期刊
CHINESE JOURNAL OF ORGANIC CHEMISTRY
卷 35, 期 4, 页码 770-780出版社
SCIENCE PRESS
DOI: 10.6023/cjoc201411041
关键词
aryne; ortho-quinomethide; reactive intermediate; pericyclic reaction; tandem reaction
资金
- National Natural Science Foundation of China [21002021]
- Program for Science AMP
- Technology Innovation Talents in Universities of Henan Province [13HASTIT010]
Aryne double bond insertion generates an ortho-quinomethide-typed intermediate, which, like aryne itself, is one of the most important reactive intermediates in organic reactions. This review summarizes recent advances in this field and the potential applications in synthetic organic chemistry, with a focus on the reaction mechanism, as well as the structure and reactivity of the ortho-quinomethide intermediates.
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