期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 6, 期 19, 页码 7212-7219出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cy00584e
关键词
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资金
- National University of Ireland
- Science Foundation Ireland [09/IN1/I2602]
The ability to tune the structural and chemical properties of colloidal nanoparticles (NPs) makes them highly advantageous for studying activity and selectivity dependent catalytic behaviour. Incorporating pre-synthesised colloidal NPs into porous support materials remains a challenge due to poor pore wetting and permeability. In this report, monodisperse, composition-controlled AgPd alloy NPs were synthesised and embedded into mesoporous silica SBA-15 using carbon dioxide and expanded hexane. Impregnation resulted in high metal loading without the requirement for surface pre-treatments. The catalytic activity, reaction profiles and recyclability of the alloy NPs embedded in SBA-15 and immobilised on non-porous SiO2 are evaluated. The NPs incorporated within the SBA-15 porous network showed significantly greater recyclability performance compared to non-porous SiO2.
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