期刊
TETRAHEDRON
卷 72, 期 22, 页码 2752-2755出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2016.01.046
关键词
Fe-2(CO)(9); 5+1; Cycloaddition; Vinylcyclopropane; CO
资金
- Natural Science Foundation of China [21232001]
- National Basic Research Program of China-973 Program [2011CB808600]
A Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes (VCPs) and CO to alpha, beta-cyclohexenones has been developed. The reaction can tolerate aryl and aliphatic groups at the alpha-position of VCPs, while VCP substrates with vinyl or alkynyl substitutions are not suitable ones. In addition, this reaction can also be used to synthesize bicyclic rings if an aryl group is attached to the vinyl moiety of the substrate. Compared to the Fe(CO)(5)-mediated [5+1] reaction, the use of cheap and safe Fe-2(CO)(9) and abandoning the photo-irradiation conditions are the two major advantages of the present method. (C) 2016 Elsevier Ltd. All rights reserved.
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