期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 18, 期 10, 页码 7251-7260出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cp06913k
关键词
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资金
- Australian Research Council
- Redflow Ltd
- Alpha Chemicals
- University of Sydney
Six different bromide salts - tetraethylammonium bromide ([N-2,N-2,N-2,N-2]Br, 1Br), 1-ethyl-1-methylpiperidinium bromide ([C(2)MPip]Br, 2Br), 1-ethyl-1-methylpyrrolidinium bromide ([C(2)MPyrr]Br, 3Br), 1-ethyl-3-methylimidazolium bromide ([C(2)MIm]Br, 4Br), 1-ethylpyridinium bromide ([C2Py]Br, 5Br), and 1-(2-hydroxyethyl)pyridinium bromide ([C2OHPy]Br, 6Br) - were studied in regards to their capacity to form polybromide monoanion products on addition of molecular bromine in acetonitrile solutions. Using complementary spectroscopic and computational methods for the examination of tribromide and pentabromide anion formation, key factors influencing polybromide sequestration were identified. Here, we present criteria for the targeted synthesis of highly efficient bromine sequestration agents.
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