期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 4, 页码 1233-1238出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201503812
关键词
copper; homogeneous catalysis; photocatalysis; reaction mechanisms; reduction
资金
- Alexander von Humboldt Foundation
- Ministry for Education, Science and Culture of Mecklenburg Vorpommern
- European Union (Investing in our Future, European Regional Development) [PS4H]
- DFG/NFSC project
The reduction of water has been achieved through a non-noble-metal-based homogeneous catalyst system that is formed in situ. Optimisation of the ligand quantities increased catalyst turnover numbers compared to preformed complexes. Mechanistic studies confirm a heteroleptic Cu complex as the active photosensitiser (PS) and an in situ formed Fe-phosphido dimer complex as the water reduction catalyst. The in situ method has been used to screen a range of ligands for the active PS, which has led to the identification a number of structural features important to longevity and performance.
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