期刊
RSC ADVANCES
卷 6, 期 53, 页码 47890-47896出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra00473c
关键词
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资金
- National Natural Science Foundation of China [51303175, 51203154, 51173181, 51373166]
- The Hundred Talents Program from the Chinese Academy of Sciences
- Program of Scientific Development of Jilin Province [20150204027GX]
- International S&T Cooperation Program from Department of Science and Technology of Jilin Province [20160414032GH]
5-Hydroxymethylfurfural (HMF) is considered as a valuable platform chemical for fuels and chemical intermediates. Tremendous efforts have been made on the development of catalysts for the dehydration of saccharides to HMF with high conversion and selectivity. Here we reported a new solid acid, phosphoric acid doped polybenzimidazole (PA-PBI), for the dehydration of fructose to HMF with high selectivity (similar to 94%) at high fructose concentration (50 wt%) in a water-methyl isobutyl ketone (MIBK) biphasic system. PA-PBI was directly obtained by the one-pot polycondensation reaction and was very stable under harsh reaction conditions due to the strong acid-base interaction between PA and imidazole in PBI. PA-PBI was recycled to catalyze the dehydration of fructose four times without the loss of activity and could also catalyze a variety of disaccharides and polysaccharides to produce HMF. The high selectivity and the ease of recycling make PA-PBI a superior catalyst for the dehydration of saccharides to HMF.
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