Review
Environmental Sciences
Qian Zhang, Shuguang Yan, Xueting Yan, Yi Lv
Summary: Metal-organic frameworks (MOFs) are a new class of crystalline porous hybrid materials with high porosity, large specific surface area and adjustable channel structure and biocompatibility. They have been widely investigated for energy storage and conversion, gas adsorption/separation, catalysis, sensing and biomedicine applications. However, the release of MOFs into the environment poses a threat to human health and organisms.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Multidisciplinary Sciences
Wataru Saburi, Takanori Nihira, Hiroyuki Nakai, Motomitsu Kitaoka, Haruhide Mori
Summary: Glycoside phosphorylases are promising enzymes for efficient glycoside production. In this study, a new glycoside phosphorylase, solabiose phosphorylase, was characterized from an uncharacterized protein. The enzyme showed specific activity towards d-galactose, producing solabiose through a sequential bi-bi mechanism. Solabiose was successfully produced from lactose and sucrose without the need for chromatographic procedures.
SCIENTIFIC REPORTS
(2022)
Review
Engineering, Environmental
Qi Li, Fa-tang Li
Summary: This study discusses the feasibility of using photocatalysis technology to activate molecular oxygen and explores potential applications and activation mechanisms. It summarizes the methods of analyzing ROS, the application of activated molecular oxygen in oxidative reactions, and presents future research challenges and directions.
CHEMICAL ENGINEERING JOURNAL
(2021)
Review
Biochemistry & Molecular Biology
Jian Yang, Demeng Xie, Xiaofeng Ma
Summary: Amino sugars, carbohydrates with hydroxyl groups replaced by an amino group, play crucial roles in various biological activities. Stereoselective glycosylation of amino sugars has been a continuous effort, but it is challenging due to the competitive coordination of the amine to the Lewis acid promoter. This review focuses on the updated overview of stereoselective synthesis of 1,2-cis-aminoglycoside and its applications in complex glycoconjugate synthesis.
Article
Agricultural Engineering
Neha Srivastava, Akbar Mohammad, Manish Srivastava, Asad Syed, Abdallah M. Elgorban, Dan Bahadur Pal, P. K. Mishra, Taeho Yoon, Vijai Kumar Gupta
Summary: The study focused on the implementation of nanomaterials, specifically NiCo2O4 NPs, to improve the stability of cellulase enzyme for cost-effective biofuel production. The bioconversion of alkali treated rice straw using NiCo2O4 NPs led to the production of sugar hydrolyzate, which was further utilized for H-2 production via hybrid fermentation. The research demonstrated the potential of using nanomaterials for enhancing biofuel production efficiency.
BIORESOURCE TECHNOLOGY
(2021)
Review
Chemistry, Inorganic & Nuclear
Jiaqi Hao, Yu Zhao, Yiqi Ma, Beibei Liu, Yonglan Luo, Sulaiman Alfaifi, Xuping Sun, Min Wu
Summary: Manganese dioxide (MnO2) is a versatile transition-metal dioxide widely used in various fields such as catalysts, oxidants, ferrites, achromats, and battery materials. It is also increasingly utilized in disease diagnosis and treatment in the biomedical field. However, there is a lack of comprehensive review articles on the use of MnO2 in disease diagnosis and treatment. This review provides an overview of the latest developments in MnO2 nanomaterials, focusing on their applications as magnetic resonance, photoacoustic, and fluorescent contrast agents. The review also discusses the potential therapeutic applications of MnO2 nanomaterials and the challenges and prospects for their clinical use.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Physical
Jiani Ding, Yijian Tang, Shasha Zheng, Songtao Zhang, Huaiguo Xue, Qingquan Kong, Huan Pang
Summary: In recent years, carbon materials have been widely used for water treatment due to the increasing concerns about water pollution. Among them, metal-organic framework (MOF) derived carbon has gained popularity due to its high specific surface area, large pore volume, and excellent chemical stability. This review presents the latest developments in using MOFs as templates and precursors for various carbon materials, such as porous carbon, nanocarbon, and graphene, which are pyrolyzed at different temperatures. The article also highlights the future trends and perspectives on their application in water treatment.
Article
Food Science & Technology
Omar Alajil, Vidya R. Sagar, Charanjit Kaur, Shalini Gaur Rudra, R. R. Sharma, Rajeev Kaushik, Mahendra K. Verma, Maharishi Tomar, Manoj Kumar, Mohamed Mekhemar
Summary: The study evaluated the nutritional and nutraceutical characteristics of six commercial apricot genotypes grown in India, finding significant differences in sugars, organic acids, minerals, and antioxidant compounds. The results suggest that certain genotypes are suitable for drying, fresh consumption, or juice processing based on their dry matter and carotenoids content.
Article
Chemistry, Multidisciplinary
Supriya Rej, Amrita Das, Naoto Chatani
Summary: This study presents a metal-free directed ortho-C-H borylation of 2-pyrimidylaniline derivatives, leading to the synthesis of various boronates and triarylborane derivatives. The reaction proceeds smoothly without interference by external impurities, highlighting its importance in synthetic chemistry.
Article
Chemistry, Multidisciplinary
Wei Liu, Huotian Zhang, Songting Liang, Tong Wang, Siqing He, Yunbin Hu, Rui Zhang, Haoqing Ning, Jie Ren, Artem Bakulin, Feng Gao, Jun Yuan, Yingping Zou
Summary: In this study, a multiple D-A ring-like conjugated molecule was synthesized and demonstrated efficient charge separation and high conversion efficiency in organic solar cells. This finding highlights the potential of D-A cyclic conjugated molecules in advancing organic photovoltaic technology.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Review
Chemistry, Applied
Ning Zhang, Xue Yu, Yuewei Zhang
Summary: This review summarizes recent developments in the field of VB1 biocatalysis, allowing the construction of various biologically active heterocyclic scaffolds.
ADVANCED SYNTHESIS & CATALYSIS
(2022)
Review
Food Science & Technology
Zhipeng Lin, Jian Wei, Yongqiang Hu, Dujuan Pi, Mingguo Jiang, Tao Lang
Summary: Caffeine, derived from purine nucleotides, constitutes 2-5% of dry weight in tea and 1-2% in coffee. While plants use methylation reactions and nucleosidase reactions, bacterial degradation occurs through N-demethylation and C-8 oxidation pathways. This study aims to comprehensively summarize the metabolism and application of caffeine in microorganisms, shedding light on its potential prospects.
Review
Chemistry, Inorganic & Nuclear
Xing -Bang Liu, Yuan Huang
Summary: In this review, recent advances in the formation of C-C and C-X bonds using synergistic Ni/Cu catalytic systems are summarized. The review includes various reactions such as Sonogashira-type reactions, asymmetric allylic/propargylic alkylations, hydrofunctionalizations, silylations, borylations, Suzuki-type reactions, C-H bond functionalization, Nazarov cyclization, and diarylation of unreactive alkenes. The unique advantages of the Ni/Cu catalyst system are discussed, and its potential applications in organic synthesis, medicinal chemistry, and materials science are highlighted.
COORDINATION CHEMISTRY REVIEWS
(2023)
Review
Biochemistry & Molecular Biology
Yanan Li, Tao Liu, Jianan Sun
Summary: Nitrogen-containing heterocycles are commonly found in natural products and drugs, and have unique biological features that can be applied in various biological fields, including biological imaging. This review focuses on the synthesis and applications of N-heterocyclic organic small molecules in direct fluorescence cell imaging over the past five years, providing useful information and enlightenment for researchers in this field.
Article
Chemistry, Organic
Sefa Ucar, Arif Dastan
Summary: Protocols have been developed for the easy synthesis of 4-alkynylquinazolines under transition-metal-free conditions. The methods include ring opening reaction, direct alkynylation, and desilylation, and are applicable for scale-up synthesis.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Oncology
Ashutosh K. Dash, Debasis Nayak, Nazar Hussain, Mubashir J. Mintoo, Sumera Bano, Archana Katoch, Dilip M. Mondhe, Anindya Goswami, Debaraj Mukherjee
ANTI-CANCER AGENTS IN MEDICINAL CHEMISTRY
(2019)
Article
Chemistry, Medicinal
Asmita Magotra, Abhishek Gour, Deepak K. Sharma, Ashutosh K. Dash, Gurdarshan Singh, Debaraj Mukherjee, Utpal Nandi
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS
(2019)
Article
Chemistry, Medicinal
Ashutosh K. Dash, Debaraj Mukherjee, Abhijeet Dhulap, Saqlain Haider, Deepak Kumar
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS
(2019)
Review
Chemistry, Multidisciplinary
Sudripet Sharma, Jagattaran Das, Wilfried M. Braje, Ashutosh K. Dash, Sachin Handa
Article
Chemistry, Organic
Madhu Babu Tatina, Wang Xinzhu, Mardi Santoso, Ziad Moussa, Zaher M. A. Judeh
JOURNAL OF ORGANIC CHEMISTRY
(2020)
Article
Chemistry, Organic
Mengxin Xia, Mallikharjuna Rao Lambu, Madhu Babu Tatina, Zaher M. A. Judeh
Summary: This study developed a practical and efficient three-component reaction to synthesize densely functionalized pyrroles from common carbohydrates. The cascade reaction showed high selectivity and catalytic efficiency, suitable for large-scale synthesis and further transformation to more complex structures. The work represents a significant advancement in sustainable synthesis of these ubiquitous heterocycles.
JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Chemistry, Physical
C. P. Kaushik, Jyoti Sangwan, Raj Luxmi, Devinder Kumar, Deepak Kumar, Ashutosh Das, Ashwani Kumar, Dharmendra Singh
Summary: A series of anticancer and antioxidant compounds were synthesized through click chemistry method, with some compounds showing promising activity against cancer cell lines and strong antioxidant activity. Molecular docking studies revealed high binding affinities of certain compounds, suggesting their potential as future candidates for anticancer treatment. In-silico ADME studies also indicated good dispositional profile and patient compliance of the synthesized compounds.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Multidisciplinary
Jai Devi, Sushila Pachwania, Deepak Kumar, Deepak Kumar Jindal, Suraya Jan, Ashutosh K. Dash
Summary: Organotin(IV) complexes have been synthesized and structurally characterized in this study. The synthesized complexes exhibited significant antimicrobial and cytotoxic activities, with complex 20 showing the highest antimicrobial activity, and complex 11 demonstrating the most efficient cytotoxic activity against tested human cancerous cell lines.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Article
Chemistry, Organic
Madhu Babu Tatina, Mohammad Saif Ali, P. Ramesh, Subhash Ghosh
Summary: We present a strategy for the stereoselective synthesis of 1,2-trans-glycosides in the absence of neighboring group participation. The protocol relies on catalyst control instead of protecting group selection, and has been successfully applied for the preparation of various glycosides.
Article
Chemistry, Multidisciplinary
P. Ramesh, Mohamad Saif Ali, Subhash Ghosh, Madhu Babu Tatina
Summary: A simple and environmentally friendly method for the synthesis of glycosides using citric acid mediation has been reported. Under mild reaction conditions, a wide range of glycosides, with the α-isomer as the major product, were prepared from D-glucal, L-rhamnal, D-xylal, and D-galactal with various alcohols, yielding up to 80%.
RESULTS IN CHEMISTRY
(2022)
Article
Integrative & Complementary Medicine
Lalit Sharma, Aditi Sharma, Ashutosh Kumar Dash, Gopal Singh Bisht, Girdhari Lal Gupta
Summary: The study suggests that POL-6 has an anti-anxiety effect and may have therapeutic potential for treating ethanol-type dependence.
BMC COMPLEMENTARY MEDICINE AND THERAPIES
(2021)
Article
Plant Sciences
Banita Devi, Gurvinder Singh, Ashutosh K. Dash, S. K. Gupta
CURRENT PLANT BIOLOGY
(2020)
Article
Chemistry, Organic
Monika Bhardwaj, Nazar Hussain, Irshad Ahmad Zargar, Ashutosh K. Dash, Debaraj Mukherjee
ORGANIC & BIOMOLECULAR CHEMISTRY
(2020)
Review
Multidisciplinary Sciences
Priyanka Sharma, Bharat P. Dwivedee, Dheeraj Bisht, Ashutosh K. Dash, Deepak Deepak Kumar
Article
Chemistry, Multidisciplinary
Madhu Babu Tatina, Ziad Moussa, Mengxin Xia, Zaher M. A. Judeh
CHEMICAL COMMUNICATIONS
(2019)