期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 18, 期 22, 页码 14867-14873出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cp02878k
关键词
-
资金
- National Natural Science Foundation of China [21373213, 2013CB834604]
- Chinese Academy of Sciences
- Ministry of Science and Technology
Herein, we discuss the study of solvation dynamics of lithium-succinonitrile (SN) plastic crystalline electrolytes by ultrafast vibrational spectroscopy. The infrared absorption spectra indicated that the CN stretch of the Li+ bound and unbound succinonitrile molecules in a same solution have distinct vibrational frequencies (2276 cm(-1) vs. 2253 cm(-1)). The frequency difference allowed us to measure the rotation decay times of solvent molecules bound and unbound to Li+ ion. The Li+ coordination number of the Li+-SN complex was found to be 2 in the plastic crystal phase (22 degrees C) and 2.5-3 in the liquid phase (80 degrees C), which is independent of the concentration (from 0.05 mol kg(-1) to 2 mol kg(-1)). The solvation structures along with DFT calculations of the Li+-SN complex have been discussed. In addition, the dissociation percentage of lithium salt was also determined. In 0.5 mol kg(-1) LiBF4-SN solutions at 80 degrees C, 60% +/- 10% of the salt dissociates into Li+, which is bound by 2 or 3 solvent molecules. In the 0.5 mol kg(-1) LiClO4-SN solutions at 80 degrees C, the salt dissociation ratio can be up to 90% +/- 10%.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据