期刊
ACS CATALYSIS
卷 6, 期 5, 页码 3248-3252出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b00424
关键词
metal-organic framework; catalysis; hydrogen bond donor; urea MOF; Lewis acid
资金
- AbbVie
A new metal-organic framework (MOF) composed of urea-containing tetracarboxylate struts was synthesized, and its hydrogen bonding capabilities were evaluated. The catalytic performance of this heterogeneous framework is enhanced through preactivation with silyl Lewis acids, leading to Friedel-Crafts reaction rates greater than those of common homogeneous hydrogen bond donors.
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