flexible morphological control in this galvanic-cell mechanism than those reported previously. Importantly, the obtained silver dendrites are found to yield excellent catalytic activity for the reduction of 4-nitroaniline by borohydride.

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