期刊
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B
卷 10, 期 3, 页码 435-443出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S199079311603009X
关键词
heptane; diesel oil; auto-ignition; promotion; Mg-MoO3; Al-MoO3; Mg-fluoroplastic mixtures; mechanoactivation
资金
- Russian Foundation for Basic Research [13-03-01124]
- Presidium of the Russian Academy of Sciences [17]
The ignition delay times of heptane-air and diesel oil-air mixtures with and without additives of mechanoactivated Mg-MoO3, Al-MoO3, and Mg-fluoroplastic nanopowders are measured using a rapid-mixture-injection setup. At temperatures below a certain threshold value, the metal-MoO3 additives produce practically no effect on the ignition delay time, whereas at higher temperatures, these additives sharply reduce the ignition delay time, down to the resolution time of the experimental method. The promoting efficiency of the small heterogeneous additives tested is many times superior to that of the known homogeneous promoters. Magnesium-fluoroplastic additives are demonstrated to produce no promoting effect on the ignition of the fuel-air mixtures studied. The mechanism of the action of the heterogeneous additives on the gasphase self-ignition of fuels is discussed.
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