4.6 Article

Synthesis and Characterizations of Novel Ca-Mg-Ti-Fe-Oxides Based Ceramic Nanocrystals and Flexible Film of Polydimethylsiloxane Composite with Improved Mechanical and Dielectric Properties for Sensors

期刊

SENSORS
卷 16, 期 3, 页码 -

出版社

MDPI
DOI: 10.3390/s16030292

关键词

polymer; flexibility; dynamic mechanical property; nanocomposite; sintering; sensitivity; X-ray diffraction

资金

  1. UM/MOHE/HIR grant [D000014-16001]

向作者/读者索取更多资源

Armalcolite, a rare ceramic mineral and normally found in the lunar earth, was synthesized by solid-state step-sintering. The in situ phase-changed novel ceramic nanocrystals of Ca-Mg-Ti-Fe based oxide (CMTFOx), their chemical reactions and bonding with polydimethylsiloxane (PDMS) were determined by X-ray diffraction, infrared spectroscopy, and microscopy. Water absorption of all the CMTFOx was high. The lower dielectric loss tangent value (0.155 at 1 MHz) was obtained for the ceramic sintered at 1050 degrees C (S1050) and it became lowest for the S1050/PDMS nanocomposite (0.002 at 1 MHz) film, which was made by spin coating at 3000 rpm. The excellent flexibility (static modulus approximate to 0.27 MPa and elongation > 90%), viscoelastic property (tan delta = E ''/E ': 0.225) and glass transition temperature (T-g: -58.5 degrees C) were obtained for S1050/PDMS film. Parallel-plate capacitive and flexible resistive humidity sensors have been developed successfully. The best sensing performance of the present S1050 (3000%) and its flexible S1050/PDMS composite film (306%) based humidity sensors was found to be at 100 Hz, better than conventional materials.

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