The Synthesis, Characterization and Dehydrogenation of Sigma-Complexes of BN-Cyclohexanes

A Highly Effective Ruthenium System for the Catalyzed Dehydrogenative Cyclization of Amine-Boranes to Cyclic Boranes under Mild Conditions

(2015) Christopher J. Wallis et al.   CHEMISTRY-A EUROPEAN JOURNAL

Generation of aminoborane monomers RR′NBH2from amine–boronium cations [RR′NH–BH2L]+: metal catalyst-free formation of polyaminoboranes at ambient temperature

(2014) Owen J. Metters et al.   CHEMICAL COMMUNICATIONS

Chemistry of Guanidinate-Stabilised Diboranes: Transition-Metal-Catalysed Dehydrocoupling and Hydride Abstraction

(2014) Arne Wagner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bis-BN Cyclohexane: A Remarkably Kinetically Stable Chemical Hydrogen Storage Material

(2014) Gang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of the Dehydrocoupling and Dehydropolymerization of Amine–Boranes Using a [Rh(Xantphos)]+ Catalyst

(2014) Heather C. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B·NH3 as probed by experiment and computation

(2014) Amit Kumar et al.   Chemical Science

The Role of Chelating Phosphine Rhodium Complexes in Dehydrocoupling Reactions of Amine-Boranes: A Theoretical Investigation Attempting To Rationalize the Observed Behaviors

(2014) Valeria Butera et al.   ACS Catalysis

The Roles of Dihydrogen Bonds in Amine Borane Chemistry

(2013) Xuenian Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Boron Arylation of 1,2-Azaborines

(2013) Gabriel E. Rudebusch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B-Methyl Amine Borane Derivatives: Synthesis, Characterization, and Hydrogen Release

(2013) Patrick G. Campbell et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Mechanisms of metal-catalyzed dehydrocoupling reactions

(2013) Rory Waterman   CHEMICAL SOCIETY REVIEWS

Formation of Trinuclear Rhodium-Hydride Complexes [{Rh(PP*)H}3- (μ2-H)3(μ3-H)][anion]2-During Asymmetric Hydrogenation?

(2013) C. Kohrt et al.   CHEMISTRY-A EUROPEAN JOURNAL

A combined experimental and computational study of fluxional processes in sigma amine–borane complexes of rhodium and iridium

(2013) Andrés G. Algarra et al.   DALTON TRANSACTIONS

Dehydrocoupling of Dimethylamine Borane Catalyzed by Rh(PCy3)2H2Cl

(2013) Laura J. Sewell et al.   INORGANIC CHEMISTRY

Dehydrocoupling Reactions of Dimethylamine-Borane by Pt(II) Complexes: A New Mechanism Involving Deprotonation of Boronium Cations

(2013) Marta Roselló-Merino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials

(2013) Erin M. Leitao et al.   Nature Chemistry

Origin of Binding of Ammonia–Borane to Transition-Metal-Based Catalysts: An Insight from the Charge and Energy Decomposition Method ETS-NOCV

(2013) Monika Parafiniuk et al.   ORGANOMETALLICS

Carbon–carbon bond construction using boronic acids and aryl methyl sulfides: orthogonal reactivity in Suzuki-type couplings

(2013) Joel F. Hooper et al.   Chemical Science

Revealing the P–B coupling event in the rhodium catalysed dehydrocoupling of phosphine–boranes H3B·PR2H (R = tBu, Ph)

(2013) Miguel A. Huertos et al.   Chemical Science

Paramagnetic Titanium(III) and Zirconium(III) Metallocene Complexes as Precatalysts for the Dehydrocoupling/Dehydrogenation of Amine-Boranes

(2012) Holger Helten et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dehydrogenation of Diamine-Monoboranes to Cyclic Diaminoboranes: Efficient Ruthenium-Catalyzed Dehydrogenative Cyclization

(2012) Christopher J. Wallis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Azaborine Chemistry

(2012) Patrick G. Campbell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diborane(4)–metal bonding: between hydrogen bridges and frustrated oxidative addition

(2012) Arne Wagner et al.   CHEMICAL COMMUNICATIONS

The occurrence and representation of three-centre two-electron bonds in covalent inorganic compounds

(2012) Jennifer C. Green et al.   CHEMICAL COMMUNICATIONS

3-Methyl-1,2-BN-cyclopentane: a promising H2storage material?

(2012) Wei Luo et al.   DALTON TRANSACTIONS

A tert-butyl-substituted amino-borane bound to an iridium fragment: A latent source of free H2BNtBuH

(2012) Heather C. Johnson et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Amine–borane dehydrogenation chemistry: Metal-free hydrogen transfer, new catalysts and mechanisms, and the synthesis of polyaminoboranes

(2012) Naomi E. Stubbs et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

UV-Photoelectron Spectroscopy of 1,2- and 1,3-Azaborines: A Combined Experimental and Computational Electronic Structure Analysis

(2012) Anna Chrostowska et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron Complex-Catalyzed Ammonia–Borane Dehydrogenation. A Potential Route toward B–N-Containing Polymer Motifs Using Earth-Abundant Metal Catalysts

(2012) R. Tom Baker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of a Generic Mechanism for the Dehydrocoupling of Amine-Boranes: A Stoichiometric, Catalytic, and Kinetic Study of H3B·NMe2H Using the [Rh(PCy3)2]+ Fragment

(2012) Laura J. Sewell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Metal-Free Hydrogen Transfer between Amine–Boranes and Aminoboranes

(2012) Erin M. Leitao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Three-Stage Mechanistic Model for Ammonia–Borane Dehydrogenation by Shvo’s Catalyst

(2012) Zhiyao Lu et al.   ORGANOMETALLICS

Exploring Small Bite-Angle Ligands for the Rhodium-Catalyzed Intermolecular Hydroacylation of β-S-Substituted Aldehydes with 1-Octene and 1-Octyne

(2012) Indrek Pernik et al.   ACS Catalysis

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

(2011) Romaeo Dallanegra et al.   CHEMICAL COMMUNICATIONS

Ruthenium Bidentate Phosphine Complexes for the Coordination and Catalytic Dehydrogenation of Amine- and Phosphine-Boranes

(2011) Araminta E. W. Ledger et al.   CHEMISTRY-A EUROPEAN JOURNAL

[Ir(PCy3)2(H)2(H2BNMe2)]+ as a Latent Source of Aminoborane: Probing the Role of Metal in the Dehydrocoupling of H3B⋅NMe2H and Retrodimerisation of [H2BNMe2]2

(2011) Charlotte J. Stevens et al.   CHEMISTRY-A EUROPEAN JOURNAL

1,2-BN Cyclohexane: Synthesis, Structure, Dynamics, and Reactivity

(2011) Wei Luo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Four-Coordinate, 14-Electron RuIIComplexes: Unusual Trigonal Pyramidal Geometry Enforced by Bis(phosphino)silyl Ligation

(2011) Morgan C. MacInnis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borane to Boryl Hydride to Borylene Dihydride: Explicit Demonstration of Boron-to-Metal α-Hydride Migration in Aminoborane Activation

(2011) Michael O’Neill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Single-Component Liquid-Phase Hydrogen Storage Material

(2011) Wei Luo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catching the First Oligomerization Event in the Catalytic Formation of Polyaminoboranes: H3B·NMeHBH2·NMeH2Bound to Iridium

(2011) Heather C. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Intermolecular Ene-yne Metathesis Promoted by the Grubbs First-Generation Catalyst: An Alternative Entry Point to Catalysis

(2011) Jennifer E. Marshall et al.   ORGANOMETALLICS

Coordination and Dehydrogenation of Amine-Boranes at Metal Centers

(2010) Gilles Alcaraz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amino-borane oligomers bound to a Rh(i) metal fragment

(2010) Romaeo Dallanegra et al.   CHEMICAL COMMUNICATIONS

Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules

(2010) Anne Staubitz et al.   CHEMICAL REVIEWS

Amine− and Dimeric Amino−Borane Complexes of the {Rh(PiPr3)2}+Fragment and Their Relevance to the Transition-Metal-Mediated Dehydrocoupling of Amine−Boranes

(2010) Adrian B. Chaplin et al.   INORGANIC CHEMISTRY

Dehydrogenation Reactions of Cyclic C2B2N2H12and C4BNH12Isomers

(2010) Myrna H. Matus et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Hydrogen Storage by Boron−Nitrogen Heterocycles: A Simple Route for Spent Fuel Regeneration

(2010) Patrick G. Campbell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium, Rhodium, and Iridium Bis(σ-B−H) Diisopropylaminoborane Complexes†

(2010) Gilles Alcaraz et al.   ORGANOMETALLICS

Bis(σ-amine-borane) Complexes: An Unusual Binding Mode at a Transition-Metal Center

(2009) Romaeo Dallanegra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

BH Activation at a Rhodium(I) Center: Isolation of a Bimetallic Complex Relevant to the Transition-Metal-Catalyzed Dehydrocoupling of Amine-Boranes

(2009) Adrian B. Chaplin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structures and Aggregation of the Methylamine−Borane Molecules, MenH3−nN·BH3(n= 1−3), Studied by X-ray Diffraction, Gas-Phase Electron Diffraction, and Quantum Chemical Calculations

(2009) Simon Aldridge et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Monomeric and Oligomeric Amine−Borane σ-Complexes of Rhodium. Intermediates in the Catalytic Dehydrogenation of Amine−Boranes

(2009) Thomas M. Douglas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization of β-B-Agostic Isomers in Zirconocene Amidoborane Complexes

(2009) Taryn D. Forster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of Rhenium Catalysts for Amine Borane Dehydrocoupling and Transfer Hydrogenation of Olefins

(2009) Yanfeng Jiang et al.   ORGANOMETALLICS

B–N compounds for chemical hydrogenstorage

(2008) Charles W. Hamilton et al.   CHEMICAL SOCIETY REVIEWS

NMR: A good tool to ascertain σ-silane or σ-borane formulations?

(2008) Gilles Alcaraz et al.   COORDINATION CHEMISTRY REVIEWS

Coupling an Electrospray Ionization Mass Spectrometer with a Glovebox: A Straightforward, Powerful, and Convenient Combination for Analysis of Air-Sensitive Organometallics

(2008) Anneke T. Lubben et al.   ORGANOMETALLICS