期刊
TETRAHEDRON LETTERS
卷 57, 期 3, 页码 383-386出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.12.031
关键词
Palladium; Hydroaminocarbonylation; Alkenes; Amines; Amides
资金
- Chinese Academy of Sciences
- National Natural Science Foundation of China [21222203, 21372231, 21133011]
The weak acid has been identified as an efficient basicity-mask to overcome the basicity barrier imparted by aliphatic amines in the Pd-catalyzed hydroaminocarbonylation, which enables both aromatic and aliphatic amines to be applicable in the palladium-catalyzed hydroaminocarbonylation reaction. Notably, by using this protocol, the marketed herbicide of Propanil and drug of Fentanyl could be easily obtained in a one-pot manner. (C) 2015 Elsevier Ltd. All rights reserved.
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