期刊
ACS CATALYSIS
卷 6, 期 10, 页码 6692-6698出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b01956
关键词
nickel; borylation; silylation; esters; decarbonylation
资金
- 1000-Youth Talents Plan
- Jiangsu Specially-Appointed Professor Plan
- NSF of China [21402086, 21401099]
- NSF of Jiangsu Province [BK20140594]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
The nickel-catalyzed direct borylation and silylation of phenolic esters has been established. The key to this highly efficient acyl C-O bond borylative and silylative cleavage depends on the appropriate choice of different ligands and additives in the presence of nickel catalyst. Both transformations exhibit good functional group compatibility and can serve as powerful synthetic tools for late-stage functionalization of complex compounds. The elucidation of key mechanistic features of this newly developed acyl C-O bond activation in esters was confirmed by two well-characterized organonickel(II) intermediates.
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