Emergence of Chemical Oscillations from Nanosized Target Patterns

This work investigates experimentally the mechanism by which chemical oscillations emerge in a nanometric system. We monitor the spatiotemporal dynamics of an oscillating reaction on the surface of a nanosized three-dimensional Pt model catalyst. Using high-resolution field emission techniques, we are able to show that the oscillations are generated by nanoscale chemical target patterns of much shorter characteristic time than the period with which the oscillations occur. Our observations are made for a specific reaction system-NO2 reduction with hydrogen-and represent the first experimental evidence for the presence of target patterns at the nanoscale. They can be seen as an experimental demonstration of reaction-diffusion mechanisms to hold at the nanoscale as they do at the macroscale. These results shed new light on the emergence of complexity through different time and length scales.