Article
Chemistry, Physical
Yan Zhuang, Wei Zhang, Yingqing Bao, Mingyun Guan
Summary: LiFePO4/C (LFP/C)-coated LiNi0.8Co0.1Mn0.1(NCM811) was prepared by ball milling, and the effect of different coating amounts of LFP/C on the electrochemical performance of NCM811 was investigated. The results showed that a 1 wt% LFP/C coating resulted in good cycling stability and rate performance, as well as improved high temperature and high pressure cycling stability compared to uncoated materials. The coating layer effectively reduced resistance and suppressed side reactions, enhancing the electrochemical performance of Nickel-rich layered materials.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Electrochemistry
Ji-Hwan Kim, Yo-Seob Kim, Sang-Hyun Moon, Deok-Hye Park, Min-Cheol Kim, Jin-Hyeok Choi, Jae-Hoon Shin, Kyung-Won Park
Summary: This study synthesized micro spherical V2O3 anode samples using a facile solvothermal method and heating process, and successfully prepared V2O3/C composite samples showing enhanced electrochemical performance compared to commercial samples, including higher rate performance, cycling properties, and retention rate.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Inorganic & Nuclear
Ke Wang, Wenkai Ye, Weihao Yin, Wenwen Chai, Yichuan Rui, Bohejin Tang
Summary: In this study, Ga2O3 nanoparticles with a size of about 4 nm were synthesized via a sol-gel method, and three types of carbon materials were employed to improve the conductivity of Ga2O3. Among the carbon materials, reduced graphene oxide was found to be the most effective in providing attachment points for Ga ions, leading to a more uniform distribution of Ga2O3 nanoparticles. The Ga2O3/rGO electrode showed stable capacity retention at a current density of 1000 mA g(-1) after 600 cycles, indicating a promising approach to enhance the electrochemical stability of Li-ion batteries.
DALTON TRANSACTIONS
(2021)
Article
Biochemistry & Molecular Biology
Jeong-Hun Jang, Minseop Lee, Ji-Hye Koo, Seung-Min Paek
Summary: In this study, Ge/RuO2 nanocomposites were successfully fabricated as anode materials for lithium-ion batteries. The well-dispersed Ge nanoparticles within the rutile-type RuO2 matrices enhanced the cycle stability and capacity retention of the anode material, resulting in higher discharge capacities and better capacity retention compared to Ge/GeO2 nanoparticles.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Inorganic & Nuclear
Ping-Ping Sun, Yu-Hang Zhang, Juan Mu, Bo Tian, Fa-Nian Shi
Summary: The new GeMo complex (GeMo), synthesized by mild hydrothermal method, showed improved performance in both lithium ion batteries and supercapacitors after graphene modification.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Meltem Yanilmaz, Goktug Cihanbeyoglu, Juran Kim
Summary: Researchers have synthesized binder-free N, S-doped germanium@ porous carbon nanofiber (N, S-doped Ge@ PCNFs) anodes using a fast, safe, and scalable centrifugal spinning technique. The N, S-doped Ge@ PCNFs exhibit high reversible capacities and show great potential as an anode material for high-performance sodium-ion batteries.
Article
Materials Science, Multidisciplinary
Jungwook Song, Achmad Yanuar Maulana, Woojin Jae, Hyunjeong Gim, Boram Yun, Cybelle M. Futalan, Jongsik Kim
Summary: In this study, a one-dimensional lithium vanadium oxide electrode was successfully synthesized using a simplified method, and it exhibited good electrochemical performance in both half-cell and full cell configurations. These results demonstrate the potential of lithium vanadium oxide as an anode material and open up new possibilities for its commercial applications.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Zhaohui Li, Yongcheng Zhang, Xiangkun Li, Fangchao Gu, Leqing Zhang, Hengjun Liu, Qingtao Xia, Qinghao Li, Wanneng Ye, Chen Ge, Hongsen Li, Han Hu, Shandong Li, Yun-Ze Long, Shishen Yan, Guo-Xing Miao, Qiang Li
Summary: This study investigates the effect of ion-embedding mechanisms on the electrochemical properties of FeS2/Na (Li) cells through a combination of operando magnetometry and electrochemical measurements. It is found that the smaller iron grains produced by the conversion reaction in SIBs lead to more serious pulverization and worse cycle performance. The sluggish kinetics in SIBs caused by the larger Na-ion radius is identified as the underlying reason for the observed phenomena.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Engineering, Environmental
Jianbo Wang, Juan Lv, Mingxing Zhang, Miqi Tang, Qi Lu, Yufei Qin, Yan Lu, Bo Yu
Summary: LiCoO2 is widely used in Li-ion batteries for portable electronics, but current recycling methods involve complex procedures and the use of harmful chemicals. This study introduces a single-step recycling approach based on suspension electrolysis, which uses a simple electrolyte and shows potential for environmentally friendly LiCoO2 recovery.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Ji-Hye Koo, Seung-Min Paek
Summary: A Ge/GeO2/graphene composite material was synthesized to address the volume expansion issue of germanium/germanium oxide nanoparticles during charge/discharge cycles. The material showed superior cycling stability by trapping Ge/GeO2 nanoparticles between graphene nanosheets to offset the volume expansion effect. Transmission electron microscopy images confirmed the distribution of Ge/GeO2 nanoparticles on graphene nanosheets.
Article
Electrochemistry
Ralph Nicolai Nasara, Wen Ma, Shota Tsujimoto, Yuta Inoue, Yuko Yokoyama, Yasuyuki Kondo, Kohei Miyazaki, Yuto Miyahara, Tomokazu Fukutsuka, Shih-kang Lin, Takeshi Abe
Summary: By coating a thin-film Li4Ti5O12 layer on a hard carbon ideal model electrode, this study successfully improved the performance and stability of hard carbon powder, reduced initial reversible capacity loss, and enhanced impedance stability.
ELECTROCHIMICA ACTA
(2021)
Article
Biochemistry & Molecular Biology
Alexey A. Mikhaylov, Alexander G. Medvedev, Dmitry A. Grishanov, Timur M. Fazliev, Vasilii Chernyshev, Elena A. Mel'nik, Tatiana A. Tripol'skaya, Ovadia Lev, Petr V. Prikhodchenko
Summary: Germanium oxide was used as a precursor for germanium-based functional materials. Composite materials of GeO2-rGO, GeP-rGO, and Ge3N4-rGO were prepared and evaluated as anodes for lithium-ion batteries, showing reversible conversion-alloying reactions and high charge capacity.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Materials Science, Multidisciplinary
Dipsikha Ganguly, Sundara Ramaprabhu
Summary: The study introduces alpha-Fe2O3 nanoparticles/etched carbon nanotubes (ECNT) composites synthesized via oxidative etching of acid-functionalized CNT as a promising anode material for lithium-ion batteries. The incorporation of ECNT matrix effectively mitigates the low conductivity and capacity fading issues associated with alpha-Fe2O3, providing better accessibility of the electrolyte and higher active sites for Li+ ion interactions. The synergistic effect of alpha-Fe2O3 and ECNT network leads to excellent rate capability, high capacity, and stability of the anode.
MATERIALS CHEMISTRY AND PHYSICS
(2021)
Article
Nanoscience & Nanotechnology
Abirdu W. Nemaga, Jean Michel, Mathieu Morcrette, Jeremy Mallet
Summary: The use of a Li-active, self-organized TiO2 nanotube template for the fabrication of Ge-based nanostructured anodes is demonstrated in this study. The electrochemical synthesis methods employed are cost-effective, accessible, and scalable. The study emphasizes the important roles of TiO2 nanotube arrays in improving the performance of the anodes.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Nanoscience & Nanotechnology
Shuangying Wei, Marco Serra, Stefanos Mourdikoudis, Huaijuan Zhou, Bing Wu, Lukas Dekanovsky, Jiri Sturala, Jan Luxa, Reshef Tenne, Alla Zak, Zdenek Sofer
Summary: The researchers prepared carbon-coated WS2 nanocomposites by precipitating a carbon precursor on WS2 nanotubes, which showed improved electrochemical performance in lithium-ion batteries and sodium-ion batteries with high capacity and stable cycling performance.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Wengua Zhang, Fanghong Zeng, Huijuan Huang, Yan Yu, Mengqing Xu, Lidan Xing, Weishan Li
Summary: In this study, N-phenyl-bis(trifluoromethanesulfonimide) (PTFSI) was proposed as a novel film-forming electrolyte additive for sodium-ion batteries (SIB). The passivation film generated from the reduction of PTFSI improves the interphasial stability of the electrode material, leading to enhanced long-term cycling performance. The capacity retention of the battery was significantly improved, both in half-cells and full-cells.
Article
Chemistry, Multidisciplinary
Hongqiang Li, Kaining Gan, Ran Li, Huawei Huang, Jiabao Niu, Zhipeng Chen, Jian Zhou, Yan Yu, Jieshan Qiu, Xiaojun He
Summary: In this study, researchers developed a facile carbonization coupled oxidation strategy to produce NiO clusters-decorated Ni-N-C SACs. These SACs exhibited a high Faradaic efficiency of CO and a high turnover frequency for CO production even at high overpotentials. Density functional theory calculations revealed that the highly dispersed NiO clusters played a crucial role in enhancing the reaction kinetics for CO production. This study provides a new pathway for the construction of oxygen-regulated metal-based SACs and various catalytic applications.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Jun Jiang, Xiao-Li Zhou, Hua-Gang Lv, Han-Qing Yu, Yan Yu
Summary: This article reviews the challenges and optimization strategies for bimetallic-based oxygen evolution reaction (OER) materials, summarizing the state-of-the-art electrocatalysts and discussing the relationship between the compositional/structural features of bimetallic-based materials and their electrocatalytic properties. Future efforts to realize sustainable bimetallic-based OER applications are also discussed.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Xianming Xia, Shitan Xu, Fang Tang, Yu Yao, Lifeng Wang, Lin Liu, Shengnan He, Yaxiong Yang, Wenping Sun, Chen Xu, Yuezhan Feng, Hongge Pan, Xianhong Rui, Yan Yu
Summary: The authors developed an artificial heterogeneous interphase (Na@Na2Se/V) on the surface of sodium metal, which exhibits excellent ionic conductivity and mechanical properties. This interphase layer promotes homogeneous sodium deposition without dendrite formation, resulting in outstanding cycling life and electrochemical performance in carbonate-based electrolyte.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Miaoran Zhang, Tiezhu Xu, Di Wang, Tengyu Yao, Zhenming Xu, Qingsheng Liu, Laifa Shen, Yan Yu
Summary: A 3D-printed proton pseudocapacitor with high-mass-loading 3D-printed WO3 anodes, Prussian blue analog cathodes, and anti-freezing electrolytes was developed. It showed state-of-the-art electrochemical performance at low temperatures, with high areal capacitance and energy density. This work provides an effective strategy for practical applications of energy storage devices with complex physical structures at extreme temperatures.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Huijuan Huang, Yunlei Wang, Menghao Li, Hai Yang, Zhihao Chen, Yang Jiang, Shufen Ye, Yaxiong Yang, Shengnan He, Hongge Pan, Xiaojun Wu, Yu Yao, Meng Gu, Yan Yu
Summary: A Ni3S2/Ni3P heterostructure with high work function is constructed to suppress electrolyte decomposition in long-term sodiation process, improving the cyclability and safety of rechargeable sodium-metal batteries. The heterostructure also enhances ion-transport kinetics and enables the formation of stable solid electrolyte interphase for dendrite-free sodium anode.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Yu Jiang, Zuxi Yu, XueFeng Zhou, Xiaolong Cheng, Huijuan Huang, Fanfan Liu, Yaxiong Yang, Shengnan He, Hongge Pan, Hai Yang, Yu Yao, Xianhong Rui, Yan Yu
Summary: A material called 3D-PNCV, which consists of a three-dimensional nitrogen-doped hierarchical porous carbon matrix and single-atom vanadium, is designed and fabricated to enhance the reactivity of sulfur and the performance of sodium polysulfide adsorption and catalytic conversion. The as-fabricated RT Na-S batteries based on 3D-PNCV exhibit a high reversible capacity and excellent rate capability.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Lifeng Wang, Naiqing Ren, Yu Yao, Hai Yang, Wei Jiang, Zixu He, Yang Jiang, Shuhong Jiao, Li Song, Xiaojun Wu, Zhong-Shuai Wu, Yan Yu
Summary: A stable solid electrolyte interphase (SEI) composition, sodium bromide (NaBr), was predicted to suppress Na dendrite growth. The use of 1,2-dibromobenzene (1,2-DBB) additive in the electrolyte resulted in a desirable NaBr-rich stable SEI layer. The Na||Na3V2(PO4)(3) cell with the electrolyte containing 1,2-DBB achieved an extraordinary capacity retention of 94% after 2000 cycles at a high rate of 10 C. This study provides a design philosophy for dendrite-free Na metal anode and can be expanded to other metal anodes.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Food Science & Technology
Yuanyuan Cui, Xin Wang, Yuan Yue, Gengan Du, Hong Chen, Mengge Ning, Yahong Yuan, Tianli Yue
Summary: Metagenomic sequencing analysis revealed the composition of microflora in Tibetan kefir grains (TKGs), with 522 species identified, including Lactobacillus kefir-anofaciens as the most abundant species. Lactobacillus and Bifidobacterium were the most diverse probiotics. Metabolomics analysis showed significant changes in metabolites during kefir fermentation, with different metabolic pathways enriched in different stages of fermentation.
LWT-FOOD SCIENCE AND TECHNOLOGY
(2023)
Review
Chemistry, Physical
Peiyuan Wang, Shumin Sun, Xianhong Rui, Yonghui Zhang, Shiwen Wang, Yuanhua Xiao, Shaoming Fang, Yan Yu
Summary: Due to the limitations of dissolution, shuttle effect and sluggish conversion kinetics, researchers have developed various polar catalysts to address these issues in room-temperature sodium-sulfur batteries. Polar catalysts can not only accelerate and alter the redox process, but also inhibit the shuttle effect by adsorbing polar sodium polysulfides through polar-polar interaction. This review highlights the recent advances in the electrocatalytic effect of polar catalysts on sulfur speciation pathways in room-temperature sodium-sulfur batteries and discusses the challenges and future research directions for achieving rapid and reversible sulfur conversion.
Editorial Material
Chemistry, Multidisciplinary
Xuefeng Zhou, Xianhong Rui, Yan Yu
ACCOUNTS OF MATERIALS RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Junyi Dai, Sha Tan, Lifeng Wang, Fangxin Ling, Fuqiang Duan, Mingze Ma, Yu Shao, Xianhong Rui, Yu Yao, Enyuan Hu, Xiaojun Wu, Chunyang Li, Yan Yu
Summary: In this study, a high-entropy and potassium incorporation strategy was used to construct the HE-K-PBA cathode, which achieved high working voltage and cycling stability. The reaction mechanism of metal cations in HE-K-PBA and the entropy stabilization mechanism were revealed through experimental and simulation studies. HE-K-PBA showed high output voltage, good reversible capacity, and excellent cycling performance, and demonstrated potential application prospects in full cell and all-solid-state batteries.
Review
Chemistry, Multidisciplinary
Shitan Xu, Yi Yang, Fang Tang, Yu Yao, Xiang Lv, Lin Liu, Chen Xu, Yuezhan Feng, Xianhong Rui, Yan Yu
Summary: Next-generation secondary batteries, such as SIBs and PIBs, have great potential for large-scale energy storage systems due to their abundant and cost-effective sodium/potassium raw materials. However, the performance of SIBs (PIBs) relies heavily on the characteristics of the cathode material, and the poor electron conductivity of sodium/potassium vanadium fluorophosphate (MVPF) limits its application in large-scale energy storage. Various modification strategies, including conductive coating, morphological regulation, and heteroatomic doping, have been proposed to enhance the electronic conductivity and ion transportation of MVPF cathodes. Additionally, the development and application of MVPF cathodes in SIBs under low temperature conditions are discussed.
MATERIALS HORIZONS
(2023)
Meeting Abstract
Chemistry, Physical
Yi-jian Xu, Xiao-hui Song, Qiang Chang, Xiang-long Hou, Yi Sun, Xu-yong Feng, Xiang-ru Wang, Miao Zhan, Hong-fa Xiang, Yan Yu
Article
Chemistry, Multidisciplinary
Ying Zhang, Xiaoyu Shi, Shuanghao Zheng, Yuguo Ouyang, Mingrun Li, Caixia Meng, Yan Yu, Zhong-Shuai Wu
Summary: A synergistic strategy of layered-spinel alternate heterostructure and surface coating was developed to alleviate the electrochemical decay caused by lattice strain in Li-rich oxides, leading to improved cycle stability.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)