Synthesis of New Phosphahelicene Scaffolds and Development of Gold(I)-Catalyzed Enantioselective Allenene Cyclizations

Phosphahelicenes in Asymmetric Organocatalysis: [3+2] Cyclizations of γ-Substituted Allenes and Electron-Poor Olefins

(2015) Maxime Gicquel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic insights into the gold chemistry of allenes

(2014) Weibo Yang et al.   CHEMICAL SOCIETY REVIEWS

Phosphathiahelicenes: Synthesis and Uses in Enantioselective Gold Catalysis

(2014) Paul Aillard et al.   CHEMISTRY-A EUROPEAN JOURNAL

Helicene-like chiral auxiliaries in asymmetric catalysis

(2014) P. Aillard et al.   DALTON TRANSACTIONS

Synthesis, Characterisation, and Organocatalytic Activity of Chiral Tetrathiahelicene Diphosphine Oxides

(2014) Silvia Cauteruccio et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

From Understanding to Prediction: Gold- and Platinum-Based π-Acid Catalysis for Target Oriented Synthesis

(2013) Alois Fürstner   ACCOUNTS OF CHEMICAL RESEARCH

Development of Catalysts and Ligands for Enantioselective Gold Catalysis

(2013) Yi-Ming Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rapid Access to Dibenzohelicenes and their Functionalized Derivatives

(2013) Andrej Jančařík et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Helicenes with Embedded Phosphole Units in Enantioselective Gold Catalysis

(2013) Keihann Yavari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A [2+2+2] cyclization strategy for the synthesis of phosphorus embedding [6]helicene-like structures

(2013) Paul Aillard et al.   CHEMICAL COMMUNICATIONS

Intriguing mechanistic labyrinths in gold(i) catalysis

(2013) Carla Obradors et al.   CHEMICAL COMMUNICATIONS

Heterohelicenes with Embedded P-Chiral 1H-Phosphindole or Dibenzophosphole Units: Diastereoselective Photochemical Synthesis and Structural Characterization

(2013) Keihann Yavari et al.   CHEMISTRY-A EUROPEAN JOURNAL

Helical-Chiral Small Molecules in Asymmetric Catalysis

(2013) Maurice J. Narcis et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

1H-Phosphindoles as Structural Units in the Synthesis of Chiral Helicenes

(2012) Keihann Yavari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One hundred years of helicene chemistry. Part 3: applications and properties of carbohelicenes

(2012) Marc Gingras   CHEMICAL SOCIETY REVIEWS

Chiral cobaltI and nickel0 complexes in the synthesis of nonracemic helicenes through the enantioselective [2 + 2 + 2] cyclotrimerisation of alkynes

(2012) Barbara Heller et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

One-Point Binding Ligands for Asymmetric Gold Catalysis: Phosphoramidites with a TADDOL-Related but Acyclic Backbone

(2012) Henrik Teller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly enantioselective synthesis of silahelicenes using Ir-catalyzed [2+2+2] cycloaddition

(2011) Takanori Shibata et al.   CHEMICAL COMMUNICATIONS

Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes

(2011) Corinne Aubert et al.   CHEMICAL REVIEWS

Helicenes: Synthesis and Applications

(2011) Yun Shen et al.   CHEMICAL REVIEWS

Gold catalysis in total synthesis—an update

(2011) Matthias Rudolph et al.   CHEMICAL SOCIETY REVIEWS

Helicene-Based Phosphite Ligands in Asymmetric Transition-Metal Catalysis: Exploring Rh-Catalyzed Hydroformylation and Ir-Catalyzed Allylic Amination

(2011) Zuzana Krausová et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Tetrathiaheterohelicene Phosphanes as Helical-Shaped Chiral Ligands for Catalysis

(2011) Marco Monteforte et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Phosphoramidite Gold(I)-Catalyzed Diastereo- and Enantioselective Synthesis of 3,4-Substituted Pyrrolidines

(2011) Ana Z. González et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Gold Catalysis: Opportunities Provided by Monodentate Phosphoramidite Ligands with an Acyclic TADDOL Backbone

(2010) Henrik Teller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis and Photophysical Properties of Benzopyrano- or Naphthopyrano-Fused Helical Phosphafluorenes

(2010) Naohiro Fukawa et al.   ORGANIC LETTERS

One-Step Construction of Five Successive Rings by Rhodium-Catalyzed Intermolecular Double [2+2+2] Cycloaddition: Enantioenriched [9]Helicene-Like Molecules

(2009) Ken Tanaka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Gold-Catalyzed Hydroarylation/Cyclization Reactions

(2009) Chung-Meng Chao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand-Controlled Access to [4 + 2] and [4 + 3] Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes

(2009) Pablo Mauleón et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed [4C+2C] Cycloadditions of Allenedienes, including an Enantioselective Version with New Phosphoramidite-Based Catalysts: Mechanistic Aspects of the Divergence between [4C+3C] and [4C+2C] Pathways

(2009) Isaac Alonso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Impact of Steric and Electronic Properties of Ligands on Gold(I)-Catalyzed Cycloaddition Reactions

(2009) Diego Benitez et al.   ORGANIC LETTERS

Gold(I)-Catalyzed Enantioselective [4 + 2]-Cycloaddition of Allene-dienes

(2009) Ana Z. González et al.   ORGANIC LETTERS

Chiral carbene approach to gold-catalyzed asymmetric cyclization of 1,6-enynes

(2009) Yasumasa Matsumoto et al.   TETRAHEDRON LETTERS

A Straightforward Route to Helically Chiral N-Heteroaromatic Compounds: Practical Synthesis of Racemic 1,14-Diaza[5]helicene and Optically Pure 1- and 2-Aza[6]helicenes

(2008) Jiří Míšek et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Origin of Diastereoselectivity in [2 + 2 + 2] Cycloisomerization of Chiral Triynes:  Controlling Helicity of Helicene-like Compounds by Thermodynamic Factors

(2008) Petr Sehnal et al.   JOURNAL OF ORGANIC CHEMISTRY