期刊
CHEMICAL SCIENCE
卷 7, 期 9, 页码 5815-5820出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc01191h
关键词
-
资金
- National Natural Science Foundation of China [21125210, 21421091]
A nickel-catalyzed regioselective addition/cyclization of o-(cyano) phenyl propargyl ethers with arylboronic acids has been developed, which provides an efficient protocol for the synthesis of highly functionalized 1-naphthylamines with wide structural diversity. The reaction is characterized by a regioselective and anti-addition of the arylboronic acids to the alkyne and subsequent facile nucleophilic addition of the resulting alkenylmetal to the tethered cyano group. Mechanistic studies reveal that a Ni(I) species might be involved in the catalytic process.
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