期刊
SYNLETT
卷 27, 期 5, 页码 741-744出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561342
关键词
reduction; radical chain mechanism; anion radical; ketyl; tert-butoxy radical
资金
- JSPS
- [26620082]
- Grants-in-Aid for Scientific Research [14J01461, 26620082] Funding Source: KAKEN
Aryl halides are reduced into the corresponding arenes in high yields, using 2-propanol, cesium carbonate, and di-tert-butyl peroxide (or di-tert-butyl hyponitrite) as a reductant/solvent, a base, and a radical initiator, respectively. This simple system reduces a wide variety of aryl bromides, chlorides, and iodides through single-electron-transfer mechanism with high functional-group tolerance.
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