期刊
SYNTHESIS-STUTTGART
卷 48, 期 12, 页码 1927-1933出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561604
关键词
gold-catalyzed dimerization; ionic liquid; addition; cyclization; 1; 2; 3-trisubstituted 2; 3-dihydro-1H-indenes
资金
- Ministry of Education, Culture, Sports, Science (MEXT)
- Japan Agency for Medical Research and Development (AMED)
- Grants-in-Aid for Scientific Research [25460022] Funding Source: KAKEN
Gold-catalyzed dimerization of isoeugenol and related 1-phenylpropenes in ionic liquid enabled environmentally friendly, stereoselective synthesis of 1,2,3-trisubstituted 2,3-dihydro-1H-indenes. Dimerization of isoeugenol or isohomogenol afforded diisoeugenol or diisohomogenol, respectively, with -configuration, whereas dimerization of -asarone furnished diasarone with -configuration.
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