期刊
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
卷 86, 期 2, 页码 380-386出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363216020304
关键词
iridium catalysis; ring-closure reaction; dehydrogenation; 2,4,6-triaryl-1,3,5-triazines
资金
- Research Fund for the Doctoral Program of Higher Education [20130093120003]
- Fundamental Research Funds for the Central Universities [JUSRP1023]
An efficient iridium-catalyzed dehydrogenation, ring-closure reaction, has been developed via a cascade sequence, in which [Cp*IrI2](2)/Xantphos proved to be the most efficient catalyst for the synthesis of 2,4,6-triaryl-1,3,5-triazines from stable aryl-substituted alcohols and amidines. It was the first case of iridium catalyst successful application in such transformation.
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