4.4 Article

Copper-catalyzed selective ortho-arylations of 2-naphthol and phenol derivatives with diaryliodonium salts

期刊

TETRAHEDRON LETTERS
卷 57, 期 5, 页码 607-610

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.12.100

关键词

Arylation; Coupling reaction; Diaryliodonium salt; 2-Naphthol; Biaryls

资金

  1. National Nature Science Foundation of China (NSFC) [21272069, 21202186]
  2. Fundamental Research Funds for the Central Universities, Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

向作者/读者索取更多资源

The selective arylations of 2-naphthol and phenol derivatives catalyzed by Cu(OTf)(2) with using diaryliodonium(III) salts have been developed. With this method, biaryls bearing hydroxyl groups can be easily accessed in moderate to good yields. Additionally, this protocol provided an alternative for the preparation of 3-arylated binaphthalene derivatives. (C) 2015 Elsevier Ltd. All rights reserved.

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