Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism

Enantioselectivity in Catalytic Asymmetric Fischer Indolizations Hinges on the Competition of π-Stacking and CH/π Interactions

(2015) Trevor J. Seguin et al.   ORGANIC LETTERS

Kinetic Resolution of Unsymmetrical Acyclic Allyl Carbonates Using Trimethylsilyl Cyanide via Palladium-Catalyzed Asymmetric Allylic Alkylation

(2015) Xue-Long Hou et al.   SYNLETT

Highly Enantioselective Michael Addition of Nitroalkanes to Enones and Its Application in Syntheses of (R)-Baclofen and (R)-Phenibut

(2015) Feng Sha et al.   SYNTHESIS-STUTTGART

Toward a More Complete Understanding of Noncovalent Interactions Involving Aromatic Rings

(2014) Steven E. Wheeler et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Congested C–C Bonds by Pd-Catalyzed Enantioselective Allyl–Allyl Cross-Coupling, a Mechanism-Guided Solution

(2014) Michael J. Ardolino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Raising the pKa Limit of “Soft” Nucleophiles in Palladium-Catalyzed Allylic Substitutions: Application of Diarylmethane Pronucleophiles

(2013) Sheng-Chun Sha et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Pd(0)-Catalyzed Direct Dehydrative Coupling of Terminal Alkynes with Allylic Alcohols To Access 1,4-Enynes

(2013) Yang-Xiong Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed Allylic Substitution Reactions: Stereoselective Construction of α- and β-Substituted Carbonyl Compounds

(2013) P. Evans et al.   SYNTHESIS-STUTTGART

Understanding Substituent Effects in Noncovalent Interactions Involving Aromatic Rings

(2012) Steven E. Wheeler   ACCOUNTS OF CHEMICAL RESEARCH

Origin of Selectivity of Tsuji-Trost Allylic Alkylation of Lactones: Highly Ordered Transition States with Lithium-Containing Enolates

(2012) Mahendra Patil et al.   CHEMISTRY-A EUROPEAN JOURNAL

Natural Products As Sources of New Drugs over the 30 Years from 1981 to 2010

(2012) David J. Newman et al.   JOURNAL OF NATURAL PRODUCTS

The Reaction Mechanism of the Enantioselective Tsuji Allylation: Inner-Sphere and Outer-Sphere Pathways, Internal Rearrangements, and Asymmetric C–C Bond Formation

(2012) John A. Keith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Allylic Cross-Coupling Reactions of Primary and Secondary Homoallylic Electrophiles

(2012) Benjamin J. Stokes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of 1,5-Enynes by Stereospecific Pd-Catalyzed Allyl–Propargyl Cross-Couplings

(2012) Michael J. Ardolino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoroacetic anhydride—catalyzed conjugate addition of boronic acids to α,β-unsaturated ketones

(2012) Silvia Roscales et al.   TETRAHEDRON LETTERS

Direct Asymmetric α-Allylation of Aldehydes with Simple Allylic Alcohols Enabled by the Concerted Action of Three Different Catalysts

(2011) Gaoxi Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereocontrol in Asymmetric Allyl–Allyl Cross-Coupling: Stereocontrolled Reaction of Prochiral Allylboronates with Prochiral Allyl Chlorides

(2011) Laura A. Brozek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemo- and Regioselectivity-Tunable Pd-Catalyzed Allylic Alkylation of Imines

(2011) Jian-Ping Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Construction of All-Carbon Quaternary Centers by Branch-Selective Pd-Catalyzed Allyl–Allyl Cross-Coupling

(2011) Ping Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multinuclear Catalyst for Copper-Catalyzed Asymmetric Conjugate Addition of Organozinc Reagents

(2010) Kohei Endo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aiming for the Ideal Synthesis

(2010) Tanja Gaich et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Enantioselective Allyl−Allyl Cross-Coupling

(2010) Ping Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A DFT Study of the Effect of the Ligands in the Reductive Elimination from Palladium Bis(allyl) Complexes†

(2010) Martín Pérez-Rodríguez et al.   ORGANOMETALLICS

Stereoselective synthesis of aminocyclitol moieties of trehazolin and trehalostatin via enyne metathesis protocol

(2010) Palakodety Radha Krishna et al.   TETRAHEDRON LETTERS

Direct, ChemoselectiveN-tert-Prenylation of Indoles by CH Functionalization

(2009) Michael R. Luzung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unusual Allylpalladium Carboxylate Complexes: Identification of the Resting State of Catalytic Enantioselective Decarboxylative Allylic Alkylation Reactions of Ketones

(2009) Nathaniel H. Sherden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Enol Carbonates

(2009) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Palladium-Catalyzed Alkylation of Acyclic Amides

(2008) Kai Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Steric Tuning of Silylacetylenes and Chiral Phosphine Ligands for Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones

(2008) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Strategy for Employing Unstabilized Nucleophiles in Palladium-Catalyzed Asymmetric Allylic Alkylations

(2008) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation

(2008) John A. Enquist Jr et al.   NATURE

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION