期刊
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
卷 90, 期 10, 页码 1921-1924出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036024416100162
关键词
dehydrogenation; perhydro-m-terphenyl; catalysis; hydrogen
资金
- Ministry of Education and Science [RFMEFI61314X0012]
Comparative studies on the temperature dependence of the dehydrogenation of cis- and trans-isomers of perhydro-m-terphenyl are performed in a flow catalytic reactor. Rate constants and equilibrium constants of all elementary acts of this reaction are calculated on basis of experimental data using the KINET 0.8 program for the mathematical modeling of the kinetics of complex reactions. The resulting data indicate that perhydro-m-terphenyl cis- and trans-isomers structural differences have no appreciable effect on dehydrogenation.
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