期刊
TETRAHEDRON
卷 72, 期 27-28, 页码 4141-4150出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2016.05.065
关键词
Asymmetric cyclizations; Quaternary phosphonium; Dipeptides; Tandem Michael addition; Organocatalysis
资金
- National Natural Science Foundation of China [21272247, 21572247, 21290184]
Asymmetric tandem Michael Michael reactions between 2-substituted malonates and low reactive enones have been achieved by using novel dipeptides-derived phosphonium salts, affording the synthetically useful and highly functionalized chiral cyclopentanes with good yields, diastereoselectivities and high enantioselectivities. (C) 2016 Elsevier Ltd. All rights reserved.
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