期刊
CHEMICAL SCIENCE
卷 7, 期 9, 页码 6190-6196出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc01742h
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资金
- NSF [CHE-1619590]
- NSFC [21228204]
- NSF career Award [CHE-1149367]
- NSF IDBR [CHE-1455554]
- Direct For Biological Sciences
- Div Of Biological Infrastructure [1455554] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1619590] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1149367] Funding Source: National Science Foundation
Gold-catalyzed C-heteroatom (C-X) coupling reactions are evaluated without using sacrificial oxidants. Vital to the success of this methodology is the nucleophile-assisted activation of aryldiazonium salts, which could be an effective oxidant for converting Au(I) to Au(III) even without the addition of an assisting ligand or photocatalyst. By accelerating the reaction kinetics to outcompete C-C homo-coupling or diazonium dediazoniation, gold-catalyzed Sandmeyer reactions were achieved with different nucleophiles, forming C-Br, C-S and C-P bonds in high yields and selectivities.
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