期刊
CHEMICAL SCIENCE
卷 7, 期 7, 页码 4428-4434出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc00145a
关键词
-
资金
- National Natural Science Foundation of China [21473109]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT_14R33]
- 111 project [B14041]
- Engineering and Physical Sciences Research Council [EP/K039687/1] Funding Source: researchfish
- EPSRC [EP/K039687/1] Funding Source: UKRI
Dehydrogenative cross-coupling of aldehydes with alcohols as well as dehydrogentive cross-coupling of primary alcohols to produce esters have been developed using a Rh-terpyridine catalyst. The catalyst demonstrates broad substrate scope and good functional group tolerance, affording esters highly selectively. The high chemoselectivity of the catalyst stems from its preference for dehydrogenation of benzylic alcohols over aliphatic ones. Preliminary mechanistic studies suggest that the active catalyst is a dimeric Rh(II) species, operating via a mechanism involving metal-base-metal cooperativity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据