期刊
CHEMSUSCHEM
卷 8, 期 19, 页码 3314-3322出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201500503
关键词
hydrotalcites; oxidation; heterogeneous catalysis; supported catalysts; transition metals
资金
- National Natural Science Foundation
- Support Plan Project [2012BAE06B08]
- 973 Project [2011CBA00506]
- Beijing Natural Science Foundation [2132032]
- Beijing Engineering Center for Hierarchical Catalysts
- Doctoral Program of the Ministry of Education
- Fundamental Research Funds for the Central Universities [YS1406]
- EPSRC [EP/K014854/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K014854/1] Funding Source: researchfish
Precious metal nanoparticles supported on magnesium-aluminum hydrotalcite (HT), TiO2, and MgO were prepared by sol immobilization and assessed for the catalytic oxidation of octanol, which is a relatively unreactive aliphatic alcohol, with molecular oxygen as the oxidant under solvent- and base-free conditions. Compared with the TiO2- and MgO-supported catalysts, platinum HT gave the highest activity and selectivity towards the aldehyde. The turnover number achieved for the platinum HT catalyst was >3700 after 180min under mild reaction conditions. Moreover, the results for the oxidation of different substrates indicate that a specific interaction of octanal with the platinum HT catalyst could lead to deactivation of the catalyst.
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