Article
Chemistry, Physical
Fazhrul Haqimee Zaidon, Karimah Kassim, Hamizah Mohd Zaki, Zaidi Embong, El Hassane Anouar, Nor Zakiah Nor Hashim
Summary: In this study, four benzaldehyde thiosemicarbazone derivatives were synthesized and evaluated as organic corrosion inhibitors for mild steel in HCl solution. The compounds exhibited efficient inhibition efficiency, with L3 showing the highest effectiveness. Surface analysis revealed that the adsorption ability of these inhibitors contributed to reduced surface roughness and effective corrosion inhibition on the metal.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Materials Science, Multidisciplinary
Oluwafemi J. Sanumi, Oluwaseyi D. Saliu, Mamookho E. Makhatha
Summary: The research indicates that PEGT1% performs excellently as a corrosion inhibitor for mild steel in 1M HCl, showing better corrosion protection compared to PEGT3%. Principal component analysis revealed that surface area and activity per site were the most important factors in the corrosion rate study.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Materials Science, Multidisciplinary
Raj Kumar Mehta, Mahendra Yadav, I. B. Obot
Summary: This study investigated the anti-corrosion behavior of MTPT and PDPT inhibitors in a 15% HCl solution on oil well and pipeline steel tubes. The results showed that both inhibitors had excellent inhibitory effects and could control both the anodic and cathodic reactions.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Chemistry, Physical
A. R. Shahmoradi, M. Ranjbarghanei, A. A. Javidparvar, L. Guo, E. Berdimurodov, Bahram Ramezanzadeh
Summary: The study investigated the corrosion inhibition property of Juglone extracted from walnut green husk on mild steel samples exposed to an acid electrolyte. The results showed that the efficiency of the inhibitor increased with higher concentration and reached 95% with 800 ppm of green corrosion inhibitor after 8 hours of immersion. Additionally, the extracted GCI functioned as a mixed-type corrosion inhibitor, as revealed by Tafel extrapolated polarization results.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Anees A. Khadom, Mustafa M. Kadhim, Rana A. Anaee, Hameed B. Mahood, Mustafa S. Mahdi, Abbas W. Salman
Summary: This study utilized Density Function Theory (DFT) to investigate the corrosion inhibition effect of Citrus Aurantium extract on metal corrosion, and through molecular docking and correlation analysis of quantum chemical parameters, the study identified the order of inhibition effects of different compounds on metal and microbial corrosion and established an effective model with a 0.98 correlation coefficient.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
A. Sowmyashree, Amita Somya, Sandeep Kumar, Srilatha Rao, Gururaj Kudur Jayaprakash
Summary: This report discusses the application of a room temperature anthraquinone-based liquid crystal as a corrosion inhibitor and emphasizes the importance of mesogenic organization in inhibiting corrosion. The experimental results are in line with the findings from quantum studies.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Engineering, Environmental
Y. Fernine, N. Arrousse, Rajesh Haldhar, Chaitany Jayprakash Raorane, E. Ech-chihbi, Seong-Cheol Kim, F. El Hajjaji, A. Alami, M. Ebn Touhami, M. Taleb
Summary: Two novel organic aromatic thiophene derivatives, TET and OXM, were found to have significant anticorrosion properties on mild steel in an acidic environment. The effectiveness of these inhibitors was influenced by temperature, immersion time, and concentration. The adsorption mechanism of these compounds was evaluated using various techniques and theoretical calculations.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
M. H. Shahini, Mohammad Ramezanzadeh, Ghasem Bahlakeh, Bahram Ramezanzadeh
Summary: This study investigated the use of a novel corrosion inhibitor derived from the Lamb's ear plant to reduce corrosion damage on a metal surface caused by 1 M HCl solution. The results showed that the introduction of MG extract significantly decreased surface corrosion and roughness. High inhibition efficiency was achieved with increasing MGe concentration and exposure time, reaching 96% after 4 hours with 1200 ppm of MGe. The inhibitor followed a mixed-type inhibition mechanism, with Langmuir adsorption isotherm being the most probable. Theoretical studies using MD, MC, and DFT confirmed the adsorption of inhibitors on the metallic surface.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Rajni Narang, Priya Vashishth, Himanshi Bairagi, Sudhish K. Shukla, Bindu Mangla
Summary: The corrosive degradation of mild steel in 0.5 M sulphuric acid was inhibited by ethambutol hydrochloride drug and found to be effective. The inhibitive action increased with higher drug concentration but decreased with escalating temperature. The drug showed its maximum inhibition efficiency at 1000 ppm and 313 K. The adsorption of the drug on the metal surface followed Langmuir adsorption isotherm and EIS analysis confirmed its presence.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Multidisciplinary
Vandana Saraswat, Rinki Kumari, M. Yadav
Summary: Carbon dots (CDMU and CDMH) were synthesized and characterized as eco-friendly corrosion inhibitors for mild steel in 15% HCl solution. Both inhibitors showed high inhibition efficiency and followed Langmuir adsorption isotherm on the surface of mild steel. Various characterization techniques were used to study the inhibitive effect and adsorption behavior of CDMU and CDMH on the metal surface.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2022)
Article
Chemistry, Multidisciplinary
Shida Li, Xueyu Zhang, Shaokui Zheng, Shoupeng Duan, Jun Cui, Hangyu Zhang
Summary: This study investigated the inhibition mechanisms of NaHCO3 and Na2CO3 for mild steel corrosion in a NaCl solution at 40 degrees C. The results showed that both compounds have similar corrosion mechanisms. Higher concentrations of NaHCO3 may affect the stability of the passive film, while higher chloride concentrations decrease the inhibitory effect of NaHCO3.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2021)
Article
Chemistry, Physical
A. A. El Hassani, Z. El Adnani, A. T. Benjelloun, M. Sfaira, M. Mcharfi, M. Benzakour, A. Zarrouk
Summary: This study investigates the interaction between phenyltetrazole derivatives and iron using different density functional methods and basis sets. The results show that meta-GGA functionals are suitable for predicting metal-ligand interactions in the complexes. The interaction between iron and phenyltetrazole compounds occurs mainly through Fe-Me/Me-O/CI, Fe-O, and Fe-N interactions. The inhibitors CI-Ph-T and Me-O-Ph-T have low bond energies and enthalpies, and exhibit similar modes of action. The high adsorption energy of CI-Ph-T and Me-O-Ph-T inhibitors suggests that they are the most stable and have the strongest adsorption.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Nkem B. Iroha, Valentine Chikaodili Anadebe, Ngozi J. Maduelosi, Lebe A. Nnanna, Lucky Cole Isaiah, Omar Dagdag, Avni Berisha, Eno E. Ebenso
Summary: LGP was investigated as a mild steel corrosion inhibitor in 1 M HCl solution. The inhibitory effectiveness of LGP was found to be temperature and inhibitor concentration dependent, with significant reductions in corrosion observed. The adsorption of LGP onto the steel surface obeyed Langmuir isotherm, and the adsorbed inhibitor film layer provided protection against acid ions.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Chemistry, Physical
Seyed Ali Hosseini, Taghi Shahrabi, Bahram Ramezanzadeh
Summary: This study employed a hybrid corrosion inhibitor based on Black cumin extract and zinc cations for the first time to mitigate the dissolution rate of mild steel in NaCl media. The inhibitive film formed in the presence of the inhibitors significantly enhanced the anti-corrosion properties of the mild steel.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Materials Science, Multidisciplinary
Raj Kumar Mehta, Sujata Kumari Gupta, Mahendra Yadav
Summary: In this study, a pair of nitrogen-doped eco-friendly carbon dots (CDs) were synthesized using a one-step hydrothermal technique and their anticorrosion performance for mild steel in 15% HCl solution was investigated. The study showed that the corrosion inhibition efficiency of CD1 and CD2 increased with increasing concentration, reaching 96.8% (CD1) and 94.7% (CD2) after 6 hours immersion at 150 ppm concentration. SEM, AFM, and XPS studies confirmed the formation of a protective film of inhibitor molecules on the mild steel surface.
DIAMOND AND RELATED MATERIALS
(2023)